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III-->II were observed from above three kinds of phase diagrams with increasing the concentration of alcohol, It was observed from the Winsor phase diagram that the phase types, the phase volumes and the concentrations of alcohol at the start point and end point of the Winsor microemulsion formation change with the increase of the concentration of alcohol. From the delta-gamma fishlike phase diagram, some important parameters were calculated, such as the mass fraction of 1-butanol in the hydrophile-lipophile balanced interfacial layer, A(s), the coordinates of the start point and the end point of the Winsor microemulsion formation, and the solubilities of APG and 1-butanol in n-octane phase. The modified epsilon-beta fishlike phase diagram was presented for the first time by us. With the epsilon-beta fishlike phase diagram, the above experimental phenomena were observed and the physico-chemical parameters were calculated precisely. The epsilon-beta fishlike phase diagram has some advantages over the Winsor and delta-gamma fishlike phase diagrams in visual observations of the phase changes, and calculation of the related physico-chemical parameters. [author_in] => [Chai, J.-L] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China, Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Li, D.-X] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China@@@[ Li, G.-Z] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China@@@[ Liang, F.-Z] Department of Chemistry, Shandong Normal University, Jinan 250014, China@@@[ Zhang, G.-Y] Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China@@@[ Xia, R] Beijing Municipal Institute of Drug Controls, Beijing 100035, China [publication_type] => J [begin_page] => 47 [author_en] => Chai, JL; Li, DX; Li, GZ; Liang, FZ; Zhang, GY; Xia, R [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => middle-phase microemulsion; fishlike phase diagram; alkyl polyglucoside;; solubilization [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => GLYCEROL ETHER; BEHAVIOR; SYSTEMS; SURFACTANTS [publication_iso] => Acta Chim. Sin. [format_title_en] => 1db85632938bc923976cb234e5915152-1543514454 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 17 [email] => coliw@sdu.edu.cn [cite_awos] => 16 [wos_No] => WOS:000187998100010 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Studies on the middle-phase microemulsions of alkyl polyglucosides with mixed hydrocarbon chain [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ,middlephasemicroemulsion,alkylpolyglucoside,solubilization,fishlikephasediagram [jl_keyword_cn] => ,鱼状相图,增溶,烷基聚葡糖苷,中相微乳液 [jl_clc] => o6433 [jl_publisher] => sciencechinapress [company_id] => 0,43,169 [author_id] => 25398 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 张国艳 [irtag] => 7 [t_index] => 0 [person_id] => 25398 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1512178 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 鱼状相图,solubilization,中相微乳液,middlephasemicroemulsion,增溶,烷基聚葡糖苷,fishlikephasediagram,alkylpolyglucoside [sys_author_id] => [format_cscd_No] => 827cc9d9bddcf023ff6aecc92b464f51-1880333689 [format_title_en_publication_en_pub_year] => 5ec49a2bfd5426a67629896066b45d5c-52340373 [format_wos_No] => 7de5565e81b162ef4f02ca9cb93cef34583655459 [format_title_en_issn_pub_year] => f510fa03368cd5e01554fb4ec74d85ff251112082 [datebase] => Scopus [format_scopus_No] => ff0433967aa3b3cfe39884e50471aa13-1890847460 [cite_scopus] => 12 [sys_priority_field] => 76 [standard_in] => Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China; Department of Chemistry, Shandong Normal University, Jinan 250014, China; Beijing Municipal Institute of Drug Controls, Beijing 100035, China [scopus_No] => 2-s2.0-30744475113 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => zw1FvmUBFjIhTVEbZaRs [tags] => 0 ) [2] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3249,3252,3241 [tag] => 0 [abstract_cn] => 对吡啶-BH3复合物分别用MP2/6-31+G*和B3LYP/6-31+G*”进行理论计算以预测该复合物的构型及解离能,得到四种构型,在 MP2优化构型基础上作 CCSD/6-31+G*”单点能量计算以验证 MP2与B3LYP结果的可靠性,然后用B3LYP作振动频率分析,计算了各构型的垂直电离势,最后用更大基组作单点能量计算和自然键轨道(NBO)分析.结果表明,N-B直接相连的构型最稳定,其解离能为141.50 kJ/mol,MP2和B3LYP对N-H接近的构型结果相差较大,另外两种构型稳定性介于二者之间,解离能分别为 15.18 kJ/mol,14.6 kJ/MOL(AP2/6-31+G*)... [keyword_cn] => MP2;DFT;分子间相互作用;吡啶-BH3复合物 [article_id] => 495963,239654,332579,620415,661912 [clc] => TP333 [author_jg] => [孟凡翠] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[步宇翔] 山东大学理论化学研究所, 分子动力学国家重点实验室, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 1f5d3d34cc9f15e4f086e2e3b565722d1123403575 [hints] => 27 [issue] => 1 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => ac97560ee46ccdc70c100998b1665e62395708585 [source_type] => 351 [pub_year] => 2002 [pub_date] => 2002-01-20 [pages] => 6 [from_id] => 76,75,73,80,78 [author_cn] => 孟凡翠,步宇翔,刘成卜 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0041869147&partnerID=40&md5=6175a4ab39d85aebdf1b95f62489f2e9 [publication_cn] => 化学学报 [title_cn] => 吡啶-BH_3相互作用复合物的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 15e9a39501dab42624d87a99eb6d43ef-287962947 [page] => 7-12+7 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 11 [fund_No] => 国家自然科学基金(No.29973022); 山东省自然科学基金 [check_3Y] => 0 [language] => Chinese [delivery_No] => 513GC [format_title] => 38bad2d2e048b5d9c651670292633cdc-602386092 [cauthor_ad] => [Meng, FC]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [author_fn] => Meng, FC; Bu, YX; Liu, CB [reference] => Anane H, 1998, CHEM PHYS LETT, V287, P575, DOI@@@10.1016/S0009-2614(98)00243-7@@@Dkhissi A, 2000, CHEM PHYS LETT, V324, P127, DOI@@@10.1016/S0009-2614(00)00474-7@@@Dunbar RC, 2000, J PHYS CHEM A, V104, P8067, DOI 10.1021/jp000524l@@@Kim KS, 1997, CHEM PHYS LETT, V265, P497, DOI@@@10.1016/S0009-2614(96)01473-X@@@Lias S G, 1988, J. Phys. Chem., V17@@@Maroulis G, 2000, J PHYS CHEM A, V104, P4772, DOI 10.1021/jp9941615@@@RAPPE AK, 2000, J PHYS CHEM A, V104, P611@@@Tarakeshwar P, 1999, J PHYS CHEM B, V103, P184, DOI 10.1021/jp9833810@@@WANG YB, 1994, J MOL STRUC-THEOCHEM, V309, P235@@@朱维良, 1998, 化学学报, V56, P233@@@蒋华良, 1998, 中国科学(B), V28, P403 [publication_29] => ACTA CHIM SINICA [end_page] => 12 [abstract_en] => Geometries and dissociation energies are predicated at MP2/6-31 + G* and B3LYP/6 - 31 + G* levels respectively. Single point energy calculations using CCSD method at 6-31+ G* level are also carried out on the four obtained conformers to confirm the results. Then vibrational analysis are made using B3LYP/6-31 + G* method. Single point energy calculations at much larger basis sets and natural bond orbital analysis have been also carried out on the optimized conformers. The outcome indicates that the conformer with the boron atom directly connected to the nitrogen atom is the most stable one with a dissociation energy of 141.50 kJ/mol. The results for the conformer with the nitrogen atom close to one of the hydrogen atom in BH3 differ from each other at MP2 and B3LYP levels. The stability of the other two conformers (with boron atom lying on one of the pyridine carbons) is between that of the aforementioned two conformers and their dissociation energies are 15.18 and 14.06 kJ/mol (MP2/6-31 + G*), respectively. [author_in] => [Meng, F.-C] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China@@@[ Bu, Y.-X] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China, State Key Labortory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China@@@[ Liu, C.-B] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 7 [author_en] => Meng, FC; Bu, YX; Liu, CB [volume] => 60 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => MP2; DFT; intermolecular interaction; pyridine-BH3 complexes [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => AB-INITIO [publication_iso] => Acta Chim. Sin. [format_title_en] => 3150746d9533248eef551ea511ce15c9402255774 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 11 [email] => ji-public.sd.cninfo.net [cite_awos] => 13 [wos_No] => WOS:000173368700003 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Theoretical study of the pyridine-BH3 interaction complex [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => dft,pyridinebh3complexes,mp2,intermolecularinteraction [jl_keyword_cn] => 分子间相互作用,dft,吡啶bh3复合物,mp2 [jl_clc] => tp333 [jl_publisher] => sciencechinapress [company_id] => 133,5 [sys_subject_sort] => 0,0 [college_parent_id] => 133,5 [company_test] => Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 步宇翔 [irtag] => 7 [t_index] => 0 [person_id] => 20105 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1008330 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => intermolecularinteraction,dft,pyridinebh3complexes,分子间相互作用,mp2,吡啶bh3复合物 [sys_author_id] => [format_cscd_No] => 6e1df791b49f8ce52fb812aee290664e-456154184 [format_title_en_publication_en_pub_year] => 67b92b9dcdff15c796d3a464cac1fab6-1842673737 [format_wos_No] => 211e27d83f94e0b55389b4b346267db1-1566593205 [format_title_en_issn_pub_year] => 14c7498ea98c1be53d33d1cbb3196a4e-1156933997 [format_scopus_No] => 708e7b59277885dba205c169dc1c42b11749097738 [standard_in] => Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China; State Key Labortory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China [datebase] => Scopus [cite_scopus] => 10 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-0041869147 [id] => Cg1GvmUBFjIhTVEbF9Bp [tags] => 0 ) [3] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 射线衍射;谱图;低角度;光学玻璃;疏水;光学材料;硬脂酸根;LB;衬底;基片;XPS;层状结构;衍射峰;交换反应;离子交换; [article_id] => 581844,336434,155157,113789 [abstract_cn] => 用直接在5×10~(-5)mol·dm~(-3)稀土(Ⅲ)氯化物水溶液的液面上铺展稀土(Ⅲ)三硬脂酸盐(简称LnSt_3)的方法,在疏水光学玻璃片上连续沉积了44层以上的含稀土(Ⅲ)(La、Nd、Sm、Eu、Tb)硬脂酸盐LB膜,转移比为0.7—0.8.低角度X射线衍射(2θ=0.3—14°)结果表明,膜的结构为高度有序的层状结构,相邻稀土离子面的间距为4.7—4.8nm.X射线光电子能谱(XPS)证实了五种膜中分别含有La、Nd、Sm、Eu和Tb元素.此外,还对LnSt_3LB膜进行了红外光谱考察,表明在亚相中加入一定浓度的稀土离子能有效地抑止界面上LnSt_3的水解作用,为制备含稀土(Ⅲ)... [author_jg] => [杨孔章;肖童;穆劲]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所 济南 250100,济南 250100,济南 250100 [format_title_cn_publication_cn_pub_year] => 3359959f6d44dc3f6bbf2f459e8509be182832712 [hints] => 5 [issue] => 4 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 45135721fcbbf0808e434d101f942b9b-825459669 [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-05-01 [pages] => 4 [from_id] => 80,78,73,85 [author_cn] => 杨孔章;肖童;穆劲; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199104005&DbName=CJFQ1991 [publication_cn] => 化学学报 [title_cn] => 稀土(Ⅲ)三硬脂酸盐LB膜的制备及结构研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 642787845a6ba07a5760498825715084598593491 [page] => 340-343 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 4ba98ecab48a6b92875ce68b41b7ef87-864229722 [format_title] => 342fde6d75c2536dae4b38431b8d8836-365397703 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,lb,基片,光学玻璃,光学材料,层状结构,衬底,硬脂酸根,离子交换,低角度,疏水,交换反应,xps,衍射峰,谱图,射线衍射 [author_in] => [company_id] => 0,0,0,0,0 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 光学玻璃,lb,交换反应,硬脂酸根,光学材料,层状结构,基片,低角度,谱图,衬底,离子交换,xps,衍射峰,疏水,射线衍射 [sys_author_id] => [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [check_3Y] => 1 [language] => Chinese [delivery_No] => FV356 [cauthor_ad] => [YANG, KZ]SHANDONG UNIV,INST COLLOID & INTERFACE CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => YANG, KZ; XIAO, T; MU, J [format_title_en_issn_pub_year] => 57b659ec56cd2c13b8b2b45a01a51697296979423 [publication_29] => ACTA CHIM SINICA [end_page] => 343 [abstract_en] => The LB films of rare-earth (La, Nd, Sm, Eu, Tb) tristearates were prepared by means of spreading them directly on the solutions containing 5 x 10(-5) mol.dm-3 corresponding rare-earth trichlorides. The numbers of layers of various rare-earth tristearates could be formed up to 44 on a plate of hydrophobic glass at 25 mN.m-1, with a transfer ratio of 0.7-0.8. X-ray photoelectron spectroscopy (XPS) verified the presence of La, Nd, Sm, Eu and Tb respectively in corresponding films. IR suggested that no hydrolysis took place in the process of deposition. X-ray diffraction of films in low angle region (0.3-14-degrees) showed that the films are of periodic layered structure, the space of adjacent face of rare-earth ions is 4.7-4.8 nm. According to the area-time curves in the deposition of rare-earth tristearates, there may be a change of film\'s type. [publication_type] => J [begin_page] => 340 [author_en] => YANG, KZ; XIAO, T; MU, J [volume] => 49 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => LANGMUIR-BLODGETT FILMS; DEPOSITION [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => b6d1ac23aca521f06ca1458ea22c0bcb-1511045394 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 4 [cite_awos] => 10 [wos_No] => WOS:A1991FV35600006 [format_wos_No] => b45c0844e9943e157560bb734b6ccacf954696824 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => YANG, KZ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => INVESTIGATION ON PREPARATION AND STRUCTURE OF LB FILMS FOR RARE-EARTH TRISTEARATES [id] => oQ5IvmUBFjIhTVEbRWIm [tags] => 0 ) [4] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [abstract_cn] => 本文合成了具有隔室构造的Schiff碱配体H_3L(L~(3-)=C_(11)H_(11)N_6OS_2~(3-)),并对其进行了元素分析,IR,~1H NMR和MS等项表征.制备了该配体的分别由醋酸根和吡啶分子协配的两种锌的双核配合物,对后者进行了X射线单晶结构分析.[Zn_2L(OH)(py)_2](Py)_2,P2_1/c,a=0.9195(1),b=2.3334(6),c=1.6111(3)nm,β=93.99(1)°,Z=4.结构用直接法解得,最终的R=0.066.测定的结果表明,两锌原子间存在酚氧和羟基的两μ_2-O-桥,每个五配位的锌均具有四方锥型的配位构型. [keyword_cn] => Schiff碱配体;双核锌配合物;晶体结构 [article_id] => 170606,335581,539395,106122 [clc] => O641.4 [author_jg] => [马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,淄博市公安局 济南250100,济南250100,济南250100,济南250100,济南250100,淄博255039 [format_title_cn_publication_cn_pub_year] => d0bfd133d1197a8f0072fe547c29e8791048131311 [hints] => 24 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 541eb4e0ecfe7d2c817d83d9d34432aa-1299104508 [source_type] => 351 [pub_year] => 1996 [pub_date] => 1996-06-20 [pages] => 6 [from_id] => 80,78,73,85 [author_cn] => 马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199606006&DbName=CJFQ1996 [publication_cn] => 化学学报 [title_cn] => 含N,O和S的Schiff碱配体的双核锌配合物的合成与晶体结构 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 830e4c0795d107904455dd94896af91b-1399008932 [page] => 562-567 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 4cb6957559cd6e825d32254ba816292b-818012582 [format_title] => b42d7eb077b76b7d2178d0e929283e43-286254877 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => schiff碱配体,晶体结构,双核锌配合物 [jl_clc] => o6414 [author_in] => [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 晶体结构,双核锌配合物,schiff碱配体 [sys_author_id] => [cite_wos] => 10 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => UY132 [cauthor_ad] => [Ma, CQ]SHANDONG UNIV,COLL CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => Ma, CQ; Wang, XN; Zhang, WX; Yu, ZG; Jiang, DH; Dong, SL [format_title_en_issn_pub_year] => 616f0d6a37643129464f444a89d65e811586679960 [publication_29] => ACTA CHIM SINICA [end_page] => 567 [abstract_en] => A compartmental Schiff base ligand H(3)L(L(3-) = C11H11N6OS23-) has been synthesized and characterized by elemental analyses, H-1 NMR, IR and MS as well as etc.. Its dinuclear zinc complex, which are co-coordinated by acetate radicals and pyridine molecules respectively, have been prepared. For the later the single crystal structure has been determinated by X-ray diffraction. [Zn(2)L(OH)(py)(2)](py)(2), P2(1)/c, a = 0.9195(1), b = 2.3334(6), c = 1.6111(3), beta = 93.99(1)degrees, Z = 4. The structure was solved by direct method. The refinement converges with R = 0.066 and R(w) = 0.070 based on 2028 reflections with I greater than or equal to 3 sigma(I). The results indicate that between two zinc atoms exist two mu(2) - O- bridges formed by a phenolic oxygen atom and a hydroxy group in the lattice, respectively; and every five-coordinate zinc atom possesses a square pyramidal construction. [publication_type] => J [begin_page] => 562 [author_en] => Ma, CQ; Wang, XN; Zhang, WX; Yu, ZG; Jiang, DH; Dong, SL [volume] => 54 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => METAL [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 6f2ce8815607540212db0ef04639c663-64175109 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 6 [cite_awos] => 10 [wos_No] => WOS:A1996UY13200007 [format_wos_No] => 9a9b5ba9621c953e1101135ffa159b27-811654138 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Ma, CQ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => Syntheses and crystal structure of dinuclear zinc complex with Schiff base ligand containing N, O and S dornors [id] => 7w9KvmUBFjIhTVEbYAQa [tags] => 0 ) [5] => Array ( [batch2] => 1,2,6 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33750439156&partnerID=40&md5=2f93640f6aaf8a2eaf206d877b9856a8 [tag] => 0 [abstract_cn] => 用自组装技术在铜电极表面上制备了纯烯丙基硫脲自组装膜 ,并以十二烷基硫醇进一步修饰得到混合自组装膜 .