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IH(v\')+I\' system based on vibrationally adiabatic analysis, where the diatomic interaction potential and vibrational eigenstates are the accurate solution of the Morse oscillator. Employing distributed Gaussian bases (DGB) to expand the vibrational eigenfunctions of the Morse oscillator in calculations for reaction probabilities, the calculation method becomes efficiently simplifies. The results show that the reaction probabilities at low collision energies oscillate very rapidly but they oscillate much more slowly at higher collision energies. The reaction mechanism is also discussed. [publication_type] => J [publisher_city] => SHANGHAI [article_id] => 155173,335962,598065 [get_data] => 2018-08-29 [format_title_en_publication_en_pub_year] => b8299b228bd5c1fa80771f0283f8bfbb-932663255 [pages] => 6 [cite_wos] => 8 [check_3Y] => 0 [cite_awos] => 8 [from_id] => 80,73,78 [cauthor_ad] => [Cai, ZT]SHANDONG UNIV,INST THEORET CHEM,JINAN 250100,PEOPLES R CHINA. [school_id] => 117 [cauthor_order] => 1 [research_area] => Chemistry [sys_level_num] => 1_7 [publisher] => ACTA CHIMICA SINICA [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => f6b729a54deaf29503d29566aacaeab71264472057 [title_en] => Study on the oscillatory behaviour of the reaction probability for the I+HI\'(v)->IH(v\')+I\' system using by quantum scattering theory [publication_29] => ACTA CHIM SINICA [author_fn] => Cai, ZT; Zhao, X; Deng, CH [pub_year] => 1995 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [check_180] => 0 [end_page] => 1059 [cauthor_back] => Cai, ZT [begin_page] => 1054 [format_wos_No] => 170697aee9f65ed85afe4ecb818ab26a-926422452 [hints] => 9 [volume] => 53 [language] => Chinese [source_type] => 351 [issue] => 11 [reference_No] => 6 [batch] => 3250,3241,3252 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2371 [sys_update_time] => 2018-09-05 15:29:32 [format_title_en_issn_pub_year] => 4af37669a479b7a283333ce0d97ef328880546586 [publication_iso] => Acta Chim. Sin. [wos_sub] => Chemistry, Multidisciplinary [SYS_TAG] => 3 [wos_No] => WOS:A1995TL44500003 [page] => 1054-1059 [hb_type] => 2 [article_dt] => Article [jl_language] => chinese [jl_publication_en] => actachimicasinica [jl_article_dt] => 期刊论文 [jl_publisher] => actachimicasinica [author_jg] => [蔡政亭,赵显,邓从豪]山东大学理论化学研究室,山东大学理论化学研究室,山东大学理论化学研究室 济南250100,济南250100,济南250100 [keyword_cn] => 重…轻-重反应体系;反应几率的振荡行为;Morse振子;Gauss分布函数展开;量子散射理论 [format_title] => 8d762f763b95d87b565c0e0d58c7a538962637283 [clc] => O646 [title_cn] => I+HI′(v)→IH(v′)+I′反应几率振荡行为的量子散射理论研究 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_cn] => 化学学报 [format_title_en] => fe1073d4b992f1a2d328fa2e31b233881928765436 [sys_priority_field] => 73 [author_cn] => 蔡政亭,赵显,邓从豪 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [CSSN] => 31-1320/O6 [abstract_cn] => 本文基于振动绝热性分析,用量子散射理论研究I+HI′(v)→IH(V′)+I′反应几率的振荡行为,其中双原子间相互作用势和振动本征态是Morse振子的严格解.在计算反应几率时采用分布高斯基(Distributed Gaussian Basis Sets;DGBS)展开方法,既保持了反应几率的解析表达式,又有效地简化了计算.计算结果明显地揭示了反应几率在低碰能区域的振荡行为.