标题:Two manganese-amine complexes incorporating thioantimonates and exhibiting diversiform roles of amine ligands
作者:Cheng-Yang Yue;Xiao-Wu Lei;Hui-Ping Zang
作者机构:[Yue, C.-Y] Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University Sha 更多
通讯作者:Yue, CY
通讯作者地址:[Yue, CY]Jining Univ, Dept Chem & Chem Engn, Key Lab Inorgan Chem Univ Shandong, Qufu 273155, Shandong, Peoples R China.
来源:CrystEngComm
出版年:2014
卷:16
期:16
页码:3424-3430
DOI:10.1039/c3ce42240b
摘要:Two manganese-amine complexes incorporating thioantimonates, namely (dienH3)[(dienH)MnSb8S15]·H2O (dien = diethylenetriamine) (1) and [Mn(teta)(H2O)2]2[Mn(tren)]2Sb3S12·H3O (2, teta = triethylenetetramine, tren = tris(2-aminoethyl)amine), have been solvothermally synthesized and structurally characterized. Interestingly, the organic amines show diversiform structure-directing actions in the title compounds. In compound 1, two dien molecules exhibit partial coordination to Mn2+ ions and protonated cations, and compound 2 contains mixed tetradentate tren and teta chelating amines. The optical properties, thermal stabilities and magnetic properties have also been studied.
收录类别:SCOPUS;SCIE
WOS核心被引频次:18
Scopus被引频次:19
资源类型:期刊论文
原文链接:https://www.scopus.com/inward/record.uri?eid=2-s2.0-84897376907&doi=10.1039%2fc3ce42240b&partnerID=40&md5=fe71c23f576871459f8081ce345cde81
TOP