最后 ,将混合膜覆盖的铜电极浸入NaCl溶液中 ,进行交流电处理 .电化学交流阻抗谱和极化曲线测定表明 ,经过交流电处理后 ,在 0 .5mol·dm- 3NaCl溶液中 ,电荷传递电阻增大 ,腐蚀电流密度下降 ,膜的最大覆盖度为 98.6% ,对金属铜腐蚀的缓蚀效率为 98.5 % .而且 ,不论交流电处理与否 ,混合自组装膜在较宽的电极电位范围内均表现出很强的稳定性 [keyword_cn] => 自组装;;电化学交流阻抗;;交流电处理;;缓蚀效率 [fund_No] => 国家自然科学基金(No.20173033); 国家重点基础研究专项经费(No.G19990650)资助项目 [article_id] => 239574,26628,581877,491802,663281,331608 [clc] => O657.3 [author_jg] => [王春涛] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[陈慎豪] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[赵世勇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[李德刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 4082d1972ebf7559942ffbe91d38d2ed-764640997 [hints] => 18 [issue] => 2 [author_first] => 王春涛 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => d28b087a20aed739c97d6e9ea62e8334141953952 [source_type] => 351 [pub_year] => 2003 [pub_date] => FEB [pages] => 5 [from_id] => 76,75,73,80,78,85 [author_cn] => 王春涛;陈慎豪;赵世勇;李德刚 [issn] => 0567-7351 [batch] => 3249,3250,3252,3254,3243,3241 [publication_cn] => 化学学报 [title_cn] => 烯丙基硫脲和十二烷基硫醇对铜的缓蚀作用 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e789edab9d93e455fcd7f4da14d9ca14-1441745287 [page] => 151-155 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [check_3Y] => 4 [language] => Chinese [delivery_No] => 648VU [format_title] => 44258f7c814e336542632261bf46d5b91006423409 [cauthor_ad] => [Chen, SH]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Wang, CT; Chen, SH; Zhao, SY; Li, DG [reference] => BARCIA OE, 1993, J ELECTROCHEM SOC, V140, P2825, DOI 10.1149/1.2220917@@@Brown G M, 1995, J electroanal Chem, V38, P161@@@Cui XL, 2000, COLLOID SURFACE A, V175, P141, DOI@@@10.1016/S0927-7757(00)00528-8@@@@@@Deslouis C, 1988, J Appl Electrochem, V16, P374@@@Diao P, 1999, J ELECTROANAL CHEM, V464, P61, DOI@@@10.1016/S0022-0728(98)00470-7@@@Feng Y, 1996, CORROS SCI, V38, P369, DOI 10.1016/0010-938X(96)00110-2@@@Feng YQ, 1997, J ELECTROCHEM SOC, V144, P55, DOI 10.1149/1.1837365@@@Folquer ME, 2002, CORROSION, V58, P240, DOI 10.5006/1.3279875@@@@@@Itoh M, 1995, Electrochem Soc, V142, P1839@@@Jennings GK, 1998, LANGMUIR, V14, P6130, DOI 10.1021/la980333y@@@Kim T, 1997, J AM CHEM SOC, V119, P189, DOI 10.1021/ja9617956@@@@@@LAIBINIS PE, 1992, J AM CHEM SOC, V114, P9022, DOI 10.1021/ja00049a038@@@Lee H P, 1996, Electrochem Soc, V133, P2035@@@LOO BH, 1982, CHEM PHYS LETT, V89, P346, DOI@@@10.1016/0009-2614(82)83513-6@@@@@@Ma H, 2002, J APPL ELECTROCHEM, V32, P65, DOI 10.1023/A:1014242112512@@@Matsumoto F, 1999, LANGMUIR, V15, P857, DOI 10.1021/la980919k@@@NAHIR TM, 1994, ELECTROCHIM ACTA, V39, P2347, DOI@@@10.1016/0013-4686(94)00209-6@@@@@@SABATANI E, 1993, LANGMUIR, V9, P2974, DOI 10.1021/la00035a040@@@SCHONENBERGER C, 1994, LANGMUIR, V10, P611, DOI 10.1021/la00015a001@@@TIAN ZQ, 1990, ELECTROCHIM ACTA, V35, P879, DOI@@@10.1016/0013-4686(90)90084-D@@@@@@Wang J, 2000, ANAL SCI, V16, P457, DOI 10.2116/analsci.16.457@@@Yamamoto Y, 1993, Electrochem Soc, V140, P436 [publication_29] => ACTA CHIM SINICA [end_page] => 155 [abstract_en] => Self-assembled monolayer of allylthiourea (AT) was first formed on copper surface. 1-Dodecanethiol (DT) was then self-assembled on the surface for subsequent modification: Finally, AC voltage was loaded on copper covered with the mixed film for further improvement. After these processes, an effective inhibition film was obtained as indicated by the high charge-transfer resistance shown in electrochemical impedance spectroscopy and low corrosion current density in polarization curves. The maximum coverage and inhibition efficiency for copper corrosion was 98.6% and 98.5%, respectively. The mixed film was stable in a wide range of potential before and after AC voltage treatment. [author_in] => [Wang, C.-T] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Chen, S.-H] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, State Key Laboratory for Corrosion and Protection, Shenyang 110015, China@@@[ Zhao, S.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Li, D.-G] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 151 [author_en] => Wang, CT; Chen, SH; Zhao, SY; Li, DG [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => self-assembly; electrochemical impedance spectroscopy; AC treatment;; inhibition efficiency [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => SELF-ASSEMBLED MONOLAYERS; IMPEDANCE SPECTROSCOPY; ACID-SOLUTION; GOLD; PROTECTION; ALKANETHIOLS; ELECTRODE; THIOUREA; ELECTRODISSOLUTION; MECHANISMS [publication_iso] => Acta Chim. Sin. [format_title_en] => a4faf1840cf4804e1442d842aa84613c-302212588 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 22 [cite_awos] => 17 [wos_No] => WOS:000181172200001 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Inhibition effect of allylthiourea and 1-dodecanethiol on copper corrosion [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ,selfassembly,inhibitionefficiency,electrochemicalimpedancespectroscopy,actreatment [jl_keyword_cn] => ,电化学交流阻抗,缓蚀效率,自组装,交流电处理 [jl_clc] => o6573 [jl_publisher] => sciencechinapress [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 21630,25925 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 李德广 [irtag] => 7 [t_index] => 0 [person_id] => 21630 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 赵双宜 [irtag] => 7 [t_index] => 0 [person_id] => 25925 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1336537 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => selfassembly,自组装,电化学交流阻抗,缓蚀效率,electrochemicalimpedancespectroscopy,交流电处理,actreatment,inhibitionefficiency [sys_author_id] => [format_cscd_No] => 8a3b1d0f183a636c89058d79260675841607284196 [format_title_en_publication_en_pub_year] => 7aab03bcb657701d93c15b41b08c0f37-1175645358 [format_wos_No] => 9cbbef4d1d1fec8b5f5420a661067c72-847442823 [format_title_en_issn_pub_year] => 2b078fec6705dfb6f25534f890d51631746151285 [format_scopus_No] => 4a5f999cfb62ad56336c6deadba8913d-137805215 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; State Key Laboratory for Corrosion and Protection, Shenyang 110015, China [datebase] => Scopus [cite_scopus] => 11 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-33750439156 [id] => wg5IvmUBFjIhTVEbRWIm [tags] => 0 ) [6] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 用发散法合成了以四碳硅烷为核心 ,周边含 12个 4 硝基偶氮苯介晶基元 (M 5 )端基的新的一代树状碳硅烷 (D1)液晶 ,并用元素分析、核磁共振、基质辅助激光解吸离子化飞行时间质谱 (MALDI TOF MS)、红外、紫外、偏光显微镜、差示扫描量热 (DSC)和X射线衍射法 (WAXD)表征 .介晶基元化合物 (M 5 )显示向列相 ,树状物D1显示胆甾相和SE 相 .D1的液晶相相行为是K70Ch188I185Ch5 8SE48K . [keyword_cn] => SE相液晶;胆甾相液晶;一代树状化合物;4-硝基偶氮苯;碳硅烷 [article_id] => 661939,491947,239576,331008,105806,539408 [clc] => O621 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[盛昕] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.@@@[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国 [format_title_cn_publication_cn_pub_year] => 8170dfac23db0c4ed46e5db92b935c16 [hints] => 19 [issue] => 9 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => c1db1e67b6543d484c32d48aa06c3e5f [source_type] => 351 [pub_year] => 2003 [pub_date] => SEP [pages] => 6 [from_id] => 76,75,73,80,78,85 [author_cn] => 张其震,盛昕,殷晓颖,季怡萍,李光,赵晓光 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33750478392&partnerID=40&md5=15bb4c1b81de8c4567709cc21599978d [publication_cn] => 化学学报 [title_cn] => 一代树状碳硅烷液晶研究——端基含12个4-硝基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e9121686c8acc7935fee06bf45efc226 [page] => 1478-1483 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [fund_No] => 国家自然科学基金(Nos.29874020,59573029); 中国科学院高分子物理重点实验室基金(中国科学院长春应用化学研究所Nos.R 149833C,R159633Q,R159833C)资助项目; 山东省自然科学基金(No.Y95B0720) [check_3Y] => 1 [language] => Chinese [delivery_No] => 765AX [format_title] => 18dc671fa82aae1df82250ae3dad3429-2143997399 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Sheng, X; Yin, XY; Ji, YP; Li, G; Zhao, XG [reference] => Archut A, 1998, J AM CHEM SOC, V120, P12187, DOI 10.1021/ja9822409@@@@@@de Vries A, 1985, Mol. Cryst. Liq. Cryst., V131, P125@@@DEMUS L, 1978, TEXTURES LIQUID CRYS, P55@@@FINKELMAN H, 1991, LIQUID CRYSTALLINITY, P256@@@FISHWICK M, 1970, J ORGANOMET CHEM, V25, P69, DOI@@@10.1016/S0022-328X(00)86206-3@@@@@@FURNISS BS, 1978, VOGELS TXB PRACTICAL, P715@@@GRAY CW, 1984, SMECTIC LIQUID CRYST, P21@@@Hudson SD, 1997, SCIENCE, V278, P449, DOI 10.1126/science.278.5337.449@@@JANGE DM, 1999, J AM CHEM SOC, V121, P4912@@@KANG SK, 1985, SYNTHESIS-STUTTGART, P1161@@@Karstedt B, 1973, US 3775452@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@PERCEC V, 1995, J AM CHEM SOC, V117, P11441, DOI 10.1021/ja00151a008@@@Pesak DJ, 1997, ANGEW CHEM INT EDIT, V36, P1636, DOI@@@10.1002/anie.199716361@@@@@@Ponomarenko SA, 1996, LIQ CRYST, V21, P1, DOI 10.1080/02678299608033789@@@[唐新德 Tang XinDe], 2003, [有机化学, Chinese Journal of Organic Chemistry],@@@V23, P238@@@van der Made A W, 1992, J. Chem. Soc., Chem. Commun, P1400@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P619@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P1108@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1998, 高等学校化学学报, V19, P1175@@@张其震, 1998, 高等学校化学学报, V19, P827@@@张其震, 1997, 高等学校化学学报, V18, P158@@@周其凤, 1994, 液晶高分子@@@张其震, 2000, 功能高分子材料 [publication_29] => ACTA CHIM SINICA [end_page] => 1483 [abstract_en] => The divergent synthesis of a new carbosilane liquid crystalline (LC) dendrimer of the first generation (D1) is described. Twelve 4-nitroazobenzene are used as mesogenic fragments and attached in its periphery and fourcarbosilane as core. Structure and properties of D1 were characterized by elemental analysis, H-1 NMR, MALDITOF-MS, IR, UV-vis, polarizing optical micrograph, DSC and WAXD. Mesogenic compound NU exhibits nematic and dendrimer D1 reveals cholesteryl and smectic E liquid crystalline state. Phase behavior of D1 in LC state is K70Ch188I185Ch58S(E)48K. [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Sheng, X] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Yin, X.-Y] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Ji, Y.-P] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Li, G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China@@@[ Zhao, X.-G] Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [publication_type] => J [begin_page] => 1478 [author_en] => Zhang, QZ; Sheng, X; Yin, XY; Ji, YP; Li, G; Zhao, XG [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => smectic E liquid crystal; cholesteryl liquid crystal; dendrimer of the; first generation; 4-nitroazobenzene; carbosilane [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => MOLECULES [publication_iso] => Acta Chim. Sin. [format_title_en] => 72e6a710dc200fc72d3fa13a072b072f1961440278 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 26 [email] => qzzhang@sdu.edu.cn [cite_awos] => 10 [wos_No] => WOS:000188245700026 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on a carbosilane liquid crystalline dendrimer of the first generation - Containing twelve 4-nitroazobenzene mesogen in its periphery [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => dendrimerofthe,carbosilane,smecticeliquidcrystal,firstgeneration,cholesterylliquidcrystal,4nitroazobenzene [jl_keyword_cn] => 碳硅烷,se相液晶,一代树状化合物,4硝基偶氮苯,胆甾相液晶 [jl_clc] => o621 [jl_publisher] => sciencechinapress [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => 21651,25088,21654,25613,25608,25110 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 李广 [irtag] => 7 [t_index] => 0 [person_id] => 21654 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 张群姿 [irtag] => 8 [t_index] => 1 [person_id] => 25613 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 张庆竹 [irtag] => 7 [t_index] => 1 [person_id] => 25608 ) [3] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 尹向勇 [irtag] => 7 [t_index] => 0 [person_id] => 25110 ) [4] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 李刚 [irtag] => 7 [t_index] => 0 [person_id] => 21651 ) [5] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 3 [name] => 殷向阳 [irtag] => 7 [t_index] => 0 [person_id] => 25088 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:1240527 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => 碳硅烷,胆甾相液晶,4硝基偶氮苯,一代树状化合物,se相液晶,dendrimerofthe,carbosilane,smecticeliquidcrystal,4nitroazobenzene,cholesterylliquidcrystal,firstgeneration [sys_author_id] => [format_cscd_No] => 1a6c961ad307e103e8df8f6f9926c588 [format_title_en_publication_en_pub_year] => 9ad6c9357e51940acf84d2006a097042 [format_wos_No] => 637169992029da2a60fba69bc1ad9797 [format_title_en_issn_pub_year] => 69741bfe6e6e1b16603d457bb97c0f65 [format_scopus_No] => d0da8f3645bfba0c40230695d3bc7d88 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China [cauthor] => Zhang, QZ(qzzhang@sdu.edu.cn) [datebase] => Scopus [cite_scopus] => 8 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-33750478392 [jl_pub_year] => 2003 [jl_author_test] => unameuu5f20u7fa4u59ff,usureu0,unameuu6bb7u5411u9633,unameuu5f20u5e86u7af9,unameuu5c39u5411u52c7,uuindex3,uuindex1,upersonid25110,utindex1,utindex0,uirtag7,upersonid21654,upersonid21651,upersonid25608,upersonid25088,unameuu674eu521a,unameuu674eu5e7f,uuindex5,upersonid25613,uirtag8 [sys_author_jg_last_arr] => 中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => china [id] => _A9KvmUBFjIhTVEbYgQg [tags] => 0 ) [7] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3252 [tag] => 0 [abstract_cn] => 合成了配合物晶体FeHg(SCN)_4和MnHg(SCN)_4用单晶X射线衍射方法测定了这两个晶体的结构.以尿素为标准样品用粉末晶体倍频1064nm的Nd:YAG激光,测得其倍频光强度分别为:FeHg(SCN)_4,0.6倍于尿素;MnHg(SCN)_4,50倍于尿素.