对反应机理也作了探讨. [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199511002&DbName=CJFQ1995 [jl_publication_cn] => 化学学报 [jl_keyword_cn] => morse振子,gauss分布函数展开,反应几率的振荡行为,重…轻重反应体系,量子散射理论 [jl_clc] => o646 [author_in] => [company_id] => [author_id] => 25938 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 2 [name] => 赵显 [sys_author_id] => Array ( [0] => 25938 ) [irtag] => 0 [t_index] => 0 [person_id] => 25938 ) ) [sys_author_id_arr] => 25938赵显 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 重…轻重反应体系,反应几率的振荡行为,morse振子,gauss分布函数展开,量子散射理论 [sys_author_id] => 25938 [format_title_cn_publication_cn_pub_year] => 85f4a8adaa6c7e4cb95f95310f655219663047940 [format_title_cn_issn_pub_year] => b49932cc439cd9370faa90a8d71aef41-1434126786 [id] => yQifvWUBFjIhTVEbH9iI [tags] => 0 ) [2] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 分别以二苯胺和咔唑为端基 ,以芴为共轭桥 ,合成了两个对称型芴衍生物 :2 ,7 二 (N ,N 二苯胺基 ) 9,9 二乙基芴[2 ,7 bis(N ,N diphenylamino) 9,9 diethyl fluorene ,简称DPDEF]和 2 ,7 二咔唑基 9,9 二乙基芴 (2 ,7 dicarbazol 9′ yl 9,9 diethyl fluorene ,简称DCDEF) .用四圆X射线衍射方法测定了其晶体结构 .DPDEF单晶属于单斜晶系 ,C2 /c空间群 .晶胞参数 :a =2 864 9(4 )nm ,b =0 85 111(9)nm ,c =2 7... [keyword_cn] => DPDEF;DCDEF;芴衍生物;蓝色上转换荧光 [article_id] => 490183,597903,68715,237927,330442,661667 [clc] => Q789 [author_jg] => [曹笃霞,方奇,薛刚,许贵宝,于文涛,刘志强]山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室 济南250100,济南250100,济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 48f5b01d6f43485d8826427539a798701670844254 [hints] => 63 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => 19f6abc8013cd0667d4343d4fa6bc9a8-1247977769 [source_type] => 351 [pub_year] => 2004 [pub_date] => FEB 14 [pages] => 5 [from_id] => 76,75,73,80,85,78 [author_cn] => 曹笃霞,方奇,薛刚,许贵宝,于文涛,刘志强 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200403000&DbName=CJFQ2004 [publication_cn] => 化学学报 [title_cn] => 芴衍生物的合成、结构与蓝色(λ_(max)=418nm)双光子荧光 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 2d27ce0d50159282dc7f50cee8fb78ef-1872726298 [page] => 225-229 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 188ea0d4119bee1a7cc4fca98db166f6-69771576 [format_title] => 250a1db45481d6f404b588f30b4285c31243066833 [hx_id] => 2377,2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => dcdef,dpdef,蓝色上转换荧光,芴衍生物 [jl_clc] => q789 [author_in] => [Cao, D.-X] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Fang, Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Xue, G] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Xu, G.-B] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Yu, W.-T] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Liu, Z.-Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China [company_id] => 24,0,151 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => dcdef,dpdef,蓝色上转换荧光,芴衍生物 [cite_wos] => 8 [publication_en] => ACTA CHIMICA SINICA [fund_No] => 国家自然科学基金; 高等学校骨干教师资助计划项目 [check_3Y] => 3 [language] => Chinese [delivery_No] => 773BK [cauthor_ad] => [Fang, Q]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China. [author_fn] => Cao, DX; Fang, Q; Xue, G; Xu, GB; Yu, WT; Liu, ZQ [reference] => Abbotto A, 2002, ORG LETT, V4, P1495, DOI 10.1021/ol025703v@@@Albota M, 1998, SCIENCE, V281, P1653, DOI 10.1126/science.281.5383.1653@@@Belfield KD, 2002, J LUMIN, V97, P141, DOI 10.1016/S0022-2313(02)00216-8@@@Bhawalkar JD, 1996, REP PROG PHYS, V59, P1041, DOI@@@10.1088/0034-4885/59/9/001@@@Cho BR, 2001, J AM CHEM SOC, V123, P10039, DOI 10.1021/ja010770q@@@HIROSUKE T, 1993, CHEM ABSTR, V118, P22035@@@Kannan R, 2001, CHEM MATER, V13, P1896, DOI 10.1021/cm000747o@@@Liu ZQ, 2002, CHEM COMMUN, P2900, DOI 