a, upsilon \" = m) transition: and the anharmonicities of the terminal bonds of the quencher molecules. In addition, the influence of the polarizability on the quenching rate constants is discussed. [publication_type] => J [keyword_plu] => SMALL POLYATOMIC-MOLECULES; RATE CONSTANTS; COLLISIONAL DEACTIVATION [author_in] => [Zou, SL; Liu, CP; Guo, JZ; Gu, YS; Chu, YN; Cao, DZ]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China.@@@[Zou, SL; Liu, CP; Guo, JZ; Gu, YS; Chu, YN; Cao, DZ] Acad Sinica, Anhui Inst Opt & Fine Mech, Laser Spect Lab, Hefei 230031, Peoples R China. [publisher_city] => SHANGHAI [article_id] => 334499,239663,214925 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => ce4e6a3ea2e0691486b6f5a200f16ee51697963774 [begin_page] => 209 [cite_wos] => 0 [check_3Y] => 0 [cite_awos] => 0 [from_id] => 80,73 [cauthor_ad] => [Zou, SL]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [hx_id] => 2371 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 9,5 [format_issn_issue_page_pub_year] => 6093452217357bf2fd58de975de434cc2010166786 [title_en] => Study on the quenching for PCl(b(1)Sigma(+)) by E-V model [publication_29] => ACTA CHIM SINICA [author_fn] => Zou, SL; Liu, CP; Guo, JZ; Gu, YS; Chu, YN; Cao, DZ [pub_year] => 1998 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [check_180] => 0 [keyword_en] => metastable molecule PCl(b(1)Sigma(+)); quenching rate constant; E-V; energy transfer [end_page] => 214 [cauthor_back] => Zou, SL [pages] => 6 [format_wos_No] => 7f8ff603597e95fff03452b96f1010f1-983549644 [hints] => 5 [volume] => 56 [language] => Japanese [source_type] => 351 [issue] => 3 [reference_No] => 6 [batch] => 3241,3252 [publication_en] => ACTA CHIMICA SINICA [school_id] => 117 [sys_update_time] => 2018-09-05 15:29:31 [format_title_en_issn_pub_year] => 7a13c5127696a15d5bff0afe01431a6736929600 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:000072849300001 [page] => 209-214 [hb_type] => 2 [article_dt] => Article [jl_language] => japanese [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ev,metastablemoleculepclb1sigma,energytransfer,quenchingrateconstant [jl_publisher] => actachimicasinica [author_jg] => 山东大学化学系 [keyword_cn] => 亚稳态分子;猝灭过程;E－V传能;PCl [format_title] => df29c2b455c4e6af055439c4c1171f011942024015 [clc] => O613.62 [title_cn] => 利用E―V传能模型研究亚稳态分子PC1(b^1Σ^+)的猝灭过程 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => a6bb28a462722bf647eeb6c8d4e9fa17-2026430942 [CSSN] => 31-1320/O6 [abstract_cn] => 亚稳态分子猝灭机理的研究一直受到人们的极大重视.本文利用E-V传能模型对亚稳态分子PCl(b1∑+)的猝灭过程进行了定量处理.结果表明PCl(b1∑+)的猝灭是PCl(b1∑+→a1△)跃迁和试剂分子端键X-Y振动能级近共振传能的结果,与PCl(b1∑+→a1△)跃迁的Franck-Condon因子及试剂分子端键X-Y振动的非谐性系数有关,而且也受猝灭试剂分子极化率的影响. [sys_priority_field] => 73 [author_cn] => 邹胜利;储焰南 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => 亚稳态分子,猝灭过程,pcl,ev传能 [jl_clc] => o61362 [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => quenchingrateconstant,energytransfer,猝灭过程,pcl,ev传能,亚稳态分子,ev,metastablemoleculepclb1sigma [sys_author_id] => [format_title_cn_publication_cn_pub_year] => c4ad408053007e2b0372ea2c45263112510450851 [format_title_cn_issn_pub_year] => b4d6727bbf40968b002d3228eea84f96-989245316 [id] => sgifvWUBFjIhTVEbUuIV [tags] => 0 ) [8] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 首次报道了1-苯基-3-甲基-4-苯甲酸吡唑啉酮-5(HPMBP)萃取镓的热力学和动力学,指出在体系中形成Ga(PMBP)_3(H_2O)_2萃合物,配体PMBP既有一次溶剂化作用,又有二次溶剂化作用,并得到红外光谱和核磁共振谱的证实.镓的萃取过程为水相化学反应控制,决速步骤为一次溶剂化过程:Ga~(3+)+HPMBP→Ga(PMBP)~(2+)+H~+.添加剂三辛基氧化膦(TOPO)不影响HPMBP萃取镓的分配比,但降低了HPMBP萃取镓的正向速率,表明动力学抑萃作用与热力学抑萃作用无对应关系. [keyword_cn] => HPMBP;镓;萃取热力学;萃取动力学 [article_id] => 334504,44190,237947,554751,498149 [clc] => O657.3 [author_jg] => [杨永会,孙思修,薛梅,刘萍]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => e2ca34822c05f20f678916560bb40081-1580571387 [hints] => 12 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 4236dbc286e737f9e3a8a0d274f55093-354221067 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-06-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 杨永会,孙思修,薛梅,刘萍 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199806014&DbName=CJFQ1998 [publication_cn] => 化学学报 [title_cn] => 1-苯基-3-甲基-4-苯甲酰吡唑啉酮-5萃取镓的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 13f10c3345f748c30848f2a1ff694e65796344967 [page] => 606-611 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 49e59e7f12fc8fb95f17d3bd9187061d-1844975706 [format_title] => 36f5a72fb3f474c77e38976ad1cc9c9c-2112878130 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 萃取动力学,hpmbp,镓,萃取热力学 [jl_clc] => o6573 [author_in] => [Yang, Y.