标题:Synthesis, Structure and Properties of a Novel Nickel(Ⅱ) Chloride Complex Supported by Phosphine Ligands
作者:LI Jun-Ye[1];SUN Hong-Jian[2]
作者机构:[Li Junye] Department of Pharmaceutical Science and Technology, Heze University, Heze, Shandong 274000, China.;[Sun Hongjian] School of Chemistry and 更多
通讯作者:Sun, HJ(hjsun@sdu.edu.cn)
通讯作者地址:[Sun, HJ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250199, Peoples R China.
来源:结构化学
出版年:2015
卷:34
期:11
页码:1735-1741
关键词:晶体结构;氯配合物;单晶X-射线衍射;配体;性能;镍;合成;三甲基膦;
摘要:The C-Cl bond of N-(2-chlorophenyl)acetamide (1) was successfully activated by tetrakis(trimethylphosphine)nickel(0). The four-coordinate nickel(II) chloride complex trans-[(C6H4NHC(=O)Me)Ni(PMe3)(2)Cl] (2) as a C-Cl bond activation product was obtained without coordination of the amide group. Phosphonium salt Cl-[Me3P+-ortho-C6H4NHC(=O)Me] (3) was isolated by reacting complex 2 as a starting material under 1 bar of CO at room temperature. The molecular and crystal structures of 2 were determined by single-crystal X-ray diffraction.
收录类别:CSCD;SCOPUS;SCIE
资源类型:期刊论文
原文链接:http://lib.cqvip.com/qk/95925X/201511/666772466.html
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