10.1039/b207210f@@@REYNOLDS GA, 1975, OPT COMMUN, V13, P222, DOI@@@10.1016/0030-4018(75)90085-1@@@Ventelon L, 2001, ANGEW CHEM INT EDIT, V40, P2098, DOI@@@10.1002/1521-3773(20010601)40:11<2098::AID-ANIE2098>3.3.CO;2-S@@@Xu C, 1996, J OPT SOC AM B, V13, P481, DOI 10.1364/JOSAB.13.000481 [cite_wanfang] => 12 [format_title_en_issn_pub_year] => 64a968079f34c163d3cd79d21ce23e31-1833161579 [datebase] => Scopus [format_scopus_No] => 926a29348b92be8fdfea5f26f1f4f7c885200320 [publication_29] => ACTA CHIM SINICA [end_page] => 229 [abstract_en] => Two symmetrical fluorene derivatives with diphenylamino and carbazolyl as terminal group have been synthesized, which are named 2,7-bis(N, N-diphenylamino)-9,9-diethyl-fluorene (abbreviated to DPDEF) and 2,7-dicarbazol-9\'-yl-9,9-diethyl-fluorene (abbreviated to DCDEF). Their crystal structures were determined by four-circle X-ray diffraction. DPDEF belongs to monoclinic system, C2/c space group, a = 2. 8649 (4) nm, 3 b 0.85111(9) nm, c = 2.7012(4) nm, beta = 100.982(11)degrees, V = 6.4657(14) nm(3), Z = 8, D-c = 1.144 g(.)cm(-3), R = 0.0581. DCDEF belongs to monoclinic system, P2(1)/c space group, a = 0. 92794 (12) nm, b = 0.88561 (9) nm, c = 3.7236(4) nm, beta = 96.914(9)degrees, V = 3.0378 (6) nm(3), Z = 4, D-c = 1.208 g(.)cm(-3), R = 0.0652. The fluorene bridge shows perfect planarity with very small dihedral angle (3.0degrees for DPDEF and 5.8degrees for DCDEF respectively) between two involved phenyls. Pumped by 730 nm laser pulses, DPDEF exhibited strong blue upconverted fluorescence (lambda(max) = 418 nm) in THF with the two-photon absorption cross-section of 15 GM. [researcherID] => Xu, Guibao/F-3461-2010; Liu, Zhiqiang/D-9589-2017 [orcID] => Liu, Zhiqiang/0000-0001-7863-1759 [publication_type] => J [begin_page] => 225 [author_en] => Cao, DX; Fang, Q; Xue, G; Xu, GB; Yu, WT; Liu, ZQ [format_cscd_No] => 9168fe78a449ede2d3115624f6e6b909616083794 [volume] => 62 [publisher] => SCIENCE CHINA PRESS [get_data] => 2018-08-29 [keyword_en] => DPDEF; DCDEF; fluorene derivative; blue up-converted fluorescence [keyword_plu] => CROSS-SECTIONS; DYES; CHROMOPHORES; FLUOROPHORES; EXCITATION [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 675a4cee8d971a45094802d7bbcecb25561794884 [cite_scopus] => 9 [publisher_city] => BEIJING [cite_cscd] => 6 [publication_info] => 0567-7351(2004)62:3<225:WYSWDH>2.0.TX;2-X [email_c] => fangqi@ic.sdu.edu.cn [email] => fangqi@icm.sdu.edu.cn [reference_No] => 12 [cite_awos] => 10 [cscd_No] => CSCD:1612211 [wos_No] => WOS:000188877700001 [format_wos_No] => ac83573a5d2fd25f1d42e0de92cfbde8-1623314436 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China [scopus_No] => 2-s2.0-33749138073 [title_en] => Synthesis, structure and two-photon excited blue fluorescence of fluorene derivatives [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_country] => 中国 [jl_keyword_en] => dcdef,fluorenederivative,dpdef,blueupconvertedfluorescence [sys_author_in_last_arr] => china [jl_publisher] => sciencechinapress [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 24,151 [company_test] => Array,Array [id] => Ow5HvmUBFjIhTVEbZSTq [tags] => 0 ) [3] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [CSSN] => 31-1320/O6 [abstract_cn] => 本文用解析梯度和 RHF/STO-3G 方法研究了锂卤类卡宾 H2C=CLiF 势能面的主要特征,得到了四种平衡构型及其异构化的过渡态构型.