标题:A novel three-dimensional Cd II metal-organic framework based on [Cd 6(malonate) 6] metallomacrocycles with zeolite SOD (sodalite) topology: Poly[ammine-μ 3-malonato-cadmium(II)]
作者:Yuan,S.;Liu,M.-J.;Xie,H.-Y.;Xu,M.-Z.;Sun,D.
作者机构:[Yuan, S] Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan, Shandong 250100, China;[ Liu, M.-J] Ke 更多
通讯作者:Sun, D
来源:Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications
出版年:2012
卷:68
期:3
页码:m57-m60
DOI:10.1107/S0108270112003277
关键词:Anorectal manometry;Rectoanal inhibitory reflex;Reflexes
摘要:A novel Cd II metal-organic framework, [Cd(C 3H 2O 4)(NH 3)] n, was synthesized by liquid diffusion conducted in the presence of ammonia. The Cd II atom has seven-coordinate O 6N penta-gonal-bipyramidal geometry. Six Cd II centers are joined by six malonate ligands to form an S 6-symmetric [Cd 6(malon-ate) 6] metallomacrocycle, which is further extended through a side-on chelating malonate ligand to form a three-dimensional network. Topologically, each Cd II center is connected to four others to yield an infinite three-periodic four-coordinated SOD (sodalite) network with point symbol {4 2·6 4}. The overall network structure in the crystal is maintained and stabilized by the presence of N - H?O hydrogen bonds.
收录类别:EI;SCOPUS
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84858138451&doi=10.1107%2fS0108270112003277&partnerID=40&md5=baeb19676f83a471be536fcdc80d5416
TOP