后者显示了作为新的非线性光学材料的发展前景. [keyword_cn] => FeHg(SCN)_4;MnHg(SCN)_4;合成;结构;非线性光学性质 [article_id] => 334193,598069,497487,239674 [clc] => O657.62 [author_jg] => [延云兴,方奇,于文涛,袁多荣,田玉鹏,蒋民华,I.D.Williams,蔡志岗]山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,香港科技大学化学系,中山大学超快光谱国家重点实验室 济南250100,济南250100,济南250100,济南250100,济南250100,济南250100,广州510275 [format_title_cn_publication_cn_pub_year] => 7f5526acac20ac0ab19ea339f1fea66b2010541780 [hints] => 16 [issue] => 11 [sys_level_num] => 2_3 [sys_jg_type] => 8,3,5,8,8 [format_issn_issue_page_pub_year] => ffc90dae027a2ed5d456a676c34ce58341070224 [source_type] => 351 [pub_year] => 1999 [pub_date] => 1999-11-20 [pages] => 5 [from_id] => 76,80,73,78 [author_cn] => 延云兴,方奇,于文涛,袁多荣,田玉鹏,蒋民华,I.D.Williams,蔡志岗 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-0042760475&partnerID=40&md5=389c6718d63b164cba411cca6d848bc7 [publication_cn] => 化学学报 [title_cn] => 金属硫氰酸根配合物FeHg(SCN)_4,MnHg(SCN)_4的合成、晶体结构与非线性光学性质的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => c38bd49848c694709001f8325875cbf6-205425360 [page] => 1257-1261 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [check_3Y] => 2 [language] => Chinese [delivery_No] => 257LT [format_title] => 23cbbceaa13fcf3c53eb990c1bd966ea1529278062 [cauthor_ad] => [Yan, YX]Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China. [author_fn] => Yan, YX; Fang, Q; Yu, WT; Yuan, DR; Tian, YP; Williams, ID; Cai, ZG [publication_29] => ACTA CHIM SINICA [end_page] => 1261 [researcherID] => williams, ian/B-2907-2009 [abstract_en] => The title compounds FeHg(SCN)(4) and MnHg(SCN)(4) were synthesized and their structures were determined by single crystal X-ray diffraction analysis. Irradiated with a 1064 nm Nd: YAG laser beam, the powdered crystals of FeHg(SCN)(4) show a 532 nm second harmonic intensity of 0.6 times that of urea which was taken as standard sample, whereas the powdered crystals of MnHg(SCN)(4) show a second harmonic intensity of 18 times that of urea. The latter shows a quite promising application value as a useful nonlinear optical materials. [orcID] => williams, ian/0000-0001-8743-401X [author_in] => [Yan, Y.-X] Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Fang, Q] Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Yu, W.-T] Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Yuan, D.-R] Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Tian, Y.-P] Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Williams, I.D] Department of Chemistry, Hong Kong University of Science and Technology, Hong Kong, Hong Kong@@@[ Cai, Z.-G] Institute of Laser Spectroscopy, Stake Key Laboratory of Ultrafast Laser Spectroscopy, Zhongshan University, Guangzhou, 510275, China [publication_type] => J [begin_page] => 1257 [author_en] => Yan, YX; Fang, Q; Yu, WT; Yuan, DR; Tian, YP; Williams, ID; Cai, ZG [volume] => 57 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => FeHg(SCN)(4); MnHg(SCN)(4); synthesis; structure; non-linear optical; properties [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en] => a4552d36299face55689379cb981779c1585052025 [publisher_city] => BEIJING [hx_id] => 2378,2371 [reference_No] => 7 [cite_awos] => 11 [wos_No] => WOS:000083783900013 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Synthesis, structure and non-linear optical properties of FeHg(SCN)(4) and MnHg(SCN)(4) [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => nonlinearoptical,mnhgscn4,fehgscn4,properties,structure,synthesis [jl_keyword_cn] => 结构,非线性光学性质,fehgscn4,mnhgscn4,合成 [jl_clc] => o65762 [jl_publisher] => sciencepress [company_id] => 24,0,151 [sys_subject_sort] => 0,0 [college_parent_id] => 24,151 [company_test] => Array,Array [author_id] => 24888,20672 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 1 [name] => 延云兴 [irtag] => 0 [t_index] => 1 [person_id] => 24888 ) [1] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 2 [name] => 方奇 [sys_author_id] => Array ( [0] => 24888 [1] => 20672 ) [irtag] => 0 [t_index] => 0 [person_id] => 20672 ) ) [sys_author_id_arr] => 20672方奇,24888延云兴 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => nonlinearoptical,非线性光学性质,合成,mnhgscn4,synthesis,fehgscn4,properties,structure,结构 [sys_author_id] => 20672,24888 [format_title_en_publication_en_pub_year] => 9835378386dab0cf092e6f6d5041f8b11297614056 [format_wos_No] => eaf42e16978abfb932facabcd43f37a5-1011724265 [format_title_en_issn_pub_year] => 8915900ea909370a1ec332561f29d4b9235157633 [datebase] => Scopus [format_scopus_No] => 0cbd29fea4dade47160ebfe37bf8cc95371133132 [cite_scopus] => 5 [sys_priority_field] => 76 [standard_in] => Institute of Crystal Materials, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China; Department of Chemistry, Hong Kong University of Science and Technology, Hong Kong, Hong Kong; Institute of Laser Spectroscopy, Stake Key Laboratory of Ultrafast Laser Spectroscopy, Zhongshan University, Guangzhou, 510275, China [scopus_No] => 2-s2.0-0042760475 [id] => 4Q5HvmUBFjIhTVEbZySy [tags] => 0 ) [8] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3249,3252,3241 [tag] => 0 [abstract_cn] => 研究了Cr(VI)在带结构正电荷的Mg-Al型类水滑石(HTlc)上的吸附性能,考察了pH、无机电解质添加剂NaCl,NaNO3,Na2SO4和Na3PO4及有机添加剂EDTA和柠檬酸等因素的影响,并结合红外光谱和XRD实验结果探讨了吸附机理.研究表明,Mg-Al型HTlc对Cr(VI)有很强的吸附能力,其吸附动力学和吸附等温线分别符合准二级速率方程和Langmuir方程,饱和吸附量达105mg/g,有望成为一种优良的含Cr(VI)污水处理剂和Cr(VI)污染土壤修复剂.初始pH增大,吸附量降低.无机电解质和有机添加剂均能明显抑制Cr(VI)在HTlc上的吸附,其抑制吸附作用的强弱顺序分别为N... [keyword_cn] => 类水滑石;双层金属氢氧化物;铬(VI);吸附 [article_id] => 662750,238351,597933,325376,484562 [clc] => O645 [author_jg] => [臧运波] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[侯万国] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[王文兴] 山东大学环境研究院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => fac3a08d0bc5ad6e077cdaceb9d500e11808613030 [hints] => 24 [issue] => 9 [sys_level_num] => 2_3 [sys_jg_type] => 11,8,3,5 [format_issn_issue_page_pub_year] => 9b78952b3f1064530f4877252fef0562-1686157375 [source_type] => 351 [pub_year] => 2007 [pub_date] => MAY 14 [pages] => 6 [from_id] => 76,75,73,80,78 [author_cn] => 臧运波;侯万国;王文兴; [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-80052801664&partnerID=40&md5=b3d47e23efeaec606e941d096353d5dd [publication_cn] => 化学学报 [title_cn] => Cr(VI)在Mg-Al型类水滑石上的吸附-脱附性研究I.吸附性 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 98a5320ecf13ab9f6eab83bcb9540fdf-2109314069 [page] => 773-778 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [fund_No] => 国家重大基础研究973计划项目; 国家自然科学基金; 山东省自然科学基金资助项目 [check_3Y] => 8 [language] => Chinese [delivery_No] => 171DR [format_title] => a43de7867977da7f77f0420d6b24adb9-675640967 [cauthor_ad] => [Zang, YB]Shandong Univ, Educ Minist, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China. [author_fn] => Zang Yun-Bo; Hou Wan-Guo; Wang Wen-Xing [reference] => Ferreira OP, 2006, CHEMOSPHERE, V62, P80, DOI@@@10.1016/j.chemosphere.2005.04.009@@@Goswamee RL, 1998, APPL CLAY SCI, V13, P21, DOI@@@10.1016/S0169-1317(98)00010-6@@@Ho YS, 1998, CHEM ENG J, V70, P115, DOI 10.1016/S0923-0467(98)00076-1@@@Hu J, 2005, C. Water Res, V39, P4528@@@[金志林 Jin Zhilin], 2003, [化学学报, Acta Chemical Sinica], V61, P1208@@@Kongsricharoern N, 1996, WATER SCI TECHNOL, V34, P109, DOI@@@10.1016/S0273-1223(96)00793-7@@@Lazaridis NK, 2004, IND ENG CHEM RES, V43, P2209, DOI 10.1021/ie030735n@@@Li F, 2005, J HAZARD MATER, V125, P89, DOI 10.1016/j.jhazmat.2005.04.037@@@[李志萍 LI Zhiping], 2006, [环境科学学报, Acta Scientiae Circumstantiae], V26,@@@P99@@@Lv L, 2006, J HAZARD MATER, V133, P119, DOI@@@10.1016/j.jhazmat.2005.10.012@@@Pavan PC, 2000, J COLLOID INTERF SCI, V229, P346, DOI@@@10.1006/jcis.2000.7031@@@Pavlovic I, 2005, APPL CLAY SCI, V30, P125, DOI@@@10.1016/j.clay.2005.04.004@@@PEREZCANDELA M, 1995, WATER RES, V29, P2174, DOI@@@10.1016/0043-1354(95)00035-J@@@Rengaraj S, 2001, J HAZARD MATER, V87, P273, DOI@@@10.1016/S0304-3894(01)00291-6@@@Rives V, 1999, COORDIN CHEM REV, V181, P61, DOI@@@10.1016/S0010-8545(98)00216-1@@@Sasaki S, 2006, J EUR CERAM SOC, V26, P655, DOI@@@10.1016/j.jeurceramsoc.2005.06.021@@@Wang SL, 2006, COLLOID SURFACE A, V277, P8, DOI@@@10.1016/j.colsurfa.2005.10.073@@@Wartelle LH, 2005, WATER RES, V39, P2869, DOI@@@10.1016/j.watres.2005.05.001@@@Wu CH, 2000, COLLOID SURFACE A, V166, P251, DOI@@@10.1016/S0927-7757(99)00404-5@@@Zhu MX, 2005, J HAZARD MATER, V120, P163, DOI@@@10.1016/j.jhazmat.2004.12.029@@@邹献中, 1999, 博士论文@@@武汉大学, 1994, 无机化学, P958@@@魏振枢, 1998, 化工环保, V19, P30 [publication_29] => ACTA CHIM SINICA [end_page] => 778 [abstract_en] => Adsorption properties of Cr(VI) on Mg-Al hydrotalcite-like compounds (HTlc) were studied. The influences of initial solution pH, additives of inorganic electrolytes, NaCl, NaNO3, Na2SO4 and Na3PO4, and organic ligands, EDTA and citric acid on the adsorption of Cr(VI) were investigated, and the adsorption mechanism was discussed in combination with the results of IR and XRD experiments. It was found that Mg-Al HTlc showed good adsorption ability for Cr(VI) from solution, indicating that the use of HTlc as a promising inorganic sorbent for the removal of Cr(VI) from wastewater is possible. The adsorption kinetics and the adsorption isotherms of Cr(VI) on the HTlc can be described by the pseudo-second order kinetic and Langmuir isotherm, respectively. With increasing pH, the adsorption amount decreased. The additives of inorganic electrolytes, NaCl, NaNO3, Na2SO4 and Na3PO4, and organic ligands, EDTA and citric acid, could obviously restrain the adsorption of Cr(VI) on the HTlc, and the orders of the restraining ability on the adsorption are Na3PO4 >= Na2SO4 >= NaCl >> NaNO3 and citric acid > EDTA, respectively. The adsorption of Cr(VI) on the HTlc arose from the anion exchange in the interlayer space and the adsorption on the external surface, respectively. Furthermore, the adsorption layer of Cr(VI) on the external surface may be divided into two layers: the inner-sphere surface complexes arising from the chemical binding and the outer-sphere surface complexes arising from the electrostatic interaction. [researcherID] => SDU, ERI/G-8937-2016; SDU, Environ Res/P-4462-2015; sdu, eri/O-2991-2015 [orcID] => SDU, ERI/0000-0003-2503-7398; [author_in] => [Zang, Y.-B] Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China@@@[ Hou, W.-G] Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China, Environment Research Institute, Shandong University, Jinan 250100, China@@@[ Wang, W.-X] Environment Research Institute, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 773 [author_en] => Zang, YB; Hou, WG; Wang, WX [volume] => 65 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => hydrotalcite-like compound; layered double hydroxide; chromium(VI);; adsorption [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => LAYERED DOUBLE HYDROXIDES; AQUEOUS-SOLUTION; WASTE-WATER; REMOVAL; SORPTION; CR(VI); CHROMATE; DYE [publication_iso] => Acta Chim. Sin. [format_title_en] => ac05877f986856e166458adb3bb7ac4a-1947223303 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 23 [email] => wghou@sdu.edu.cn [cite_awos] => 34 [wos_No] => WOS:000246715600001 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Adsorption-desorption of chromium(VI) on Mg-Al hydrotalcite-like compounds part I. Adsorption [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => ,adsorption,layereddoublehydroxide,hydrotalcitelikecompound,chromiumvi [jl_keyword_cn] => 铬vi,吸附,类水滑石,双层金属氢氧化物 [jl_clc] => o645 [jl_publisher] => sciencechinapress [author_id] => 21153,24236 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 3 [name] => 王文兴 [irtag] => 0 [t_index] => 0 [person_id] => 24236 ) [1] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 2 [name] => 侯万国 [sys_author_id] => Array ( [0] => 24236 [1] => 21153 ) [irtag] => 0 [t_index] => 0 [person_id] => 21153 ) ) [company_id] => 0,39,64,188 [sys_subject_sort] => 0,0,0 [college_parent_id] => 39,64,188 [company_test] => Array,Array,Array [sys_author_id_arr] => 21153侯万国,24236王文兴 [cscd_No] => CSCD:2874544 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 双层金属氢氧化物,hydrotalcitelikecompound,layereddoublehydroxide,吸附,类水滑石,adsorption,铬vi,chromiumvi [sys_author_id] => 21153,24236 [format_cscd_No] => 43c16d00d4a8acc301407df4fda040b8-1927055732 [format_title_en_publication_en_pub_year] => 48b8514b6b5aca7c34e3f4fca08f553c76821999 [format_wos_No] => 8d5b6fb41f38716ebe4c8865377c8fe5-1184474206 [format_title_en_issn_pub_year] => e01a68748c4e36d342170f9a8f26c329-1739401608 [format_scopus_No] => 6a424a1f0ca20841e1433da8bd00a664-107236120 [standard_in] => Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China; Environment Research Institute, Shandong University, Jinan 250100, China [cauthor] => Hou, WG(wghou@sdu.edu.cn) [datebase] => Scopus [cite_scopus] => 15 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-80052801664 [id] => WQ5HvmUBFjIhTVEbZSTq [tags] => 0 ) [9] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 以N-烷基咔唑作为电子给体和共轭桥中心,二米基硼作为端基电子受体,合成了两个V形A-π-D-π-A型新化合物:3,6-二-N-丁基-咔唑-carbazole,BBTC}和3,6-二[(E)-(4-二米基硼)苯乙烯基]-N-己基-咔唑,.这两个化合物在蓝绿光波段都有较强的荧光发射.光谱数据表明,扩大共轭... [keyword_cn] => 咔唑衍生物;有机硼化合物;V形分子;荧光 [article_id] => 489275,249260,328450,663847,33879,648086 [clc] => O627.4;O641.4 [author_jg] => [王伟] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[刘志强] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[曹笃霞] 济南大学材料科学与工程学院, 济南, 山东 250022, 中国.@@@[邓敏智] 中国科学院上海有机化学研究所, 中科院有机氟化学重点实验室, 上海 200032, 中国 [format_title_cn_publication_cn_pub_year] => 4f38c086ccd39da8091d401ced34922c2010258390 [hints] => 25 [issue] => 14 [sys_level_num] => 2_3 [sys_jg_type] => 10,3,5,8 [format_issn_issue_page_pub_year] => 3639c17564b0c85b6e99fc1ca4000862251091718 [source_type] => 351 [pub_year] => 2005 [pub_date] => JUL 28 [pages] => 6 [from_id] => 76,75,73,80,78,85 [author_cn] => 王伟,方奇,刘志强,曹笃霞,邓敏智 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33749133416&partnerID=40&md5=ecdb7e132a4da44f0b38086d104368bd [publication_cn] => 化学学报 [title_cn] => V形咔唑衍生物的合成及荧光性质 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 93c38d1a7b33704aa473ab5a570850e91255186535 [page] => 1323-1328+1242 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [fund_No] => 中国科学院上海有机化学研究所有机氟化学重点实验室基金资助项目; 国家自然科学基金; 高等学校博士点基金 [check_3Y] => 4 [language] => Chinese [delivery_No] => 950KX [format_title] => 4bb46c316842af4c0937fbe52b1f2cc01263560621 [cauthor_ad] => [Wang, W]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China. [author_fn] => Wang, W; Fang, Q; Lui, ZQ; Cao, DX; Deng, MZ [reference] => BUUHOI NP, 1951, J AM CHEM SOC, V73, P98, DOI 10.1021/ja01145a036@@@[曹笃霞 Cao Duxia], 2004, [化学学报, Acta Chemical Sinica], V62, P225@@@CAO DX, 2003, J ORG CHEM, P3628@@@Entwistle CD, 2002, ANGEW CHEM INT EDIT, V41, P2927, DOI@@@10.1002/1521-3773(20020816)41:16<2927::AID-ANIE2927>3.0.CO;2-L@@@FANG Q, 1996, ACTA CRYSTALLOGR, V52, P2274@@@GLOGOWSKI ME, 1981, J ORGANOMET CHEM, V218, P137, DOI@@@10.1016/S0022-328X(00)86094-5@@@@@@Lakowicz J. R., 1983, PRINCIPLES FLUORESCE, P190@@@Liu ZQ, 2004, ORG LETT, V6, P2933, DOI 10.1021/ol048984a@@@Liu ZQ, 2003, CHEM-EUR J, V9, P5074, DOI 10.1002/chem.200304833@@@REYNOLDS GA, 1975, OPT COMMUN, V13, P222, DOI@@@10.1016/0030-4018(75)90085-1@@@Yuan Z, 2000, J SOLID STATE CHEM, V154, P5, DOI 10.1006/jssc.2000.8803 [publication_29] => ACTA CHIM SINICA [end_page] => 1328 [abstract_en] => Two new V-shaped A-pi-D-pi-A type compounds, N-butyl-3,6-bis{(E)-2-[5-(dimesitylboryl)thiophen-2-yl]vinyl}carbazole (BBTC) and N-hexyl-3,6-bis[(E)-4-(dimesitylboryl)styryl]-carbazole (BBSC), with trivalent boron and carbazole as electron acceptor and the core of pi-conjugated bridge respectively, were synthesized. All these carbazole derivatives can emit strong blue-green fluorescence either in solution or in solid state. Both the absorption and emission band have been greatly red-shifted when trivalent boron was introduced at the terminal as electron acceptor or the phenyls in pi-conjugated bridge were replaced by thienyls. [orcID] => Liu, Zhiqiang/0000-0001-7863-1759 [author_in] => [Wang, W] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Fang, Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China, Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China@@@[ Liu, Z.-Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Cao, D.-X] College of Materials and Engineering, Jinan University, Jinan 250022, China@@@[ Deng, M.-Z] Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China [publication_type] => J [begin_page] => 1323 [author_en] => Wang, W; Fang, Q; Lui, ZQ; Cao, DX; Deng, MZ [volume] => 63 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => pi; carbazole derivative; organoboron compound; V-shaped molecule; fluorescence [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => 2-PHOTON-EXCITED FLUORESCENCE; OPTICAL-PROPERTIES; SINGLE-PHOTON; BORON [publication_iso] => Acta Chim. Sin. [format_title_en] => f8c0f5e2196e9edc99bdd0b3f61b3087614513863 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 11 [email] => fangqi@icm.sdu.edu.cn [cite_awos] => 11 [wos_No] => WOS:000230857100014 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Synthesis and fluorescence of two V-shaped carbazole derivatives [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => vshapedmolecule,pi,organoboroncompound,carbazolederivative,fluorescence [jl_keyword_cn] => 荧光,v形分子,有机硼化合物,咔唑衍生物 [jl_clc] => o6274,o6414 [jl_publisher] => sciencepress [company_id] => 24,151 [sys_subject_sort] => 0,0 [college_parent_id] => 24,151 [company_test] => Array,Array [author_id] => 20672,22582,24212,24213,24211,24214 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 方奇 [irtag] => 7 [t_index] => 0 [person_id] => 20672 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 刘志强 [irtag] => 7 [t_index] => 0 [person_id] => 22582 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 王伟 [irtag] => 7 [t_index] => 0 [person_id] => 24211 ) [3] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 王伟 [irtag] => 7 [t_index] => 0 [person_id] => 24212 ) [4] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 王伟 [irtag] => 7 [t_index] => 0 [person_id] => 24213 ) [5] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 王伟 [irtag] => 7 [t_index] => 0 [person_id] => 24214 ) ) [sys_author_id_arr] => 20672方奇,22582刘志强 [cscd_No] => CSCD:2111716 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => fluorescence,v形分子,vshapedmolecule,咔唑衍生物,有机硼化合物,organoboroncompound,pi,carbazolederivative,荧光 [sys_author_id] => 20672,22582 [format_cscd_No] => 0672df6924e6f1cae0a0e2f659c74a0d-2108726319 [format_title_en_publication_en_pub_year] => 1373cc183f94f5bf034558497829146d1788834477 [format_wos_No] => 8ccbba2b0234c7292c9657a73338880e626727698 [format_title_en_issn_pub_year] => 331cd7402d293ab9ace086285d61b1a1928876829 [format_scopus_No] => b5089290948fec7eb90d20268571d102-215191276 [standard_in] => State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China; Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China; College of Materials and Engineering, Jinan University, Jinan 250022, China [datebase] => Scopus [cite_scopus] => 12 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-33749133416 [id] => 3Q1EvmUBFjIhTVEbKGBy [tags] => 0 ) [10] => Array ( [batch2] => 1,2,6 [batch] => 3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 从结晶化学角度出发,研究了硫氰酸汞镉(简写为CMTC)结构中的基本结构单元即HgS4和CdN4的结晶方位与晶体各族晶面间的对应关系.在对CMTC的生长溶液结构测定和推理基础上,提出该晶体生长基元的结构形式和生长基元向各族晶面上堆积的规律,进而讨论了该晶体生长习性的形成机理.实验发现,CMTC的生长溶液中存在着与晶体结构中相同的基团即阴离子多面体生长基元,随着生长条件的变化,生长基元的维度有所不同,不同维度的生长基元往各族晶面上的堆积速率也发生相应改变,从而解释了CMTC的生长习性和晶体形貌的多变性. [keyword_cn] => 硫氰酸汞镉晶体;溶液结构;生长基元;生长习性;形貌;紫外倍频晶体;晶体生长;非线性光学材料; [clc] => O781 [author_jg] => [姜雪宁;袁多荣;许东;吕孟凯;郭世义;于文涛;张光辉;方奇]山东大学晶体材料研究所,,中国 [format_title_cn_publication_cn_pub_year] => 8aa7d38f572ccdf3ab554cf81750b4a1762398303 [from_id] => 76,80,73,85 [issue] => 5 [sys_level_num] => 2_1 [sys_jg_type] => 0,5 [source_type] => 351 [pub_year] => 2001 [article_id] => 496043,333198,237794,82387 [pages] => 5 [hints] => 19 [author_cn] => 姜雪宁;袁多荣;许东;吕孟凯;郭世义;于文涛;张光辉;方奇 [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/200105/5250720.html [publication_cn] => 化学学报 [title_cn] => 紫外倍频晶体硫氰酸汞镉的生长习性与形成机理研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 5fa862b7d39d42aa52084649d6c140171996413521 [hb_type] => 2 [jl_publication_cn] => 化学学报 [jl_country] => 中国 [jl_keyword_cn] => 形貌,非线性光学材料,,晶体生长,生长习性,硫氰酸汞镉晶体,溶液结构,生长基元,紫外倍频晶体 [jl_clc] => o781 [author_in] => [Xue-Ning, J] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Duo-Rong, Y] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Dong, X.U] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Meng-Kai, L.U] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Shi-Yi, G.U.O] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Wen-Tao, Y.U] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Guang-Hui, Z] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China@@@[ Qi, F] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China [author_id] => 24824,20672,25389,20981 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 8 [name] => 方奇 [irtag] => 0 [t_index] => 0 [person_id] => 20672 ) [1] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 5 [name] => 郭世义 [irtag] => 0 [t_index] => 0 [person_id] => 20981 ) [2] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 3 [name] => 许东 [irtag] => 0 [t_index] => 0 [person_id] => 24824 ) [3] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 7 [name] => 张光辉 [sys_author_id] => Array ( [0] => 20672 [1] => 20981 [2] => 24824 [3] => 25389 ) [irtag] => 0 [t_index] => 0 [person_id] => 25389 ) ) [company_id] => 24,0,151 [sys_subject_sort] => 0,0 [college_parent_id] => 24,151 [company_test] => Array,Array [sys_author_id_arr] => 20672方奇,20981郭世义,24824许东,25389张光辉 [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 形貌,溶液结构,硫氰酸汞镉晶体,生长习性,紫外倍频晶体,生长基元,非线性光学材料,晶体生长 [hb_batch] => grant_no [cite_wos] => 10 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 0 [language] => Chinese [delivery_No] => 436AD [cauthor_ad] => [Jiang, XN]Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China. [format_title] => 75f3825c6666c75f5ccee6c85bb6bd4e-372958533 [author_fn] => Jiang, XN; Yuan, DR; Xu, D; Lu, MK; Guo, SY; Yu, WT; Zhang, GH; Fang, Q [format_title_en_issn_pub_year] => bb144d6bb44dedd1e86c3e0b6b7e6b281520083270 [datebase] => Scopus [format_scopus_No] => dd87f922c34ac0eb424d59167985443a-1950249190 [publication_29] => ACTA CHIM SINICA [end_page] => 728 [abstract_en] => Growth habits of cadmium mercury thiocyanate crystal (CMTC) in solutions and the relation between its structure and morphology have been studied. On the basis of the structural investigation of CMTC growing solution, the growth units of CMTC crystal HgS4 and CdN4 tetrahedra, which have the same coordination polyhedron structures as the anion groups in the crystal lattice, are proposed. The growth mechanisms of various morphologies of CMTC crystal are well explained. [article_dt] => Article [publication_type] => J [begin_page] => 724 [author_en] => Jiang, XN; Yuan, DR; Xu, D; Lu, MK; Guo, SY; Yu, WT; Zhang, GH; Fang, Q [volume] => 59 [publisher] => SCIENCE PRESS [get_data] => 2018-08-29 [keyword_en] => cadmium mercury thiocyanate crystal (CMTC); solution structure; growth; units; crystal habit and morphology [page] => 724-728 [keyword_plu] => COMPLEX CRYSTAL [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => b560df329fb8d38ca66c190e310181d256429831 [format_title_en] => b4943e9870fd91f8bfa646fb0cdd14f22146315974 [publisher_city] => BEIJING [cauthor_order] => 1 [hx_id] => 2378,2371 [reference_No] => 7 [format_issn_issue_page_pub_year] => 3d1e3a8816dea3195f36c640638b68b31754901974 [cite_awos] => 10 [wos_No] => WOS:000168913600018 [format_wos_No] => 842964a34c0181b1e98313c9a291c00a1133012845 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Jiang, XN [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-0442327555 [title_en] => Growth habits and mechanism of cadmium mercury thiocyanate crystal for laser diode frequency doubling [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_article_dt] => 期刊论文 [jl_author_test] => usureu0,unameuu90edu4e16u4e49,uirauthortype0,uirtstag0,unameuu65b9u5947,upersonid24824,unameuu4e8eu6587u6d9b,uuindex8,upersonid20672,uuindex3,upersonid25191,uuindex6,uuindex7,utindex0,uirtag6,uirinspecttag0,uirtag0,uuindex5,uirtypical3,upersonid25389,unameuu5f20u5149u8f89,upersonid20981,unameuu8bb8u4e1c [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 中国 [jl_company_test] => uircu0,uorgidu24,uparentidu24,unameuu6676u4f53u6750u6599u7814u7a76u6240,ulevelu1 [jl_keyword_en] => units,crystalhabitandmorphology,cadmiummercurythiocyanatecrystalcmtc,growth,solutionstructure [sys_author_in_last_arr] => china [jl_publisher] => sciencepress [sys_author_id] => [id] => 4QkwvmUBFjIhTVEbnLlv [tags] => 0 ) [11] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3241,3254,3243,3252 [tag] => 0 [abstract_cn] => 采用耗散颗粒动力学(DPD)方法在介观层次上模拟了表面活性剂烷基苯磺酸盐在油,水界面的排布行为,考察了分子结构、浓度、盐度、油相等因素对表面活性剂界面密度和界面效率的影响,并探讨了利用表面活性剂复配协同效应提高界面活性的理论机制、分子模拟给出的分子水平的微观信息为强化采油技术中配方筛选和表面活性剂的有效应用提供指导. [keyword_cn] => 耗散颗粒动力学模拟;界面密度;界面效率;烷基苯磺酸盐; [clc] => TE357.46 [author_jg] => [李振泉] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.@@@[曹绪龙] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.@@@[宋新旺] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.@@@[崔晓红] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.@@@[何秀娟] 山东大学化学与化工学院, 胶体与界面教育部重点实验室, 济南, 山东 250100, 中国.@@@[李英] 山东大学化学与化工学院, 胶体与界面教育部重点实验室, 济南, 山东 250100, 中国.@@@[马保民] 山东大学化学与化工学院, 胶体与界面教育部重点实验室, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 3bd82ec1f23ceb55ae8fe9bb03391eaf-337526265 [from_id] => 76,75,73,80,78,85 [issue] => 24 [sys_level_num] => 2_1 [sys_jg_type] => 11,10,5 [source_type] => 351 [pub_year] => 2007 [article_id] => 620591,323864,483511,33887,238487,662743 [pages] => 6 [hints] => 25 [author_cn] => 李振泉[2];何秀娟[1];李英[1];马保民[1];曹绪龙[2];宋新旺[2];崔晓红[2] [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-78751564648&partnerID=40&md5=39e2caaddcb270a8be1c3fdd9c7efb49 [publication_cn] => 化学学报 [title_cn] => 烷基苯磺酸盐在油水界面行为的介观模拟 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => efb04f2b4a431944a30a77d0b0b8fae4-2061735352 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 10 [fund_No] => 中石化重大先导试验项目(No.03003); 中石化重点项目(No.P04049)资助项目 [check_3Y] => 11 [language] => Chinese [delivery_No] => 252WW [format_title] => 1bb54e9d769bbd653e659e1e3deef2a4-563380810 [cauthor_ad] => [Li, ZQ]Shengli Oilfield, Geol Sci Res Inst, Dongying 257015, Peoples R China. [author_fn] => Li Zhen-Quan; He Xiu-Juan; Li Ying; Ma Bao-Min; Cao Xu-Long; Song Xin-Wang; Cui Xiao-Hong [reference] => Aleksey M, 2005, Phys. Chem. B, V109, P1210@@@Bresme F, 2003, J CHEM PHYS, V118, P4134, DOI 10.1063/1.1540090@@@Bresme F, 2004, LANGMUIR, V20, P5127, DOI 10.1021/la036026w@@@Conboy JC, 1998, LANGMUIR, V14, P6722, DOI 10.1021/la980132u@@@Dong FL, 2004, CHEM PHYS LETT, V399, P215, DOI@@@10.1016/j.cplett.2004.10.022@@@Groot RD, 2001, BIOPHYS J, V81, P725, DOI 10.1016/S0006-3495(01)75737-2@@@Groot RD, 1997, J CHEM PHYS, V107, P4423, DOI 10.1063/1.474784@@@HOOGERBRUGGE PJ, 1992, EUROPHYS LETT, V19, P155, DOI@@@10.1209/0295-5075/19/3/001@@@Hromadova M, 1994, J Phys Chem, V98, P11519@@@Li Y, 2005, J. Mol. Simul, V31, P1027@@@Rekvig L, 2003, LANGMUIR, V19, P8195, DOI 10.1021/la0346346@@@Richmond GL, 2002, CHEM REV, V102, P2693, DOI 10.1021/cr0006876@@@Watry MR, 2000, J AM CHEM SOC, V122, P875, DOI 10.1021/ja9917666@@@[燕永利 Yan Yongli], 2005, [化学学报, Acta Chemical Sinica], V63, P1686@@@[苑世领 YUAN ShiLing], 2006, [化学学报, Acta Chemical Sinica], V64, P1659@@@[翟利民 ZHAI LiMin], 2007, [化学学报, Acta Chemical Sinica], V65, P27 [publication_29] => ACTA CHIM SINICA [end_page] => 2808 [abstract_en] => With a simple coarse-grained model, the properties of sodium dodecylbenzene sulphonate (SDBS) adsorbed at the water/oil interface, has been investigated on a mesoscopic level by considering the variation of interfacial density using dissipative particle dynamics (DPD) simulation. Compared with sodium dodecyl sulphonate systems, sodium dodecylbenzene sulphonate are more efficient. An increase of surfactants interfacial concentration results in the increase of its interfacial density before reaching a full monolayer and appropriate salts make surfactant molecules adsorbed more at interface. It is beneficial to decrease interfacial tension if the hydrophobic chains of the surfactant and the oil have similar structure. The simulation conclusions are well consistent with the experimental results. Also with computer simulation method, we have observed that SDBS is not distributed homogeneously over the interface. Rather, the interfacial layer contains large cavities between SDBS clusters filled with water or oil clusters. When TX-100 molecules were introduced, clusters formed by nonionic surfactants filled SDBS cavities, thus decreased the interfacial tension to ultra low, even lower than 10(-3) mN.m(-1). This inhomogeneous distribution helps to enhance our understanding of the synergism interaction of the different surfactants. [author_in] => [Li, Z.-Q] Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015, China@@@[ He, X.-J] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China@@@[ Li, Y] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China@@@[ Ma, B.-M] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China@@@[ Cao, X.-L] Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015, China@@@[ Song, X.-W] Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015, China@@@[ Cui, X.-H] Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015, China [publication_type] => J [begin_page] => 2803 [article_dt] => Article [author_en] => Li, ZQ; He, XJ; Li, Y; Ma, BM; Cao, XL; Song, XW; Cui, XH [volume] => 65 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => dissipative particle dynamics; interfacial density; interfacial; efficiency; salt alkylbenzene sulphonate [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => DISSIPATIVE PARTICLE DYNAMICS; LIQUID/LIQUID INTERFACE; SURFACTANTS; SPECTROSCOPY; EFFICIENCY [publication_iso] => Acta Chim. Sin. [format_title_en] => d7c02b8ceb0fe57916250a2314b5fec3-626384257 [publisher_city] => BEIJING [pub_date] => DEC 28 [hx_id] => 2377,2378,2371 [reference_No] => 15 [email] => yingli@sdu.edu.cn [cite_awos] => 15 [wos_No] => WOS:000252479000001 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Mesoscopic simulation study on the behavior of salt alkylbenzene sulphonate adsorbed at oil/water interface [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => interfacialdensity,efficiency,saltalkylbenzenesulphonate,dissipativeparticledynamics,interfacial [jl_keyword_cn] => ,耗散颗粒动力学模拟,界面密度,界面效率,烷基苯磺酸盐 [jl_clc] => te35746 [jl_publisher] => sciencechinapress [author_id] => 21994 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 0 [name] => 李英 [sys_author_id] => Array ( [0] => 21994 ) [irtag] => 0 [t_index] => 0 [person_id] => 21994 ) ) [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => [cscd_No] => CSCD:3052875 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 耗散颗粒动力学模拟,烷基苯磺酸盐,interfacial,interfacialdensity,saltalkylbenzenesulphonate,界面效率,efficiency,dissipativeparticledynamics,界面密度 [sys_author_id] => 21994 [format_cscd_No] => ad64b5d3187a6d7640707a2e0e67a70d-866253841 [format_title_en_publication_en_pub_year] => 25e9b125e4a375b7565ea6f322bd4b2e-569873606 [format_wos_No] => 18713130369e4fb93b0c8ca77d9e9f88-1625778125 [format_title_en_issn_pub_year] => 774530244de70fee9bf8bc482f64e3cf1774622136 [format_scopus_No] => 5d07146e4647e438f77cc7ecb61feaaa331173739 [standard_in] => Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China; Geological Scientific Research Institute, Shengli Oilfield, Dongying 257015, China [cauthor] => Li, Y(yingli@sdu.edu.cn) [datebase] => Scopus [page] => 2803-2808 [cite_scopus] => 11 [format_issn_issue_page_pub_year] => 7fca5629ecfab03ecee0a646008b6d66-1755253878 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-78751564648 [id] => 8wozvmUBFjIhTVEbAoJx [tags] => 0 ) [12] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3252,3254,3241 [tag] => 0 [abstract_cn] => 应用密度泛函理论在B3LYP/6—311+G(d)水平上研究了硼碳团簇BnC2(n=1~6)的几何结构、生长机制和相对稳定性.