标题:Synthesis and structure of a thiocyanato-bridged one-dimensional Cd II coordination polymer
作者:Li, L.;Liang, J.;Tian, G.
作者机构:[Li, L] College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, Ningxia 750021, China;[ Liang, J] College of Chemistry and Chemic 更多
通讯作者:Li, L
通讯作者地址:[Li, L]Ningxia Univ, Coll Chem & Chem Engn, Ningxia 750021, Peoples R China.
来源:Journal of chemical crystallography
出版年:2011
卷:41
期:1
页码:44-47
DOI:10.1007/s10870-010-9834-3
关键词:One-dimensional coordination polymer;Single crystal X-ray diffraction;Thiocyanato-bridged
摘要:Synthesis and structure of a new thiocyanatobridged one-dimensional coordination polymer, [Cd(NCS)_2 (TPPO)]_n (1, TPPO = triphenylphosphine oxide), have been described. The title compound crystallizes in the monoclinic P2_(1/c) space group with the unit cell parameters: a = 9.4917(4) ?, b = 22.2895(11) ?, c = 11.3300(5) ?, β = 117.433(3)°, V = 2127.49(17) ?3, and Z = 4. The single crystal X-ray diffraction revealed that the structure of 1 features thiocyanate bridges and 1D zigzag chains. The chains consist of thiocyanato-bridged five-coordinated Cd atoms. And the coordination fashion of thiocyanate group is different from the previous reported five-coordinated Cd-NCS systems.
收录类别:SCOPUS;SCIE
WOS核心被引频次:2
Scopus被引频次:1
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-79951673617&doi=10.1007%2fs10870-010-9834-3&partnerID=40&md5=bb6778c35e052ffe2e307879f017a71a
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