标题:Synthetic[FeFe]-H_2ase models bearing phosphino thioether chelating ligands
作者:Yingjie Zhao;Xin Yu;Huilan Hu;Xinlong Hu;Sakthi Raje;Raja Angamuthu;Chen-Ho Tung;Wenguang Wang
作者机构:[Yingjie Zhao;Xin Yu;Huilan Hu;Xinlong Hu;Sakthi Raje;Raja Angamuthu;Chen-Ho Tung;Wenguang Wang]School of Chemistry and Chemical Engineering.;[Yingjie 更多
通讯作者:Wang, WG
通讯作者地址:[Wang, WG]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China.
来源:Chinese Chemical Letters
出版年:2018
卷:29
期:11
页码:1651-1655
DOI:10.1016/j.cclet.2018.03.013
关键词:[FeFe]-H_2ases models;;Mixed-valence Fe(Ⅰ)Fe(Ⅱ);;Phosphino thioether ligand;;Diiron bridging hydride;;Lewis-acid basicity
摘要:A series of{2Fe3S}complexes bearing phosphino thioether chelating ligand were synthesized on the basis of Fe_2(Me_2pdt)(1,2-Cy_2PC_6H_4SMe)(CO)_4(Me_2pdt=Me_2C(CH_2S~1)_2,1).The disubstituted Fe(Ⅰ)Fe(Ⅰ)compound 1 exhibits a reversible one-electron redox even for[Fe(Ⅰ)Fe(Ⅱ)]~(+/0)couple.Based on the ...
收录类别:SCOPUS;SCIE
WOS核心被引频次:1
资源类型:期刊论文
原文链接:http://kns.cnki.net/kns/detail/detail.aspx?FileName=FXKB201811019&DbName;=CJFQTEMP
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