计算结果表明,对于n=2-6的簇,平面多环状构型为最稳定的结构,其中C原子分布于环的顶点、有尽可能多的三配位硼原子和尽可能多的B—C键.碳原子作为杂原子倾向掺杂于团簇的顶点位置,它的掺杂不改变硼团簇的主体结构.与平面多环状结构相比,随着簇尺寸的增大,三维结构和线性链结构更不稳定.在低能线性结构中,C原子位于链两侧的第二个位置.计算的碎片分裂能、递增键能以及及HOMO—LUMO能隙表明,B4C2为幻数簇. [keyword_cn] => 硼碳团簇;掺杂;几何结构;稳定性;密度泛函理论; [clc] => O561.3 [author_jg] => [王若曦] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[张冬菊] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[朱荣秀] 山东大学理论化学研究所, 济南, 山东 250100, 中国.@@@[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => e995297ed940f390b87e07613e3c61311514183995 [from_id] => 75,78,73,80,85 [issue] => 19 [sys_level_num] => 2_1 [sys_jg_type] => 0,3,5 [source_type] => 351 [pub_year] => 2007 [article_id] => 238349,662752,33886,597894,324237 [pages] => 5 [hints] => 13 [author_cn] => 王若曦[1,2];张冬菊[1];朱荣秀[1];刘成卜[1] [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/200719/25534521.html [publication_cn] => 化学学报 [title_cn] => 硼碳团簇BnC2(n=1~6)的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => f5b372b2127d56c2448cdbe4efd7f16f-1174128540 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 9 [fund_No] => 国家重点基础研究发展计划(973计划)(No.2004CB719902); 国家自然科学基金(Nos.20473047,20633060,20773078); 山东警察学院(No.Y2005L03)资助项目 [check_3Y] => 11 [language] => Chinese [delivery_No] => 222PE [format_title] => d44ade5959194e6e1688b711f1504ccc1998160137 [cauthor_ad] => [Wang, RX]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [author_fn] => Wang Ruo-Xi; Zhang Dong-Ju; Zhu Rong-Xiu; Liu Cheng-Bu [reference] => Aselage TL, 2001, PHYS REV B, V64, DOI 10.1103/PhysRevB.64.054302@@@BECKER S, 1988, INT J MASS SPECTROM, V82, P287, DOI@@@10.1016/0168-1176(88)80021-1@@@Chuchev K, 2004, J PHYS CHEM A, V108, P5226, DOI 10.1021/jp040063u@@@Frisch M J, 2003, Gaussian 03, Revision B. 01@@@HAY PJ, 1985, J CHEM PHYS, V82, P299, DOI 10.1063/1.448975@@@HIRSCH G, 1987, J CHEM PHYS, V87, P6004, DOI 10.1063/1.453524@@@KNIGHT LB, 1989, J CHEM PHYS, V90, P690, DOI 10.1063/1.456148@@@KOUBA JE, 1970, J CHEM PHYS, V53, P3923, DOI 10.1063/1.1673861@@@Li GL, 2003, J PHYS CHEM A, V107, P5317, DOI 10.1021/jp034719f@@@Ma R, 2002, CHEM MATER, V14, P4403, DOI [10.1021/cm020630v,@@@10.1021/cm02063Ov]@@@[马文瑾 Ma Wenjin], 2004, [化学学报, Acta Chemical Sinica], V62, P1785@@@MARTIN JML, 1993, J CHEM PHYS, V99, P12, DOI 10.1063/1.465792@@@McColm I. J., 1990, CERAMIC HARDNESS@@@McIlroy DN, 2001, APPL PHYS LETT, V79, P1540, DOI 10.1063/1.1400079@@@MIYAMOTO Y, 1994, PHYS REV B, V50, P18360, DOI 10.1103/PhysRevB.50.18360@@@Presilla-Marquez JD, 1999, J CHEM PHYS, V110, P5702, DOI@@@10.1063/1.478468@@@PresillaMarquez JD, 1996, J CHEM PHYS, V105, P3398, DOI 10.1063/1.472225@@@THOMSON C, 1973, J CHEM PHYS, V58, P216, DOI 10.1063/1.1678908@@@Van Orden A, 1998, J. Chem. Rev, V98, P2313@@@WANG CR, 1995, CHEM PHYS LETT, V237, P463, DOI@@@10.1016/0009-2614(95)00355-8@@@Wang RX, 2005, CHEM PHYS LETT, V411, P333, DOI@@@10.1016/j.cplett.2005.06.055@@@WOOD C, 1984, PHYS REV B, V29, P4582, DOI 10.1103/PhysRevB.29.4582@@@Xu FF, 2004, J PHYS CHEM B, V108, P7651, DOI 10.1021/jp037669n@@@Yamamoto H, 2003, NUCL INSTRUM METH B, V206, P42, DOI@@@10.1016/S0168-583X(03)00713-4@@@Zhan C G, 1997, Phys. Chem. A, V101, P591@@@葛茂发, 1996, 高等学校化学学报, V17, P1458@@@葛茂发, 1997, 高等学校化学学报, V18, P1838 [publication_29] => ACTA CHIM SINICA [end_page] => 2096 [abstract_en] => The geometrical structures, growth modes, and relative stabilities of boron-carbon clusters BnC2 (n = 1 similar to 6) have been investigated by performing density functional theory calculations at B3LYP/6-311 + G(d) level. The calculated results show that the planar multi-cyclic geometries for n=2 similar to 6 with C atoms at the apexes with the most B-C bonds and the most three-coordination boron atoms are the most stable structures. It is also shown that the C atoms prefer the apexes of the rings, which does not change the frame structures of the B clusters. The compact 3D structures and the linear isomers, however, are energetically more unfavorable with the increasing size. In the energetically lowest linear isomers, the carbon atoms prefer the second positions of the chains. The calculated disproportionation energies, binding energies and HOMO-LUMO gaps show that the B4C2 is a magic cluster. [author_in] => [Wang, RX; Zhang, DJ; Zhu, RX; Liu, CB]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China.@@@[Wang, RX; Zhang, DJ; Zhu, RX; Liu, CB] Shandong Police Coll, Crim Technol Dept, Jinan 250014, Peoples R China. [publication_type] => J [begin_page] => 2092 [article_dt] => Article [author_en] => Wang, RX; Zhang, DJ; Zhu, RX; Liu, CB [volume] => 65 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => boron-carbon cluster; doping; geometric structure; stability; density; functional theory [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => AB-INITIO; VIBRATIONAL-SPECTRA; CARBIDE; STABILITY; MOLECULES; ARGON; ION; BC2; CNB [publication_iso] => Acta Chim. Sin. [format_title_en] => 6608119b51cc1daed5daf3601f176c3a1091371391 [publisher_city] => BEIJING [pub_date] => OCT 14 [hx_id] => 2377,2371 [reference_No] => 27 [email] => cbliu@sdu.edu.cn [cite_awos] => 14 [wos_No] => WOS:000250308600002 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Theoretical study of boron-carbon clusters BnC2 (n=1 similar to 6) [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => density,stability,functionaltheory,doping,geometricstructure,boroncarboncluster [jl_keyword_cn] => ,密度泛函理论,硼碳团簇,几何结构,掺杂,稳定性 [jl_clc] => o5613 [jl_publisher] => sciencepress [company_id] => [author_id] => 25363,26194 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 张冬菊 [irtag] => 7 [t_index] => 0 [person_id] => 25363 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 朱荣秀 [irtag] => 7 [t_index] => 0 [person_id] => 26194 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:2933936 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 几何结构,硼碳团簇,密度泛函理论,density,稳定性,掺杂,stability,functionaltheory,doping,geometricstructure,boroncarboncluster [sys_author_id] => [format_cscd_No] => fc74e2a53b5b354e02ed407f691d9e12-2038614561 [format_title_en_publication_en_pub_year] => 0d7acbc0b898a5cd45bab2c176653203-521561597 [format_wos_No] => 58cb7990d16a597a326a47084ab10e95477009357 [format_title_en_issn_pub_year] => e8273bfcc1802d4a5a812f17fe73b8cc1979494693 [id] => 8gozvmUBFjIhTVEbAoJx [tags] => 0 ) [13] => Array ( [batch2] => 1,2,6 [batch] => 3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 用最大气泡压力法测定了十六烷基三甲基溴化铵(CTAB)水溶液的动态表面张力,研究了CTAB水溶液表面吸附的动力学及其影响因素.结果表明,吸附过程由初始的扩散控制经混合控制过渡到势垒控制.扩散控制吸附速率快,时间短;势垒控制速率慢,时间长,吸附势垒一般为4~10kJ@mol-1.温度升高,动态表面张力减小,但吸附机理不变;无机盐或醇类的加入对势垒值影响不大,但对扩散控制步骤的影响较大. [keyword_cn] => 动态表面张力;吸附动力学;CTAB;动态表面张力;表面活性剂;十六烷基三甲基溴化铵;水溶液;表面吸附机制; [clc] => O647.1 O647.31 [author_jg] => [柴金岭;李干佐;李英;徐桂英;马忠娟]山东大学,中国.@@@[张高勇]中国日用化学工业研究院,,中国 [format_title_cn_publication_cn_pub_year] => 262326157fd5a65cd66565796ee09893-1031014471 [from_id] => 76,80,73,85 [issue] => 12 [sys_level_num] => 2_1 [sys_jg_type] => 3,5 [source_type] => 351 [pub_year] => 2001 [article_id] => 496138,82195,333211,239515 [pages] => 4 [hints] => 4 [author_cn] => 柴金岭[1];张高勇[2];李干佐[1];李英[1];徐桂英[1];马忠娟[1] [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/200112/5912514.html [publication_cn] => 化学学报 [title_cn] => CTAB水溶液表面的吸附动力学 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 1c3b52761ced7e1a44781df788640946-314942219 [hb_type] => 2 [jl_publication_cn] => 化学学报 [jl_country] => 中国 [jl_keyword_cn] => ,十六烷基三甲基溴化铵,ctab,表面吸附机制,动态表面张力,吸附动力学,表面活性剂,水溶液 [jl_clc] => o6471o64731 [author_in] => [Chai, J.-L] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100, China, China Research Institute of Daily Chemical Industry, Taiyuan, 030001, China@@@[ Zhang, G.-Y] China Research Institute of Daily Chemical Industry, Taiyuan, 030001, China@@@[ Li, G.-Z] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100, China@@@[ Li, Y] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100, China@@@[ Xu, G.-Y] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100, China@@@[ Ma, Z.-J] Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100, China [company_id] => [author_id] => 21993,21994 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 李英 [irtag] => 7 [t_index] => 0 [person_id] => 21993 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 李英 [irtag] => 7 [t_index] => 0 [person_id] => 21994 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 9 [check_3Y] => 4 [language] => Chinese [delivery_No] => 504QQ [format_title] => c8048b25827c8073c15129e6385defc5-1532016108 [cauthor_ad] => [Li, Y]Shandong Univ, State Educ Minist, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China. [author_fn] => Chai, JL; Zhang, GY; Li, GZ; Li, Y; Xu, GY; Ma, ZJ [cite_wanfang] => 10 [format_title_en_issn_pub_year] => a3dbc785d9ae76dff69cff42d88d790c-552398941 [datebase] => Scopus [format_scopus_No] => 5a1d9de6129a6dc7614eddfab79f7617-2109855973 [publication_29] => ACTA CHIM SINICA [end_page] => 2125 [abstract_en] => Maximum bubble pressure method (MBPM) was used to determine the dynamic surface tension of aqueous solution of cetyltrimethylammonium bromide (CTAB). Adsorption kinetics of CTAB at the air/water interface has been studied. Effects of temperature, concentration of CTAB, additives on the adsorption kinetics were also investigated. The results show that at beginning, the adsorption process is controlled by a diffusion step; whereas toward the end, it changes to an activation mechanism with an adsorption barrier of between 4 and 10 kJ mol(-1). It seems that this burrier does not depend on the temperature and additives. Additives influence diffusion process significantly. [publication_type] => J [begin_page] => 2122 [article_dt] => Article [author_en] => Chai, JL; Zhang, GY; Li, GZ; Li, Y; Xu, GY; Ma, ZJ [volume] => 59 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => dynamic surface tension; adsorption kinetics; CTAB [page] => 2122-2125 [keyword_plu] => TENSION [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 09d33acae024a345db9655526c8d566b-1614277033 [cite_scopus] => 9 [format_title_en] => e12d6d8254b1e43317474ba3b53a954b-1289996033 [publisher_city] => BEIJING [cauthor_order] => 4 [hx_id] => 2378,2371 [reference_No] => 11 [format_issn_issue_page_pub_year] => 467ad713e645ae0ebf9073c73b3c34dc-360417749 [cite_awos] => 9 [wos_No] => WOS:000172867700016 [format_wos_No] => 0909592b4f3b6a9854f65deda225caab1345449871 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Li, Y [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [scopus_No] => 2-s2.0-0442280410 [standard_in] => Key Laboratory for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100, China; China Research Institute of Daily Chemical Industry, Taiyuan, 030001, China [title_en] => Adsorption kinetics of cetyltrimethylammonium bromide at the air/water interface [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_article_dt] => 期刊论文 [jl_author_test] => uirtypical3,uirtstag0,upersonid21994,uuindex0,usureu0,unameuu674eu82f1,utindex0,uirtag6,uirinspecttag0,upersonid21993,uirauthortype0 [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 中国,中国 [jl_keyword_en] => dynamicsurfacetension,ctab,adsorptionkinetics [sys_author_in_last_arr] => china [jl_publisher] => sciencechinapress [sys_author_id] => [id] => IQkwvmUBFjIhTVEbmrnE [tags] => 0 ) [14] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 通过表面张力和胶束聚集数的测定,研究了聚乙烯吡咯烷酮(PVP)与两性表面活性剂十四烷基甜菜碱(C14BE)之间的相互作用,结果表明,PVP与C14BE可通过其分子间的疏水作用和极性基团间的静电力形成PVP大分子/表面活性剂聚集体,因此,混合溶液的表面张力-浓度曲线表现出两个转折点,C14BE的胶束聚集数随PVP浓度增大而减小。 [keyword_cn] => 聚乙烯吡咯烷酮;十四烷基甜菜碱;聚集体;复合物; [clc] => O647.2 O633.22 [author_jg] => [徐桂英;隋卫平]山东大学胶体与界面化学国家教委开放实验室,中国 [format_title_cn_publication_cn_pub_year] => 9864aa849a845ede241b6be3022c5c67-809052702 [from_id] => 76,80,78,73,85 [issue] => 12 [sys_level_num] => 2_1 [sys_jg_type] => 0,5 [source_type] => 351 [pub_year] => 1997 [article_id] => 334870,620580,84567,498295,155187 [pages] => 6 [hints] => 13 [author_cn] => 徐桂英;隋卫平 [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/199712/2771580.html [publication_cn] => 化学学报 [title_cn] => PVP与C14BE之间的相互作用 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e2761b13651c20a3905957f08f3cf400240368162 [hb_type] => 2 [jl_publication_cn] => 化学学报 [jl_country] => 中国 [jl_keyword_cn] => 聚乙烯吡咯烷酮,,聚集体,十四烷基甜菜碱,复合物 [jl_clc] => o6472o63322 [author_in] => [Xu, G.-Y] Key Laboratory for Colloid and Interface Chemistry of State Education Commission, Shandong University, Jinan, 250100, China@@@[ Sui, W.-P] Key Laboratory for Colloid and Interface Chemistry of State Education Commission, Shandong University, Jinan, 250100, China@@@[ Li, G.