标题：Synthesis, Structure and Properties of a Novel Nickel（Ⅱ） Chloride Complex Supported by Phosphine Ligands
作者：LI Jun-Ye[1];SUN Hong-Jian[2]
作者机构：[Li Junye] Department of Pharmaceutical Science and Technology, Heze University, Heze, Shandong 274000, China.;[Sun Hongjian] School of Chemistry and 更多[Li Junye] Department of Pharmaceutical Science and Technology, Heze University, Heze, Shandong 274000, China.;[Sun Hongjian] School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong 250199, China. 收起
摘要：The C-Cl bond of N-(2-chlorophenyl)acetamide (1) was successfully activated by tetrakis(trimethylphosphine)nickel(0). The four-coordinate nickel(II) chloride complex trans-[(C6H4NHC(=O)Me)Ni(PMe3)(2)Cl] (2) as a C-Cl bond activation product was obtained without coordination of the amide group. Phosphonium salt Cl-[Me3P+-ortho-C6H4NHC(=O)Me] (3) was isolated by reacting complex 2 as a starting material under 1 bar of CO at room temperature. The molecular and crystal structures of 2 were determined by single-crystal X-ray diffraction.
