标题：Two manganese-amine complexes incorporating thioantimonates and exhibiting diversiform roles of amine ligands
作者：Cheng-Yang Yue;Xiao-Wu Lei;Hui-Ping Zang
作者机构：[Yue, C.-Y] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Sha 更多[Yue, C.-Y] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China;[ Lei, X.-W] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China, State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University Shandong, Jinan 250100, China;[ Zang, H.-P] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China;[ Zhai, X.-R] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China;[ Feng, L.-J] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China;[ Zhao, Z.-F] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China;[ Zhao, J.-Q] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China;[ Liu, X.-Y] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Shandong, Qufu 273155, China 收起 通讯作者：Yue, CY
通讯作者地址：[Yue, CY]Jining Univ, Dept Chem & Chem Engn, Key Lab Inorgan Chem Univ Shandong, Qufu 273155, Shandong, Peoples R China.
来源：CrystEngComm
出版年：2014
卷：16
期：16
页码：3424-3430
DOI：10.1039/c3ce42240b
摘要：Two manganese-amine complexes incorporating thioantimonates, namely (dienH3)[(dienH)MnSb8S15]·H2O (dien = diethylenetriamine) (1) and [Mn(teta)(H2O)2]2[Mn(tren)]2Sb3S12·H3O (2, teta = triethylenetetramine, tren = tris(2-aminoethyl)amine), have been solvothermally synthesized and structurally characterized. Interestingly, the organic amines show diversiform structure-directing actions in the title compounds. In compound 1, two dien molecules exhibit partial coordination to Mn2+ ions and protonated cations, and compound 2 contains mixed tetradentate tren and teta chelating amines. The optical properties, thermal stabilities and magnetic properties have also been studied.
收录类别：SCOPUS;SCIE
WOS核心被引频次：18
Scopus被引频次：19
资源类型：期刊论文
原文链接：https://www.scopus.com/inward/record.uri?eid=2-s2.0-84897376907&doi=10.1039%2fc3ce42240b&partnerID=40&md5=fe71c23f576871459f8081ce345cde81