平衡构型的能量按三元环构型、四元环构型、σ-配合物构型和 p-配合物构型的顺序递增.文中分析了各构型的特点,给出了偶极矩、电荷分布和前线分子轨道,并对该类卡宾的化学反应性质进行了讨论. [clc] => O64 [author_jg] => [王秉泽;许临晓;邓从豪]山东大学化学系,复旦大学化学系,山东大学化学系 济南,上海,济南 [format_title_cn_publication_cn_pub_year] => 5161804246f9f222647e2a9bc46caa4b-1879127419 [from_id] => 80,78,73,85 [issue] => 12 [sys_level_num] => 2_1 [sys_jg_type] => 0,5 [source_type] => 351 [pub_year] => 1988 [article_id] => 336927,19329,582036,168109 [pages] => 7 [hints] => 13 [author_cn] => 王秉泽;许临晓;邓从豪 [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/198812/72888866495756564950484849.html [publication_cn] => 化学学报 [title_cn] => 类卡宾H2C=CLiF的构型及其异构化 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e06392efecf45c7fdff88b19eddde08c598027517 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 8 [check_3Y] => 0 [language] => Chinese [delivery_No] => U0412 [format_title] => d8fa9c98cc540ac4c9b8422e66163e91263222502 [cauthor_ad] => [WANG, BZ]SHANDONG UNIV,DEPT CHEM,JINAN,PEOPLES R CHINA. [author_fn] => WANG, BZ; XU, LX; DENG, CH [publication_29] => ACTA CHIM SINICA [end_page] => 1167 [publication_type] => J [begin_page] => 1161 [article_dt] => Article [author_en] => WANG, BZ; XU, LX; DENG, CH [volume] => 46 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en] => f831373994392ca49a890f094ee8075a-299917046 [publisher_city] => SHANGHAI [pub_date] => 1988-12-26 [hx_id] => 2371 [reference_No] => 0 [cite_awos] => 8 [wos_No] => WOS:A1988U041200002 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => STRUCTURES AND ISOMERIZATIONS OF CARBENOID H2C=CLIF [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国 [jl_clc] => o64 [jl_publisher] => actachimicasinica [author_in] => [company_id] => 43,169 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [sys_author_id] => [format_title_en_publication_en_pub_year] => c9a060f09a87284342885289cdfb60fc330085150 [format_wos_No] => da3dc031da52fe3c57a1c4809e51e814-613933583 [format_title_en_issn_pub_year] => a0dcaf256d6c9db6a5a6863d019516a01697440409 [id] => TgozvmUBFjIhTVEbnbf8 [tags] => 0 ) [4] => Array ( [issn] => 0567-7351 [reference] => CHARLES RG, 1965, J INORG NUCL CHEM, V27, P119, DOI@@@10.1016/0022-1902(65)80200-7@@@Christiana A. M., 2008, J INORG BIOCHEM, V102, P77@@@Cleare M.J., 1973, PLATIN MET REV, V17, P2@@@ERNEST W, 1999, CHEM REV, V99, P2451@@@FREDERIK CK, 2002, J ORG CHEM, V67, P7185@@@GAO ZJ, 1998, J AM CHEM SOC, V120, P8253@@@John VD, 2002, J EXP CLIN CANC RES, V21, P219@@@Junko I., 2002, BIOORGAN MED CHEM, V10, P3481@@@Kelland LR, 1999, J INORG BIOCHEM, V77, P111, DOI@@@10.1016/S0162-0134(99)00141-5@@@Lev-Ari S, 2006, ANTICANCER RES, V26, P4423@@@Liu Q, 2001, J CHEM SOC DALTON, P911, DOI 10.1039/b008611h@@@Mishra S, 2005, BIOORGAN MED CHEM, V13, P1477, DOI@@@10.1016/j.bmc.2004.12.057@@@Song YM, 2009, J INORG BIOCHEM, V103, P396, DOI@@@10.1016/j.jinorgbio.2008.12.001@@@Su CC, 2006, ANTICANCER RES, V26, P4379@@@Sundquist W I, 1990, J.Coord.Chem.Rev, V100, P293@@@张金超, 2006, [科学通报, Chinese science bulletin], V51, P796@@@ZHANG Q, 2008, CHINESE CHEM LETT, V19, P281@@@[周双生 ZHOU Shuangsheng], 2008, [药学学报, Acta Pharmaceutica Sinica], V43,@@@P490@@@李大圣, 2009, 博士论文 [batch2] => 1,2,6 [format_cscd_No] => 1fd7446ad3b2544058c332fcf23367fd1590889565 [begin_page] => 2335 [tag] => 0 [research_area] => Chemistry [publication_info] => 0567-7351(2011)69:19<2335:JHSLBI>2.0.TX;2-J [abstract_en] => Four kinds of platinum(II) complexes of curcumin analog (A similar to D) were synthesized by self-made curcumin derivatives (L-1 similar to L-4) and potassium tetraiodoplatinate(II) as the starting material with ethanol as solvent. Their compositions were characterized by FT-IR, H-1 NMR, MS, TG-DTA and elemental analysis. MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) was used to study the complexes\' antitumor activity in vitro against human lung adenocarcinoma cancer cell line (A549), human cervix cancer cell line (Hela) and human breast cancer cell line (MCF-7), the results showed that the complexes had strong antitumor activity against these cell lines. Inhibition of human liver tumor of A549 was examined by antitumor rate, complex A showed inhibition activity on transplanting-tumor growth of A549, 800 mg.kg(-1) was as potent as cisplatin, its LD50 was 945.6 mg.kg(-1). [abstract_cn] => 以乙醇为溶剂,用自制的姜黄素衍生物(L1~L4)和碘亚铂酸钾为原料,合成得到了4种姜黄素类铂(II)配合物(A~D),通过FT-IR、1H NMR、MS、差热热重和元素分析对所有目标化合物进行了结构表征.应用MTT(3-(4,5-二甲基噻唑-2)-2,5-二苯基四氮唑溴盐)法研究了化合物体外对人肺腺癌A549、子宫颈癌HeLa和乳腺癌MCF-7细胞的抗肿瘤活性,结果表明这些化合物对上述癌细胞均有较强活性;并用抑瘤率测定了人肺腺瘤(A549)细胞的抑制作用,体内试验也显示铂(II)配合物A具有抗人肺腺癌瘤(A549)作用.其中剂量为800 mg·kg-1的抗瘤活性与顺铂相当,它的半数致死量为94... [keyword_cn] => 姜黄素;铂(Ⅱ)配合物;合成;抗肿瘤活性 [fund_No] => 国家自然科学基金; 安徽省级高校自然科学研究重点项目; 现代中药安徽省工程技术研究中心项目; 安徽中医学院自然科学研究重点项目 [format_title_en_publication_en_pub_year] => d9dd5c1e8a72c51eb24aeddc577c826d606367557 [publication_type] => J [author_jg] => [周双生] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.@@@[薛璇] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.@@@[姜波] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.@@@[鲁传华] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.@@@[田玉鹏] 安徽大学化学化工学院, 晶体材料国家重点实验室, 合肥, 安徽 230039, 中国.@@@[蒋明华] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国 [cite_cscd] => 8 [cite_awos] => 10 [from_id] => 76,75,73,80,78 [issue] => 19 [email] => zshuangsheng@126.com [email_c] => zshuangsheng@126.com [sys_level_num] => 1_1 [format_title_cn_publication_cn_pub_year] => 0dce27a1effac6cc8ea87bdf29581b96-1475139052 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => e5e05545ae1ef1e9f5227f748e618b9e1321155259 [title_en] => Synthesis and Antitumor Activities of Platinum(II) Complexes of Curcumin Analog [volume] => 69 [author_fn] => Zhou Shuangsheng; Xue Xuan; Jiang Bo; Lu Chuanhua; Tian Yupeng; Jiang Minghua [pub_year] => 2011 [check_180] => 0 [keyword_en] => curcumin; platinum(II) complex; synthesis; antitumor activity [end_page] => 2340 [article_id] => 183211,643650,375429,659695,465291 [pages] => 6 [hints] => 106 [author_cn] => 周双生;薛璇;姜波;鲁传华;田玉鹏;蒋明华; [language] => Chinese [source_type] => 351 [reference_No] => 19 [cscd_No] => CSCD:4341063 [batch] => 3250,3243,3249,3252,3241 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2377,2378,2371 [author_in] => [Zhou, S] School of Pharmacy, Anhui College of Traditional Chinese Medicine, Hefei 230031, China@@@[ Xue, X] School of Pharmacy, Anhui College of Traditional Chinese Medicine, Hefei 230031, China@@@[ Jiang, B] School of Pharmacy, Anhui College of Traditional Chinese Medicine, Hefei 230031, China@@@[ Lu, C] School of Pharmacy, Anhui College of Traditional Chinese Medicine, Hefei 230031, China@@@[ Tian, Y] School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China, State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Jiang, M] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China [format_title_en_issn_pub_year] => 304883cbc981364ec3b33d05d6236a1c1741745387 [check_3Y] => 18 [publication_cn] => 化学学报 [title_cn] => 姜黄素类铂(Ⅱ)配合物的合成及其抗肿瘤活性 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e55e7dc080490cea7848c95a56f21f8f-1447262221 [page] => 2335-2340 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_1_7 [cite_wos] => 8 [delivery_No] => 846WK [format_title] => a5979a377840ccddfbe3aee9adc7fb87816062815 [cauthor_ad] => [Zhou, SS]Anhui Coll Tradit Chinese Med, Sch Pharm, Hefei 230031, Peoples R China. [publication_29] => ACTA CHIM SINICA [author_en] => Zhou, SS; Xue, X; Jiang, B; Lu, CH; Tian, YP; Jiang, MH [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => CISPLATIN; APOPTOSIS [publication_iso] => Acta Chim. Sin. [format_title_en] => 65b853689b4ef685c0245ac20395ff2f-1512059267 [publisher_city] => BEIJING [pub_date] => OCT 14 [wos_No] => WOS:000296933700021 [sys_priority_field] => 76 [wos_sub] => Chemistry, Multidisciplinary [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国 [jl_keyword_en] => curcumin,platinumiicomplex,antitumoractivity,synthesis [jl_keyword_cn] => 铂Ⅱ配合物,姜黄素,抗肿瘤活性,合成 [jl_publisher] => sciencepress [cite_wanfang] => 5 [clc] => O643.32 [CSSN] => 31-1320/O6 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-84873837202&partnerID=40&md5=b08fc073f953bf50225ecea76daebbea [jl_clc] => o64332 [company_id] => 24,0,43,169 [sys_subject_sort] => 0,0,0 [college_parent_id] => 24,43,169 [company_test] => Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 合成,antitumoractivity,铂Ⅱ配合物,抗肿瘤活性,姜黄素,curcumin,platinumiicomplex,synthesis [format_scopus_No] => 87d5b4cad5a0e9b92dc8f5bf6076fe441963013408 [format_wos_No] => 13e77ef343b06c0a273c4e84e4bda3991655656023 [standard_in] => School of Pharmacy, Anhui College of Traditional Chinese Medicine, Hefei 230031, China; School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, China; State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China [cauthor] => Zhou, S(zshuangsheng@126.com) [datebase] => Scopus [cite_scopus] => 8 [scopus_No] => 2-s2.0-84873837202 [sys_author_jg_last_arr] => 中国,中国,中国,中国,中国,中国 [jl_company_test] => uircu0,uorgidu24,uparentidu24,unameuu6676u4f53u6750u6599u7814u7a76u6240,ulevelu1 [sys_author_in_last_arr] => china [sys_author_id] => [id] => 2wZ1vWUBFjIhTVEblYtB [tags] => 0 ) [5] => Array ( [batch2] => 1,2,6 [batch] => 3249,3243,3251,3241,3254,3252 [tag] => 0 [abstract_cn] => 将硫酸钛浸渍到SBA-15孔道中,经升温原位沉淀、焙烧得到纳米孔道中均匀分散的锐钛矿相TiO2.用TEM,BET,XRD,SAXD,Raman,UV-Vis漫反射吸收光谱,XPS,XRF等方法对材料进行了表征.表征结果表明,改性后的SBA-15仍保持着有序的孔道,TiO2颗粒较均匀地分布在SBA-15孔道内部,SBA-15孔道合适的纳米尺寸对TiO2颗粒的长大起到较好的限制作用,从拉曼光谱和XPS数据上看,未发现有Ti—O—Si键形成,氧化钛多以TiO2的形式沉积在载体上;紫外光下的甲基橙光降解结果表明,TiO2颗粒大小和含量对光催化活性均有较大影响,6~7nm左右的TiO2颗粒有最佳的光催化... [keyword_cn] => SBA-15;空间限制;纳米TiO2;光催化 [clc] => O626.32 [author_jg] => [苏继新] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[屈文] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[马丽媛] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[殷晶] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.