标题:Simultaneous determination of hydroquinone and catechol based on glassy carbon electrode modified with gold-graphene nanocomposite
作者:Xuemei Ma;Zhaona Liu;Cuicui Qiu
作者机构:Key Laboratory for Colloid and Interface Chemistry of State ducation Ministry, School of Chemistry and Chemical;Key Laboratory f
来源:Mikrochimica Acta: An International Journal for Physical and Chemical Methods of Analysis
出版年:2013
期:5
页码:461-468
关键词:Gold;Graphene;Hydroquinone;Catechol;Voltammetry
摘要:We have synthesized a virtually monodisperse gold-graphene (Au-G) nanocomposite by a single-step chemical reduction method in aqueous dimethylformamide solution. The nanoparticles are homogenously distributed over graphene nanosheets. A glassy carbon electrode was modified with this nanocomposite and displayed high elec-trocatalytic activity and extraordinary electronic transport properties due to its large surface area. It enabled the simultaneous determination of hydroquinone (HQ) and catechol (CC) in acetate buffer solution of pH4.5. Two pairs of well-defined, quasi-reversible redox peaks are obtained, one for HQ and its oxidized form, with a 43 mV separation of peak potentials (ΔE_p), the other for CC and its oxidized form, with a ΔE_p of 39 mV. Due to the large separation of oxidation peak potentials (102 mV), the concentrations of HQ and CC can be easily determined simultaneously. The oxidation peak currents for both HQ and CC increase linearly with the respective concentrations in the 1.0 μ M to 0.1 mM concentration range, with the detection limits of 0.2 and 0.15 μ M (S/N=3), respectively. The modified electrode was successfully applied to the simultaneous determination of HQ and CC in spiked tap water, demonstrating that the Au-G nanocomposite may act as a high-performance sensing material in the selective detection of some environmental pollutants.
资源类型:期刊论文
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