-H] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Sun, S.-X] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Xue, M] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Liu, P] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 镓,hpmbp,萃取热力学,萃取动力学 [cite_wos] => 0 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => 104TR [cauthor_ad] => [Yang, YH]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Yang, YH; Sun, SX; Xue, M; Liu, P [cite_wanfang] => 6 [format_title_en_issn_pub_year] => 1385093e21e981f8ea2ce977cbea016d500697136 [datebase] => Scopus [format_scopus_No] => c4146302fd9349e49de59893eb76d57c1950601997 [publication_29] => ACTA CHIM SINICA [end_page] => 611 [abstract_en] => The extraction equilibrium and kinetics of gallium(III) from hydrochloric acid solutions with 1 - phenyl - 3 - methyl - 4 - benzoyl - pyrazolone - 5(HPMBP) in carbon tetrachloride have been investigated. The composition of the extracted species was found to be Ga(PMBP)(3) . 2H(2)O via the method of slopes, IR and NMR spectra. The values of K-ex, Delta H degrees, Delta G degrees and Delta s degrees at 298K were calculated. The extraction kinetics of Ga(III) was studied with the growing drop method. The extraction rate equation can be expressed as R-f = k(f)[Ga3+][HL]((o)). The activation energy of the reaction was calculated to be 15. 9kJ . mol(-1). The rate determining step was deduced to take place in water phase:Ga3+ + HL --> GaL2+ + H+,which is an immediate coordination process. [publication_type] => J [begin_page] => 606 [author_en] => Yang, YH; Sun, SX; Xue, M; Liu, P [volume] => 56 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5; gallium; extraction; equilibrium; extraction kinetics [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => ada8d8d5baf57bc6c32ef2fea04e1516-428949017 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 17 [cite_awos] => 0 [wos_No] => WOS:000075031900015 [format_wos_No] => 2b159157ad2b61146e0b243650181dc9446894357 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Yang, YH [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33748668790 [title_en] => Extraction of gallium(III) with HPMBP [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => extraction,equilibrium,gallium,extractionkinetics,1phenyl3methyl4benzoylpyrazolone5 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => jw5JvmUBFjIhTVEbudND [tags] => 0 ) [9] => Array ( [batch2] => 2 [batch] => 3250 [tag] => 0 [abstract_cn] => 探讨了电位滴定(PT)法测定的零电荷点的物理意义,认为是零净电荷点(ZPNC).并对零净电荷点PH(pH_(ZPNC)),零可变电荷点pH(pH_(ZPVC)),永久电荷密度(σ_P),可变电荷密度(σ_V)和净电荷密度(σ_T)之间的关系进行了理论分析.用PT法测定了氢氧化铝镁纳米颗粒的pH_(ZPNC)和σp,探讨了电解质浓度和pH对各电化学性质的影响规律.另外,还考察了CO_3~(2-)对PT法测定结果的影响. [keyword_cn] => 零电荷点;电荷密度;氢氧化铝镁;纳米颗粒;电位滴定 [article_id] => 581859 [clc] => O658 [author_jg] => [侯万国,夏春友,韩书华,王果庭,张春光]山东大学胶体与界面化学国家教委开放实验室,山东大学化学院,山东大学胶体与界面化学国家教委开放实验室,山东大学胶体与界面化学国家教委开放实验室,山东大学胶体与界面化学国家教委开放实验室 济南250100,1996届硕士研究生,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 3050245d85141c0771afcdfc40121b38-1008232597 [hints] => 4 [issue] => 05 [sys_level_num] => 2_3 [sys_jg_type] => 0 [format_issn_issue_page_pub_year] => 347d45dd0e22b722be7a1d360e9a80a3312194609 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-05-20 [pages] => 7 [from_id] => 78 [author_cn] => 侯万国,夏春友,韩书华,王果庭,张春光 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199805016&DbName=CJFQ1998 [publication_cn] => 化学学报 [title_cn] => 氢氧化铝镁纳米颗粒的零电荷点及电荷密度研究(英文) [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 8b28190f668db0784cf9e192421ab224-1129442029 [page] => 514-520 [hb_type] => 2 [article_dt] => 期刊论文 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 电位滴定,氢氧化铝镁,零电荷点,电荷密度,纳米颗粒 [jl_clc] => o658 [author_in] => [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [sys_author_id] => [id] => sA5IvmUBFjIhTVEbRWIm [tags] => 0 ) ) 1-->