@@@[潘齐] 山东省环境监测中心, 济南, 山东 250013, 中国 [format_title_cn_publication_cn_pub_year] => de9f86bb66b88546ef751cf78c06a8d6-1208301867 [from_id] => 76,75,73,80,78,85 [issue] => 21 [sys_level_num] => 2_1 [sys_jg_type] => 11,8,5 [source_type] => 352,351 [pub_year] => 2008 [article_id] => 661398,321718,21245,480384,514280,167967 [pages] => 7 [hints] => 50 [author_cn] => 苏继新;屈文;马丽媛;殷晶;潘齐; [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-77953149792&partnerID=40&md5=7b627030fa6bef032f373ea06b69bb52 [publication_cn] => 化学学报 [title_cn] => SBA-15空间限制纳米TiO_2颗粒的制备及其光催化性能研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => a38e72d8b06a4c6242757c345dfae4891749315050 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 8 [fund_No] => 国家自然科学基金(No.20577030)资助项目 [check_3Y] => 5 [language] => Chinese [delivery_No] => 381HX [format_title] => 890af71550a43b70f5bbb1d576b0ac681185479425 [cauthor_ad] => [Su, JX]Shandong Univ, Sch Environm Sci & Engn, Jinan 250100, Peoples R China. [author_fn] => Su Ji-Xin; Qu Wen; Ma Li-Yuan; Yin Jing; Pan Qi [reference] => Aguado J, 2002, CATAL TODAY, V75, P95, DOI 10.1016/S0920-5861(02)00049-4@@@@@@Aronson BJ, 1997, CHEM MATER, V9, P2842, DOI 10.1021/cm970180k@@@Busuioc AM, 2007, CATAL COMMUN, V8, P527, DOI@@@10.1016/j.catcom.2006.02.013@@@Jung WY, 2008, CATAL TODAY, V131, P437, DOI 10.1016/j.cattod.2007.10.072@@@Lopez-Mu?oz M J, 2005, Catal. Today, V101, P307@@@Luan ZH, 1999, CHEM MATER, V11, P3680, DOI 10.1021/cm9905141@@@van Grieken R, 2002, J PHOTOCH PHOTOBIO A, V148, P315, DOI@@@10.1016/S1010-6030(02)00058-8@@@@@@Wang W, 2006, MATER RES BULL, V41, P436, DOI@@@10.1016/j.materresbull.2005.07.034@@@[席红安 Xi Hongan], 2002, [化学学报, Acta Chemical Sinica], V60, P2124@@@Zhao DY, 1998, SCIENCE, V279, P548, DOI 10.1126/science.279.5350.548@@@陈绍源, 2006, 化学研究与应用, V18, P11 [publication_29] => ACTA CHIM SINICA [end_page] => 2422 [abstract_en] => Nanocrystalline anatase TiO2 limited within the mesoporous channels of SBA-15 has been prepared by in-situ hydrolysis precipitation of Ti(SO4)(2) solution and subsequent calcination. The as-synthesized samples were characterized by TEM, BET, XRD, SAXD, Raman, UV-Vis, XPS and XRF techniques, and the results indicated that the nano-TiO2 particles were restricted within the channels and dispersed uniformly without blocking the pores. The Raman and XPS data indicated that most TiO2 particles were deposited on the support without forming a TI-O-Si bond. The activities of the samples were evaluated by the photo degradation of methyl orange under UV light. The results showed that the TiO2 contents and the size of the particles on the support of SBA-15 affected the catalytic activity obviously, and the samples with TiO2 particle sizes of about 6 similar to 7 nm showed the best catalytic activity. Little difference of the activity was observed between the fresh sample and the sample used for 5 times. [researcherID] => SDU, Environ Res/P-4462-2015 [author_in] => [Su, J.-X] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Qu, W] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Ma, L.