-Z] Key Laboratory for Colloid and Interface Chemistry of State Education Commission, Shandong University, Jinan, 250100, China [company_id] => 0,0,0,0,0,0,0,0 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 9 [check_3Y] => 2 [language] => Chinese [delivery_No] => YX408 [format_title] => 6f85d6e5c3165547c0a2888b03859683-1844101814 [cauthor_ad] => [Xu, GY]Shandong Univ, State Educ Commiss, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China. [author_fn] => Xu, GY; Sui, WP; Li, GZ [format_title_en_issn_pub_year] => a4221f7c5ca3ff901a03f26b1aaddfdc-991019346 [datebase] => Scopus [format_scopus_No] => c215f75781cb0b7bfd28f009a9bfc4371336070766 [publication_29] => ACTA CHIM SINICA [end_page] => 1184 [abstract_en] => The interaction between polyvinylpyrrolidone ( PVP) and zwitterionic surfactant tetradecylbetaine(C14BE) has been investigated by means of surface tension and time resolved fluorescence measurements. It is shown that the addition of PVP results in a decrease of the aggregation number of C14BE and an appearance of two transition points in the surface tension - concentration curve. The results indicate that PVP associates with C14BE to form aggregate by the hydrophobic effect between hydrophobic groups and electrostatic force between polar head groups of C14BE and PVP. [publication_type] => J [begin_page] => 1179 [article_dt] => Article [author_en] => Xu, GY; Sui, WP; Li, GZ [volume] => 55 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [page] => 1179-1184 [keyword_plu] => WATER; POLYVINYLPYRROLIDONE [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 82769698d6f9df368a66d83b7706e915950901026 [cite_scopus] => 4 [format_title_en] => 56e917d10ec17f5a01477ab787d9aa3b-1777023570 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2378,2371 [reference_No] => 13 [format_issn_issue_page_pub_year] => eb68b1ab085f38c91316b38ce1d6a0f6-824740246 [cite_awos] => 9 [wos_No] => WOS:000072037000006 [format_wos_No] => f0e7c4f9f95ebb4cb07f1e75a42a221c1018302053 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Xu, GY [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Key Laboratory for Colloid and Interface Chemistry of State Education Commission, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33749826744 [title_en] => The interaction between PVP and C14BE [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => vgkwvmUBFjIhTVEbgrLf [tags] => 0 ) [15] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 研究了新的含 3 6个丁氧基偶氮苯介晶基元的二代光致变色液晶树枝状碳硅烷 (D2 )在氯仿、四氢呋喃溶液中的光强 ,吸收光强 ,摩尔消光系数 ,最大吸收波长 ,量子产率 ,活化能 ,异构转换率 ,光回复异构化反应平衡常数 ,反 -顺光异构化反应速率常数 ,光回复异构化正 /逆和热回复异构化反应速率常数 [keyword_cn] => 光致变色液晶树状大分子;光电信息功能材料;反顺光异构化;光回复异构;热回复异构;反/顺异构组分比;活化能 [article_id] => 26634,249262,490019,661665,330441,629389 [clc] => O753.2 [author_jg] => [张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 6aa548e34d4a83f069437161b71f254f [hints] => 46 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 11,10,3,5 [format_issn_issue_page_pub_year] => 19ab6c5dbf7d63b9caf00565c3930291 [source_type] => 351 [pub_year] => 2004 [pub_date] => FEB 14 [pages] => 7 [from_id] => 76,75,73,80,78,85 [author_cn] => 张其震,刘建强,张静智 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-18444368897&partnerID=40&md5=9bcad671ec7091720264df3960688091 [publication_cn] => 化学学报 [title_cn] => 二代光致变色液晶树枝状碳硅烷的光化学研究——端基含36个丁氧基偶氮苯介晶基元 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 26981317e147d8e7ddbbccc3dbfbd3fd [page] => 317-323 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 9 [fund_No] => 国家自然科学基金; 山东省自然科学基金; 中国科学院高分子物理重点实验室 [check_3Y] => 1 [language] => Chinese [delivery_No] => 773BK [format_title] => 389a1681bd495ab732a6c82ec648f59f1327318726 [cauthor_ad] => [Zhang, QZ]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Zhang, QZ; Liu, JQ; Zhang, JZ [reference] => Archut A, 1998, J AM CHEM SOC, V120, P12187, DOI 10.1021/ja9822409@@@@@@CHEN X, 1997, MOL CRYST LIQ CRYST, V295, P93@@@IKEDA T, 1995, SCIENCE, V268, P1873, DOI 10.1126/science.268.5219.1873@@@Junge DM, 1999, J AM CHEM SOC, V121, P4912, DOI 10.1021/ja990387+@@@Nagasaki T, 1997, CHEM LETT, P717, DOI 10.1246/cl.1997.717@@@NIEMANN M, 1993, MAKROMOL CHEM, V194, P1169@@@PERKAMPUS HH, 1986, UV VIS SPEKTROSKOPIE, P158@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P1108@@@[张其震 Zhang Qizhen], 2003, [化学学报, Acta Chemical Sinica], V61, P416@@@[张其震 Zhang Qizhen], 2002, [化学学报, Acta Chemical Sinica], V60, P2232@@@张其震, 1997, 高等学校化学学报, V18, P158@@@张静智, 1997, 化学学报, V55, P930@@@张其震, 1996, 高分子学报, P121 [publication_29] => ACTA CHIM SINICA [end_page] => 323 [abstract_en] => The photochemical behavior of a new photochromic liquid crystalline (LC) carbosilane dendrimer of the second generation (D2) in CHCl3 and THF was described. Thirty-six 4-butoxyazobenzene mesogenic fragments were attached in its periphery. The intensity of light, intensity of absorption light, molar extinction coefficient, maximum absorption wave length, quantum yield, activation energy, reaction rate constant of trans/cis photochemical isomerization, photochemical back-isomerization, thermal back-isomerization and the equilibrium constant of photochemical back-isomerization reaction were discussed. [author_in] => [Zhang, Q.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Liu, J.-Q] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, School of Physics and Microelectronics, Shandong University, Jinan 250100, China@@@[ Zhang, J.-Z] School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 317 [author_en] => Zhang, QZ; Liu, JQ; Zhang, JZ [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => photochromic liquid crystalline dendrimer; photo-electro information; functional material; trans/cis photoisomerization; photo chemical; back-isomerization; trans/cis isomer ratio; thermal back-isomerization;; activation energy [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => AZOBENZENE MOIETIES; 1ST GENERATION; POLYMERS [publication_iso] => Acta Chim. Sin. [format_title_en] => f32610c7febb31b078d31beb2ba3a013-746276801 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 14 [email] => qzzhang@sdu.edu.cn [cite_awos] => 9 [wos_No] => WOS:000188877700016 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on photochemistry of photochromic liquid crystalline carbosilane dendrimer of the second generation - Containing thirty-six 4-butoxyazobenzene mesogenic groups in its periphery [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,纳米比亚,瑞士,印度 [jl_keyword_en] => photochemical,photochromicliquidcrystallinedendrimer,functionalmaterial,photoelectroinformation,thermalbackisomerization,transcisphotoisomerization,transcisisomerratio,activationenergy,backisomerization [jl_keyword_cn] => 光致变色液晶树状大分子,活化能,光回复异构,热回复异构,光电信息功能材料,反顺光异构化,反顺异构组分比 [jl_clc] => o7532 [jl_publisher] => sciencechinapress [company_id] => 133,5,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 133,5,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 刘建强 [irtag] => 7 [t_index] => 0 [person_id] => 22294 ) ) [sys_author_id_arr] => 22294刘建强 [cscd_No] => CSCD:1612589 [jl_publication_cn_publication_en] => 化学学报,actachimicasinica [jl_keyword_cn_keyword_en] => photochemical,photochromicliquidcrystallinedendrimer,transcisphotoisomerization,光致变色液晶树状大分子,活化能,光回复异构,热回复异构,functionalmaterial,光电信息功能材料,反顺光异构化,photoelectroinformation,thermalbackisomerization,反顺异构组分比,transcisisomerratio,activationenergy,backisomerization [sys_author_id] => [format_cscd_No] => 4c0a930f5ae95dd7bfe6ca6cd0acf346 [format_title_en_publication_en_pub_year] => 3f9dfc7789a0be892a89af30f688fd87 [format_wos_No] => 94777c92cf48abefced7051eeb4a7fb1 [format_title_en_issn_pub_year] => 74fa36f5fc329e3f73fbcf4a3a80e5f3 [format_scopus_No] => 10bc1aeda4e43080819a4f7c0df81624 [standard_in] => School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; School of Physics and Microelectronics, Shandong University, Jinan 250100, China [cauthor] => Zhang, QZ(qzzhang@sflu.edu.cn) [datebase] => Scopus [cite_scopus] => 6 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-18444368897 [jl_pub_year] => 2004 [jl_author_test] => upersonid22294,usureu0,uuindex0,utindex0,uirtag7,uirmagnum0,unameuu5218u5efau5f3a [sys_author_jg_last_arr] => 中国 [jl_company_test] => unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uorgidu5,uparentidu43,unameuu7269u7406u5b66u9662,uircu0,uorgidu43,ulevelu1,uparentidu5 [sys_author_in_last_arr] => china [id] => zQ1FvmUBFjIhTVEbZaRs [tags] => 0 ) [16] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 在G3(MP2 )水平上 ,通过对CH3 S与O2 反应势能面 (PES)上关键驻点的能量计算 ,共找到 4种中间体 ,9个过渡态 ,6种产物通道 ,并对这些气相反应机理进行了讨论 ,同时应用TST RRKM理论对主要反应的速率进行计算 .结果表明 :CH3 S与O2 反应在低温下以生成CH3 SOO为主 ,并与实验结果吻合 ;在中高温下以加成消去和抽提反应为主 ,分别生成CH3 +SO2 和CH2 S +HO2 ,其它产物较少 . [keyword_cn] => 从头算方法;甲基硫自由基(CH3S);TST-RRKM理论;反应机理 [article_id] => 26626,332386,661176,581876,237805,495477 [clc] => O646 [author_jg] => [王少坤,张庆竹,曹成波,顾月姝]山东大学化学与化工学院,山东大学化学与化工学院,山东大学化学与化工学院,山东大学化学与化工学院 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 6577b3c75f59c904c2719001d90e830a-1825728987 [hints] => 14 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => 82e29ec6bf9d6849babd2da0e233f4b81617301876 [source_type] => 351 [pub_year] => 2002 [pub_date] => MAR [pages] => 6 [from_id] => 76,75,73,80,85,78 [author_cn] => 王少坤,张庆竹,曹成波,顾月姝 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200203009&DbName=CJFQ2002 [publication_cn] => 化学学报 [title_cn] => CH_3S与O_2气相反应机理的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => c1412ed7667dc8716fab5e6177883103-646764068 [page] => 432-437+379 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 69aac89bb01eb58c10f84fe6a8074128-1908857084 [format_title] => dd7d7e6511bd6d7e5129230c2b02868f-2141603976 [hx_id] => 2377,2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 从头算方法,甲基硫自由基ch3s,反应机理,tstrrkm理论 [jl_clc] => o646 [author_in] => [Wang, S.-K] School of Chemistry and Chemical Industry, Shandong University, Jinan 250100, China@@@[ Zhang, Q.-Z] School of Chemistry and Chemical Industry, Shandong University, Jinan 250100, China@@@[ Cao, C.-B] School of Chemistry and Chemical Industry, Shandong University, Jinan 250100, China@@@[ Gu, Y.-S] School of Chemistry and Chemical Industry, Shandong University, Jinan 250100, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => tstrrkm理论,从头算方法,反应机理,甲基硫自由基ch3s [cite_wos] => 9 [publication_en] => ACTA CHIMICA SINICA [fund_No] => 高等学校博士点专项科研基金(No. 1995042201)资助项目 [check_3Y] => 1 [language] => Chinese [delivery_No] => 533UW [cauthor_ad] => [Wang, SK]Shandong Univ, Sch Chem & Chem Ind, Jinan 250100, Peoples R China. [author_fn] => Wang, SK; Zhang, QZ; Cao, CB; Gu, YS [reference] => Baboul AG, 1999, J CHEM PHYS, V110, P7650, DOI 10.1063/1.478676@@@BALLA RJ, 1986, CHEM PHYS, V109, P101, DOI 10.1016/0301-0104(86)80188-4@@@Curtiss LA, 1999, J CHEM PHYS, V110, P4703, DOI 10.1063/1.478385@@@TURNIPSEED AA, 1992, J PHYS CHEM-US, V96, P7502, DOI 10.1021/j100198a006@@@@@@TYNDALL GS, 1991, INT J CHEM KINET, V23, P383@@@YIN FD, 1990, J ATMOS CHEM, V11, P309, DOI 10.1007/BF00053780@@@ [cite_wanfang] => 10 [cauthor] => Wang, SK(guojz@icm.sdu.edu.cn) [format_title_en_issn_pub_year] => 8aa17556a0df0d3da96cc545e96a5160939641631 [datebase] => Scopus [format_scopus_No] => 3bf16b2a057f868ddb1637bb28d03475-1913923286 [publication_29] => ACTA CHIM SINICA [end_page] => 437 [abstract_en] => A series of key stationary points of potential energy surface (PES) for the CH3S + O-2 system was calculated at the G3 (MP2) level. The calculations reveal four intermediates, nine transition states and six product channels. With the stationary points and TST-RRKM theory, the reaction rates are calculated, gas phase reaction mechanism of CH3S + O-2 is discussed. At low temperature, the reaction producing CH3SOO is the main channel. At high temperature, the addition elimination mechanism giving products of CH3 + SO2 and H-abstraction mechanism giving products of CH2S + HO2 are dominant reaction channels, the other products might be neglected. [publication_type] => J [begin_page] => 432 [author_en] => Wang, SK; Zhang, QZ; Cao, CB; Gu, YS [format_cscd_No] => 8b6e66eade8b559658ead5815c48e367-2062825452 [volume] => 60 [publisher] => SCIENCE CHINA PRESS [get_data] => 2018-08-29 [keyword_en] => ab initio; methylthiyl radical; TST-RRKM; reaction mechanism [keyword_plu] => GAUSSIAN-3 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 7f71dd92ffe19592ff6bc14edbc0348a1179263095 [cite_scopus] => 8 [publisher_city] => BEIJING [cite_cscd] => 6 [publication_info] => 0567-7351(2002)60:3<432:CYOQXF>2.0.TX;2-U [email_c] => guojz@icm.sdu.edu.cn [email] => guojz@icm.sdu.edu.cn [reference_No] => 6 [cite_awos] => 10 [cscd_No] => CSCD:1008497 [wos_No] => WOS:000174549600010 [format_wos_No] => ae11a46b84bf69652a8d47814310fcd2-1673170385 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => School of Chemistry and Chemical Industry, Shandong University, Jinan 250100, China [scopus_No] => 2-s2.0-0442264869 [title_en] => Theoretical study of the gas phase reaction of CH3S with O-2 [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => tstrrkm,abinitio,reactionmechanism,methylthiylradical [sys_author_in_last_arr] => china [jl_publisher] => sciencechinapress [sys_author_id] => [id] => wQ5IvmUBFjIhTVEbRWIm [tags] => 0 ) [17] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3252 [tag] => 0 [abstract_cn] => 触变性是分散体系一种复杂的流变学性质,指流变性质随剪切时间而发生变化的现象.以往研究过程中,先后发现了切稀现象和切稠现象,即正触变性和负触变性.最近,我们又发现了复合触变性,即一个体系可先后呈现正触变性和负触变性特征.研究了Mg-Fe型混合金属氢氧化物(简称MMH)-钠质蒙脱土(简称MT)分散体系的触变性,发现在不同MMH/MT质量比条件下,可分别呈现正触变性、负触变性,另外又观察到了复合触变性.在所研究的MMH/MT质量比范围(0~0.5)内,随MMH/MT质量比增大,体系的触变性发生负触变性-正触变性-复合触变性-负触变性的转化.考察了电解质NaCl对触变性的影响,发现不改变触变性的类型.... [keyword_cn] => 混合金属氢氧化物;蒙脱土;触变性;流变性;分散体系;层状二元氢氧化物 [article_id] => 620594,496956,333776,239396 [clc] => O657.3 [author_jg] => [侯万国,苏延磊,孙德军,张春光]山东大学,山东大学化学院,山东大学,山东大学 胶体与界面化学教育部重点实验室 济南250100,99届硕士研究生,胶体与界面化学教育部重点实验室 济南250100,胶体与界面化学教育部重点实验室 济南250100 [format_title_cn_publication_cn_pub_year] => e62ed125075eeb00028215b0e6a69dfe-1386212058 [hints] => 11 [issue] => 6 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => edda42c92bd8335d556b7c8999488fc1-14463833 [source_type] => 351 [pub_year] => 2000 [pub_date] => 2000-06-20 [pages] => 5 [from_id] => 76,80,73,78 [author_cn] => 侯万国,苏延磊,孙德军,张春光 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200006024&DbName=CJFQ2000 [publication_cn] => 化学学报 [title_cn] => Mg-Fe-MMH-钠质蒙脱土分散体系的触变性研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 194fe95806202ed94551ce7159f1ad131073064704 [page] => 722-726 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 触变性,流变性,分散体系,层状二元氢氧化物,蒙脱土,混合金属氢氧化物 [jl_clc] => o6573 [author_in] => [Hou, W.-G] Key Laboratory for Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan, 250100, China@@@[ Su, Y.-L] Key Laboratory for Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan, 250100, China@@@[ Sun, D.-J] Key Laboratory for Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan, 250100, China@@@[ Zhang, C.-G] Key Laboratory for Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 层状二元氢氧化物,混合金属氢氧化物,蒙脱土,流变性,触变性,分散体系 [hb_batch] => grant_no [cite_wos] => 8 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 1 [language] => Chinese [delivery_No] => 329EY [cauthor_ad] => [Hou, WG]Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China. [format_title] => 4946604ed9806ce0bed13c1618926ece-664746183 [author_fn] => Hou, WG; Su, YL; Sun, DJ; Zhang, CG [cite_wanfang] => 36 [cauthor] => Hou, WG(wghou@sdu.edu.cn) [format_title_en_issn_pub_year] => e827a816ff4fa8e817062daa782672162079556510 [datebase] => Scopus [format_scopus_No] => 789bf297c3b44caff916dc2c0b06dd3e2124251644 [publication_29] => ACTA CHIM SINICA [end_page] => 726 [abstract_en] => The thixotropy of suspension, the rheological properties change with the shear time, is a complicated rheological phenomenon. The shear - thinning and the shear - thickening phenomena, i.e., positive thixotropy and negative thixotropy, respectively were observed in the previous studies. Recently we found a novel thixotropic phenomenon, described as \"complex thixotropy\", during studying the thixotropic phenomenon of magnesium aluminum hydroxide - montmorillonite suspension. In this paper, the study of thixotropy of the aqueous suspension consisting of magnesium ferric hydroxide (Mg - Fe - MMH) possessing permanent positive charges and Na - montmorillonite (MT) possessing permanent negative charges is reported. The suspensions studied may display positive thixotropy or negative thixotropy, depending on the Mg - Fe - MMH/MT ratios. The complex phenomenon is also observed. In the range of Mg - Fe - MMH/MT ratio 0 similar to 0. 5 examined in this work, with increasing the Mg - Fe - MMH/MT ratio, the thixotropy of suspension changes from negative passing through positive, complex, then back to negative again. The effect of electrolyte NaCl on the thixotropy of the suspension was investigated, which showed that in the studied range of 0 similar to 0.10 mol/L of NaCl concentration the thixotropic type of the suspension did not change. The mechanism of the thixotropy is discussed and the change process of \"dispersed particles - steric continuous net - work structures over the whole system - densed floc units\" is purposed to explain the complex thixotropic phenomenon observed. [publication_type] => J [begin_page] => 722 [author_en] => Hou, WG; Su, YL; Sun, DJ; Zhang, CG [volume] => 58 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => mixed metal hydroxide; montmorillonite; thixotropy; rheological; property; suspension; layered double hydroxide [keyword_plu] => LAYERED DOUBLE HYDROXIDES; MIXED-METAL HYDROXIDE; AQUEOUS SUSPENSION; RHEOLOGY; BEHAVIOR; SYSTEM; PH [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 0478f8f1e68a9e69a9a61efa3808af4f1573523200 [cite_scopus] => 8 [format_title_en] => 2da7c99787357336b411810632eb0d36-709856459 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2378,2371 [reference_No] => 18 [cite_awos] => 9 [wos_No] => WOS:000087894800025 [format_wos_No] => 3609a2a8c97659a5eb9f610eca0e95cd369042687 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Hou, WG [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Key Laboratory for Colloid and Interface Chemistry of the Ministry of Education, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-0042280462 [title_en] => Study on the thixotropy of magnesium ferric hydroxide - Montmorillonite suspension [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 胶体与界面化学教育部重点实验室济南250100 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => layereddoublehydroxide,rheological,montmorillonite,mixedmetalhydroxide,thixotropy,suspension,property [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => vQ1GvmUBFjIhTVEbGdA3 [tags] => 0 ) [18] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3249,3252,3241 [tag] => 0 [abstract_cn] => 以三羟甲基丙烷三丙烯酸酯(TMPTA)作交联剂,苯乙烯(St)作共聚单体,偶氮二异丁腈(AIBN)作引发剂,在低毒性乙醇和乙醇-水混合物这一新的溶剂体系中沉淀聚合反应4 h制备了单分散交联微球.通过提高交联剂用量、引发剂用量和改变反应介质中水的用量探讨了提高单体转化率的方法.结果表明,提高引发剂用量和增加溶剂中水的用量都能有效提高单体转化率并制得粒径均匀的微球.保持其他条件不变,在乙醇中使用2 wt%AIBN仅能得到79%的单体转化率,提高AIBN用量至6wt%或在介质中增加水的用量至28 vol%,在制得单分散微球的同时单体转化率可以达到95%以上.文中对微球的形成机理和提高单体转化率的方法... [keyword_cn] => 沉淀聚合;三羟甲基丙烷三丙烯酸酯;单分散微球 [article_id] => 660802,167865,597890,474703,381959 [clc] => O657.72 [author_jg] => [顾相伶] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[谭业邦] 山东大学化学化工学院, 济南, 山东 250100, 中国.@@@[朱晓丽] 济南大学化学化工学院, 济南, 山东 250022, 中国.@@@[孔祥正] 济南大学化学化工学院, 济南, 山东 250022, 中国.@@@[张利娜] 济南大学化学化工学院, 济南, 山东 250022, 中国.@@@[鲁毅] 济南大学化学化工学院, 济南, 山东 250022, 中国 [format_title_cn_publication_cn_pub_year] => 561c08dfa3dc2d2a3648c7e5d641c41e541147000 [hints] => 42 [issue] => 21 [sys_level_num] => 2_3 [sys_jg_type] => 11,3,5 [format_issn_issue_page_pub_year] => fffd587f57a14080c645acf119ecc34f468855903 [source_type] => 351 [pub_year] => 2009 [pub_date] => NOV 14 [pages] => 9 [from_id] => 76,75,73,80,78 [author_cn] => 顾相伶;朱晓丽;孔祥正;张利娜;谭业邦;鲁毅; [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-78149469338&partnerID=40&md5=6b19be56587a3deb8886895c1d90c89f [publication_cn] => 化学学报 [title_cn] => 乙醇或乙醇-水为新的溶剂体系沉淀聚合制备单分散聚合物微球 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => ef05b681b68e9368e6e9ede25e97d880-1257523557 [page] => 2486-2494 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 8 [fund_No] => 国家自然科学基金; 山东省自然科学基金 [check_3Y] => 18 [language] => Chinese [delivery_No] => 532PE [format_title] => 206c9e3596d6840393ecacbca19b0157-280637281 [cauthor_ad] => [Gu, XL]Shandong Univ, Coll Chem & Chem Engn, Jinan 250100, Peoples R China. [author_fn] => Gu Xiangling; Zhu Xiaoli; Kong Xiangzheng; Zhang Lina; Tan Yebang; Lu Yi [reference] => Bai,E, 2006, Chinese Journal of Polymer Science, V24, P163@@@[陈胜利 CHEN Shengli], 2007, [武汉理工大学学报, Journal of wuhan university of@@@technology], V29, P96@@@Comet,R.P, 2008, Journal of Chromatography A, V1179, P2@@@Downey JS, 1999, MACROMOLECULES, V32, P2838, DOI 10.1021/ma9812027@@@Frank RS, 1998, J POLYM SCI POL CHEM, V36, P2223, DOI@@@10.1002/(SICI)1099-0518(19980930)36:13<2223::AID-POLA8>3.0.CO;2-U@@@@@@Goh ECC, 2002, MACROMOLECULES, V35, P9983, DOI 10.1021/ma0211028@@@[郭红莲 Guo Honglian], 2003, [物理学报, Acta Physica Sinica], V52, P324@@@Jin JM, 2005, J POLYM SCI POL CHEM, V43, P5343, DOI 10.1002/pola.20985@@@Kim K, 2005, Appl. Polym. Sci, V96, P200@@@Kong XZ, 2009, MACROMOL RAPID COMM, V30, P909, DOI@@@10.1002/marc.200800772@@@[李建林 LI JianLin], 2006, [化学学报, Acta Chemical Sinica], V64, P1489@@@LI K, 1993, J POLYM SCI POL CHEM, V31, P3257, DOI@@@10.1002/pola.1993.080311313@@@Li,K,St6ver, 1993, Polym.Sci.Part.4:Polym.Chem, V31, P2473@@@Li WH, 1999, J POLYM SCI POL CHEM, V37, P2295, DOI@@@10.1002/(SICI)1099-0518(19990715)37:14<2295::AID-POLA2>3.0.CO;2-J@@@Li WH, 1999, J POLYM SCI POL CHEM, V37, P2899, DOI@@@10.1002/(SICI)1099-0518(19990801)37:15<2899::AID-POLA23>3.0.CO;2-8@@@Ma GH, 2004, MACROMOLECULES, V37, P2954, DOI 10.1021/ma035316g@@@Mehta RC, 1996, J CONTROL RELEASE, V41, P249, DOI@@@10.1016/0168-3659(96)01332-6@@@@@@NAKA Y, 1992, J POLYM SCI POL CHEM, V30, P1287, DOI@@@10.1002/pola.1992.080300706@@@@@@Okubo M, 1991, Colloid Polym. Sci, V267, P193@@@Shim SE, 2004, COLLOID POLYM SCI, V283, P41, DOI@@@10.1007/s00396-004-1086-3@@@Shim SE, 2004, J POLYM SCI POL CHEM, V42, P835, DOI 10.1002/pola.11028@@@Yan Q, 2008, J PHYS CHEM B, V112, P6914, DOI 10.1021/jp711324a@@@[阎青 YAN Qing], 2007, [高分子学报, Acta Polymerica Sinica], P1102@@@Yang SH, 2005, J POLYM SCI POL CHEM, V43, P1309, DOI 10.1002/pola.20417@@@ [publication_29] => ACTA CHIM SINICA [end_page] => 2494 [abstract_en] => Uniform microspheres were prepared through precipitation polymerization of 1,1,1-tris(hydroxymethyl)propane triacrylate (TMPTA)-styrene (St) with azobisisobutyronitrile (AIBN) as initiator in ethanol and ethanol-water mixture, new solvent systems with low toxicity. Impacts of TMPTA amounts, initiator concentrations and water content in the solvent mixture were studied. Uniform microspheres were obtained within 4 h along with higher monomer conversion. Results demonstrated clearly that increase of initiator amounts and use of water as a cosolvent were indeed very effective to promote the polymerization to high conversions and to get uniform microspheres. With no water under otherwise the same experimental conditions, only about 79% of monomer conversion was detected; while monomer conversion was remarkably increased to 95% when 28 vol% of water was added into ethanol. To reach this high conversion with no water in the medium, 6 wt% of AIBN was needed. Mechanisms of microsphere formation and methods to promote monomer conversion were also explained. [orcID] => Kong, Xiang Zheng/0000-0002-1725-4619 [author_in] => [Gu, X.-L] College of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China, College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China@@@[ Zhu, X.-L] College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China@@@[ Kong, X.-Z] College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China@@@[ Zhang, L.-N] College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China@@@[ Tan, Y.-B] College of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Lu, Y] College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China [publication_type] => J [begin_page] => 2486 [author_en] => Gu, XL; Zhu, XL; Kong, XZ; Zhang, LN; Tan, YB; Lu, Y [volume] => 67 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => precipitation polymerization; 1,1,1-tris(hydroxymethyl)propane; triacrylate; uniform microsphere [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => LINKED POLY(DIVINYLBENZENE) MICROSPHERES; SUSPENSION POLYMERIZATION; ACETIC-ACID; GROWTH; DIVINYLBENZENE; MORPHOLOGY; MECHANISM; EMULSION; SIZE [publication_iso] => Acta Chim. Sin. [format_title_en] => b8919329f808d3a80ad49322851fc3aa1572652019 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 24 [email] => xzkong@ujn.edu.cn [cite_awos] => 8 [wos_No] => WOS:000272761100015 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 3 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Preparation of Polymer Uniform Microspheres via Precipitation Polymerization in Ethanol or Ethanol-water Mixture as New Solvent [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国 [jl_keyword_en] => precipitationpolymerization,1,triacrylate,uniformmicrosphere,1trishydroxymethylpropane [jl_keyword_cn] => 单分散微球,沉淀聚合,三羟甲基丙烷三丙烯酸酯 [jl_clc] => o65772 [jl_publisher] => sciencepress [author_id] => 23651 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 5 [name] => 谭业邦 [sys_author_id] => Array ( [0] => 23651 ) [irtag] => 0 [t_index] => 0 [person_id] => 23651 ) ) [company_id] => 0,43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [sys_author_id_arr] => 23651谭业邦 [cscd_No] => CSCD:3745892 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => precipitationpolymerization,三羟甲基丙烷三丙烯酸酯,单分散微球,沉淀聚合,triacrylate,1,uniformmicrosphere,1trishydroxymethylpropane [format_title_en_issn_pub_year] => 5b732842de1a3c1e79e034b2668c4199629963408 [format_scopus_No] => 0d10ae010309678c28e6bb318d1e7895-279042228 [format_cscd_No] => 00404aba354714589ff5cbb1be417caf1896585843 [format_wos_No] => 2e6bfd7471d4e8875b22c12f9c0bc05b-728337101 [standard_in] => College of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China; College of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China [cauthor] => Kong, XZ(xzkong@ujn.edu.cn) [datebase] => Scopus [format_title_en_publication_en_pub_year] => 548b2cac4a14f42c28c9d3cc780dc1a2-599686696 [cite_scopus] => 6 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-78149469338 [jl_author_test] => uirtypical3,uirtstag0,unameuu8c2du4e1au90a6,usureu0,upersonid23651,utindex0,uirinspecttag0,uirauthortype0,uirtag0,uuindex5 [sys_author_jg_last_arr] => 中国,中国,中国,中国,中国,中国 [jl_company_test] => uircu0,unameuu5316u5b66u4e0eu5316u5de5u5b66u9662,uparentidu43,uorgidu43,ulevelu1 [sys_author_in_last_arr] => china [sys_author_id] => [id] => Lg5HvmUBFjIhTVEbZSTq [tags] => 0 ) [19] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3241,3254,3243,3252 [tag] => 0 [abstract_cn] => 采用溶胶-凝胶法并结合水蒸气活化制备了Si掺杂TiO2纤维,通过TG—DSC,XRD,FT—IR,UV—Vis—DRS,N2吸附一脱附,SEM等手段对纤维样品的结构参数及其表面形貌进行了表征,并以活性艳红X-3B模拟废水体系评价了其光催化活性.结果表明,与纯TiO2产物相比,适量Si掺杂制得的产物是具有丰富介孔结构的TiO2长纤维,不仅热稳定性和晶型稳定性俱佳,而且光催化活性得以显著提高,经900℃热处理后仍能保持结晶完好的锐钛矿相;在Si/Ti摩尔比为0.15时,其比表面积和孔容最大,光催化活性最佳,该纤维作为光催化剂反应75min,水中X-3B的降解率可达99.6%. [keyword_cn] => 溶胶-凝胶法;Si掺杂;TiO2纤维;光催化活性; [clc] => TQ443 [author_jg] => [包南] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[张锋] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[马志会] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[魏振涛] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[孙剑] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[刘峰] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => aab0c62beefeebf8ebe87167583b406359920873 [from_id] => 76,75,73,80,78,85 [issue] => 23 [sys_level_num] => 2_1 [sys_jg_type] => 11,8,3,5,10 [source_type] => 351 [pub_year] => 2007 [article_id] => 73355,597885,323985,483510,662942,238502 [pages] => 7 [hints] => 18 [author_cn] => 包南[1];张锋[1,2];马志会[1];魏振涛[1];孙剑[1];刘峰[1] [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-55749091365&partnerID=40&md5=b57a1dff5142104a75000ee253bb470c [publication_cn] => 化学学报 [title_cn] => Si掺杂TiO2纤维的溶胶-凝胶法制备及其光催化活性 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 61ed3d9253646976ffe02bde8747b818-1017355978 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 8 [fund_No] => 国家863计划(No.2003AA601060); 山东大学校青年基金(No.11440053187025) [check_3Y] => 5 [language] => Chinese [delivery_No] => 246QG [format_title] => c66918dbbf1ed6c8218c33d6e94a7374-770951344 [cauthor_ad] => [Bao, N]Shandong Univ, Sch Environm Sci & Engn, Jinan 250100, Peoples R China. [author_fn] => Bao Nan; Zhang Feng; Ma Zhi-Hui; Wei Zhen-Tao; Sun Jian; Liu Feng [reference] => [包南 BAO Nan], 2007, [无机化学学报, Chinese Journal of Inorganic Chemistry],@@@V23, P101@@@Cheng P, 2003, MATER LETT, V57, P2989, DOI 10.1016/S0167-577X(02)01409-X@@@DUTOIT DCM, 1995, J CATAL, V153, P165, DOI 10.1006/jcat.1995.1118@@@Hu C, 2003, APPL CATAL A-GEN, V253, P389, DOI@@@10.1016/S0926-860X(03)00545-3@@@Jung KY, 2000, APPL CATAL B-ENVIRON, V25, P249, DOI@@@10.1016/S0926-3373(99)00134-4@@@KAMIYA K, 1986, Materials Science Letters, V5, P402@@@Kochkar H, 1997, J CATAL, V171, P420, DOI 10.1006/jcat.1997.1820@@@@@@Kresge C T, 1992, J. Nature, V6397, P710@@@Kumar SR, 1999, MATER LETT, V38, P161, DOI 10.1016/S0167-577X(98)00152-9@@@[刘艳 Liu Yan], 2005, [化学学报, Acta Chimica Sinica], V63, P312@@@[麻明友 MA MingYou], 2006, [化学学报, Acta Chemical Sinica], V64, P1389@@@SCHRAMLMARTH M, 1992, J NON-CRYST SOLIDS, V143, P93, DOI@@@10.1016/S0022-3093(05)80557-5@@@Shimizu T., 1978, Yogyo-Kyokai-Shi, V86, P339@@@[宋秀芹 SONG XiuQin], 2006, [化学学报, Acta Chemical Sinica], V64, P198@@@[孙镛 SUN Yong], 2007, [化学学报, Acta Chemical Sinica], V65, P67@@@Tanev P T, 1994, J. Nature, P368321@@@Tepper T, 1999, NANOSTRUCT MATER, V11, P895, DOI@@@10.1016/S0965-9773(99)00388-8@@@Tsevis A, 1998, J CHEM SOC FARADAY T, V94, P295, DOI 10.1039/a706608b@@@Yang JB, 2002, CARBON, V40, P911, DOI 10.1016/S0008-6223(01)00222-6@@@Yin S, 2003, J MATER PROCESS TECH, V137, P45, DOI@@@10.1016/S0924-0136(02)01065-8@@@[周亚松 Zhou Yasong], 2003, [高等学校化学学报, Chemical Journal of Chinese@@@Universities], V24, P1266@@@包南, 1998, 中国环境科学, V18, P458@@@刘和义, 2006, 中国专利 1584156 [publication_29] => ACTA CHIM SINICA [end_page] => 2792 [abstract_en] => Pure TiO2 and Si-doped TiO2 fibers were prepared by a sol-gel method combined with vapor activation. The structural parameters and surface morphology were characterized by the techniques such as TG-DSC, XRD, FT-IR, UV-Vis-DRS, N-2 absorption-desorption and SEM. The photocatalytic degradation of X-3B in aqueous solution was used as a probe reaction to evaluate their photocatalytic activities. The results indicate that compared with pure TiO2, the sample prepared with a proper dopant of Si is a TiO2 long fiber with an abundant mesoporous structure, which not only possesses excellent thermal stability and crystal stability, but also has much higher photocatalytic activities. The results also indicate that the anatase phase can be maintained even after calcination at 900 degrees C. The sample has the largest specific surface area, pore volume and the best photocatalytic activity when the molar ratio of Si/Ti is 0.15. Under optimum condition, 99.6% of X-3B was degraded after irradiation within 75 min under UV-light. [researcherID] => SDU, Environ Res/P-4462-2015 [author_in] => [Bao, N] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Zhang, F] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China, College of Life Science and Biotechnology, Shanghai Jiaotong University, Shanghai 200240, China@@@[ Ma, Z.-H] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Wei, Z.-T] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Sun, J] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Liu, F] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 2786 [article_dt] => Article [author_en] => Bao, N; Zhang, F; Ma, ZH; Wei, ZT; Sun, J; Liu, F [volume] => 65 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => sol-gel method; Si doping; TiO2 fiber; photocatalytic activity [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => MESOPOROUS MOLECULAR-SIEVES; MIXED OXIDES; SILICA; TITANIA; TIO2-SIO2; TIO2/SIO2; TEMPLATE; SPHERES [publication_iso] => Acta Chim. Sin. 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21. Fe3O4超顺磁纳米晶的超声共沉淀法制备及表征 CSCD SCOPUS SCIE

作者:王冰[1,2];张锋[1];邱建华[3];张雪洪[1];陈洪[2];杜毅[2];许平[1]

作者机构:[王冰] 上海交通大学生命科学技术学院, 上海 200240, 中国.;[张锋] 上海交通大学生命科学技术学院, 上海 200240, 中国.;[张雪洪] 上海交通大学生命科学技术学院, 上海 200240, 中国.;[许平] 上海交通大学生命科学技术学院, 上海 200240, 中国.;[邱建华] 山东大学生命科学学院, 济南, 山东 250100, 中国.;[陈洪] 上海爱普香料有限公司, 上海 201809, 中国.;[杜毅] 上海爱普香料有限公司, 上海 201809, 中国

来源:化学学报,ACTA CHIMICA SINICA,2009,Vol.67,Issue.11,1211-1216

WOS被引数:11

资源类型:期刊论文

WOS:000267606400010

22. 混合碳链烷基聚葡糖苷中相微乳液的研究 CSCD SCOPUS SCIE

作者:柴金岭;李东祥;李干佐;梁芳珍;张高勇山东大学胶体与界面化学教育部重点实验室;夏瑞

作者机构:[柴金岭] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李东祥] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李干佐] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张高勇] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[梁芳珍] 山东师范大学化学系, 济南, 山东 250014, 中国.;[夏瑞] 北京药品检验所, 北京 100035, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.1,47-52

WOS被引数:11

资源类型:期刊论文

WOS:000187998100010

23. 吡啶-BH_3相互作用复合物的理论研究 CSCD SCOPUS SCIE

作者:孟凡翠,步宇翔,刘成卜

作者机构:[孟凡翠] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[步宇翔] 山东大学理论化学研究所, 分子动力学国家重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2002,Vol.60,Issue.1,7-12+7

WOS被引数:11

资源类型:期刊论文

WOS:000173368700003

24. 稀土(Ⅲ)三硬脂酸盐LB膜的制备及结构研究 SCIE

作者:杨孔章;肖童;穆劲;

作者机构:[杨孔章;肖童;穆劲]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所 济南 250100,济南 250100,济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.4,340-343

WOS被引数:10

资源类型:期刊论文

WOS:A1991FV35600006

25. 含N,O和S的Schiff碱配体的双核锌配合物的合成与晶体结构 SCIE

作者:马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利

作者机构:[马长勤,王绪宁,张文兴,于正刚,蒋德华,董士利]山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,山东大学化学院,淄博市公安局 济南250100,济南250100,济南250100,济南250100,济南250100,淄博255039

来源:化学学报,ACTA CHIMICA SINICA,1996,Vol.54,Issue.6,562-567

WOS被引数:10

资源类型:期刊论文

WOS:A1996UY13200007

26. 烯丙基硫脲和十二烷基硫醇对铜的缓蚀作用 CSCD SCOPUS SCIE

作者:王春涛;陈慎豪;赵世勇;李德刚

作者机构:[王春涛] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[陈慎豪] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[赵世勇] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[李德刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.2,151-155

WOS被引数:10

资源类型:期刊论文

WOS:000181172200001

27. 一代树状碳硅烷液晶研究——端基含12个4-硝基偶氮苯介晶基元 CSCD SCOPUS SCIE

作者:张其震,盛昕,殷晓颖,季怡萍,李光,赵晓光

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[盛昕] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[殷晓颖] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[季怡萍] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[李光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国.;[赵晓光] 中国科学院长春应用化学研究所, 长春, 吉林 130022, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.9,1478-1483

WOS被引数:10

资源类型:期刊论文

WOS:000188245700026

28. 金属硫氰酸根配合物FeHg(SCN)_4,MnHg(SCN)_4的合成、晶体结构与非线性光学性质的研究 SCOPUS SCIE

作者:延云兴,方奇,于文涛,袁多荣,田玉鹏,蒋民华,I.D.Williams,蔡志岗

作者机构:[延云兴,方奇,于文涛,袁多荣,田玉鹏,蒋民华,I.D.Williams,蔡志岗]山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,山东大学晶体材料研究所晶体材料国家重点实验室,香港科技大学化学系,中山大学超快光谱国家重点实验室 济南250100,济南250100,济南250100,济南250100,济南250100,济南250100,广州510275

来源:化学学报,ACTA CHIMICA SINICA,1999,Vol.57,Issue.11,1257-1261

WOS被引数:10

资源类型:期刊论文

WOS:000083783900013

29. Cr(VI)在Mg-Al型类水滑石上的吸附-脱附性研究I.吸附性 CSCD SCOPUS SCIE

作者:臧运波;侯万国;王文兴;

作者机构:[臧运波] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[侯万国] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[王文兴] 山东大学环境研究院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2007,Vol.65,Issue.9,773-778

WOS被引数:10

资源类型:期刊论文

WOS:000246715600001

30. V形咔唑衍生物的合成及荧光性质 CSCD SCOPUS SCIE

作者:王伟,方奇,刘志强,曹笃霞,邓敏智

作者机构:[王伟] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[刘志强] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[曹笃霞] 济南大学材料科学与工程学院, 济南, 山东 250022, 中国.;[邓敏智] 中国科学院上海有机化学研究所, 中科院有机氟化学重点实验室, 上海 200032, 中国

来源:化学学报,ACTA CHIMICA SINICA,2005,Vol.63,Issue.14,1323-1328+1242

WOS被引数:10

资源类型:期刊论文

WOS:000230857100014

31. 紫外倍频晶体硫氰酸汞镉的生长习性与形成机理研究 SCOPUS SCIE

作者:姜雪宁;袁多荣;许东;吕孟凯;郭世义;于文涛;张光辉;方奇

作者机构:[姜雪宁;袁多荣;许东;吕孟凯;郭世义;于文涛;张光辉;方奇]山东大学晶体材料研究所,,中国

来源:化学学报,ACTA CHIMICA SINICA,2001,Vol.59,Issue.5,724-728

WOS被引数:10

资源类型:期刊论文

WOS:000168913600018

32. 烷基苯磺酸盐在油水界面行为的介观模拟 CSCD SCOPUS SCIE

作者:李振泉[2];何秀娟[1];李英[1];马保民[1];曹绪龙[2];宋新旺[2];崔晓红[2]

作者机构:[李振泉] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.;[曹绪龙] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.;[宋新旺] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.;[崔晓红] 中石化胜利油田地质科学研究院, 东营, 山东 257015, 中国.;[何秀娟] 山东大学化学与化工学院, 胶体与界面教育部重点实验室, 济南, 山东 250100, 中国.;[李英] 山东大学化学与化工学院, 胶体与界面教育部重点实验室, 济南, 山东 250100, 中国.;[马保民] 山东大学化学与化工学院, 胶体与界面教育部重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2007,Vol.65,Issue.24,2803-2808

WOS被引数:10

资源类型:期刊论文

WOS:000252479000001

33. 硼碳团簇BnC2(n=1~6)的理论研究 CSCD SCIE

作者:王若曦[1,2];张冬菊[1];朱荣秀[1];刘成卜[1]

作者机构:[王若曦] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[张冬菊] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[朱荣秀] 山东大学理论化学研究所, 济南, 山东 250100, 中国.;[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2007,Vol.65,Issue.19

WOS被引数:9

资源类型:期刊论文

WOS:000250308600002

34. CTAB水溶液表面的吸附动力学 SCOPUS SCIE

作者:柴金岭[1];张高勇[2];李干佐[1];李英[1];徐桂英[1];马忠娟[1]

作者机构:[柴金岭;李干佐;李英;徐桂英;马忠娟]山东大学,中国.;[张高勇]中国日用化学工业研究院,,中国

来源:化学学报,ACTA CHIMICA SINICA,2001,Vol.59,Issue.12,2122-2125

WOS被引数:9

资源类型:期刊论文

WOS:000172867700016

35. PVP与C14BE之间的相互作用 SCOPUS SCIE

作者:徐桂英;隋卫平

作者机构:[徐桂英;隋卫平]山东大学胶体与界面化学国家教委开放实验室,中国

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.12,1179-1184

WOS被引数:9

资源类型:期刊论文

WOS:000072037000006

36. 二代光致变色液晶树枝状碳硅烷的光化学研究——端基含36个丁氧基偶氮苯介晶基元 CSCD SCOPUS SCIE

作者:张其震,刘建强,张静智

作者机构:[张其震] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[刘建强] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[张静智] 山东大学化学化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.3,317-323

WOS被引数:9

资源类型:期刊论文

WOS:000188877700016

37. CH_3S与O_2气相反应机理的理论研究 CSCD SCOPUS SCIE

作者:王少坤,张庆竹,曹成波,顾月姝

作者机构:[王少坤,张庆竹,曹成波,顾月姝]山东大学化学与化工学院,山东大学化学与化工学院,山东大学化学与化工学院,山东大学化学与化工学院 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,2002,Vol.60,Issue.3,432-437+379

WOS被引数:9

资源类型:期刊论文

WOS:000174549600010

38. Mg-Fe-MMH-钠质蒙脱土分散体系的触变性研究 SCOPUS SCIE

作者:侯万国,苏延磊,孙德军,张春光

作者机构:[侯万国,苏延磊,孙德军,张春光]山东大学,山东大学化学院,山东大学,山东大学 胶体与界面化学教育部重点实验室 济南250100,99届硕士研究生,胶体与界面化学教育部重点实验室 济南250100,胶体与界面化学教育部重点实验室 济南250100

来源:化学学报,ACTA CHIMICA SINICA,2000,Vol.58,Issue.6,722-726

WOS被引数:8

资源类型:期刊论文

WOS:000087894800025

39. 乙醇或乙醇-水为新的溶剂体系沉淀聚合制备单分散聚合物微球 CSCD SCOPUS SCIE

作者:顾相伶;朱晓丽;孔祥正;张利娜;谭业邦;鲁毅;

作者机构:[顾相伶] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[谭业邦] 山东大学化学化工学院, 济南, 山东 250100, 中国.;[朱晓丽] 济南大学化学化工学院, 济南, 山东 250022, 中国.;[孔祥正] 济南大学化学化工学院, 济南, 山东 250022, 中国.;[张利娜] 济南大学化学化工学院, 济南, 山东 250022, 中国.;[鲁毅] 济南大学化学化工学院, 济南, 山东 250022, 中国

来源:化学学报,ACTA CHIMICA SINICA,2009,Vol.67,Issue.21,2486-2494

WOS被引数:8

资源类型:期刊论文

WOS:000272761100015

40. Si掺杂TiO2纤维的溶胶-凝胶法制备及其光催化活性 CSCD SCOPUS SCIE

作者:包南[1];张锋[1,2];马志会[1];魏振涛[1];孙剑[1];刘峰[1]

作者机构:[包南] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[张锋] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[马志会] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[魏振涛] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[孙剑] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[刘峰] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2007,Vol.65,Issue.23,2786-2792

WOS被引数:8

资源类型:期刊论文

WOS:000252021400024

共 17 页, 325 条记录

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