-Y] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Yin, J] School of Environmental Science and Engineering, Shandong University, Jinan 250100, China@@@[ Pan, Q] Shandong Provincial Environmental Monitoring Center, Jinan 250013, China [publication_type] => J [begin_page] => 2416 [article_dt] => Article [author_en] => Su, JX; Qu, W; Ma, LY; Yin, J; Pan, Q [volume] => 66 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => SBA-15; space-restriction; nano-TiO2; photocatalytic activity [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => MESOPOROUS SILICA; TITANIUM [publication_iso] => Acta Chim. Sin. [format_title_en] => fbe1d598e63e272e52f3169ba51d04b4314186372 [publisher_city] => BEIJING [pub_date] => NOV 14 [hx_id] => 2377,2378,2371 [reference_No] => 11 [email] => jxsu@sdu.edu.cn [cite_awos] => 8 [wos_No] => WOS:000261527700017 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Photocatalytic Activity of Nano-size TiO2 Synthesized by Restricting the Particles within Channels of SBA-15 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [page] => 2416-2422 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => spacerestriction,photocatalyticactivity,sba15,nanotio2 [jl_keyword_cn] => 光催化,纳米tio2,sba15,空间限制 [jl_clc] => o62632 [jl_publisher] => sciencepress [author_id] => 23418 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 1 [name] => 苏继新 [sys_author_id] => Array ( [0] => 23418 ) [irtag] => 0 [t_index] => 0 [person_id] => 23418 ) ) [company_id] => 0,39,165 [sys_subject_sort] => 0,0 [college_parent_id] => 165,39 [company_test] => Array,Array [sys_author_id_arr] => 23418苏继新 [cscd_No] => CSCD:3459504 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => photocatalyticactivity,空间限制,纳米tio2,nanotio2,光催化,sba15,spacerestriction [sys_author_id] => 23418 [format_cscd_No] => c0280be687ee32f2645674b79c0cf50d-1336871942 [format_title_en_publication_en_pub_year] => cde8fe4eca30c30ef3ada481db5c9e432100376611 [format_wos_No] => df460f0c135406a2525f394f413816cb253001863 [format_title_en_issn_pub_year] => 0b6f403ef05be2cdab103c145f42e6212055096530 [format_issn_issue_page_pub_year] => 26d0cf31355d5c48b6d917557f89cdcd1969697376 [format_scopus_No] => 06819d5c55d273f1d47b36a1e527639f-93721966 [standard_in] => School of Environmental Science and Engineering, Shandong University, Jinan 250100, China; Shandong Provincial Environmental Monitoring Center, Jinan 250013, China [cauthor] => Su, JX(jxsu@sdu.edu.cn) [datebase] => Scopus [cite_scopus] => 7 [sys_priority_field] => 76 [scopus_No] => 2-s2.0-77953149792 [id] => MQozvmUBFjIhTVEbh682 [tags] => 0 ) [6] => Array ( [batch2] => 1,2 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199302005&DbName=CJFQ1993 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 钠氟类硅烯;;钠氯类硅烯;;三元环构型;;p-配合物构型;;构型异构 [fund_No] => 国家自然科学基金 [article_id] => 648257,113791,155162,336074 [abstract_cn] => 本文用RHF/STO-3G解析梯度方法研究了钠卤类硅烯H_2SiNaX(X=F,C1)势能面的主要特征,得到了它们的几种平衡构型及其异构化的过渡态构型.与锂卤类硅烯相似,三元环构型和p-配合物构型是最稳定的构型;其它的两种构型—σ-配合物和经典“四面体”,也是势能面上的极值点,但能量相对较高、不稳定.文中对各构型的特点进行了分析. [author_jg] => [冯圣玉;邓从豪]山东大学理论化学研究室@@@[冯圣玉;邓从豪]山东大学理论化学研究室 济南 250100@@@[冯圣玉;邓从豪]济南 250100 [format_title_cn_publication_cn_pub_year] => b6524c292884d2c60f5d21099e6af975-289987063 [hints] => 3 [issue] => 2 [author_first] => 冯圣玉; [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => d64cbf0b7106348611a70a68bef5d2c5-772191844 [source_type] => 351 [pub_year] => 1993 [pub_date] => 1993-03-02 [pages] => 5 [from_id] => 80,78,73,85 [author_cn] => 冯圣玉;邓从豪; [issn] => 0567-7351 [batch] => 3250,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 钠卤类硅烯的结构与稳定性 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 1d4e2aed33f9a10c00094e6b34a4ed8a2024887443 [page] => 138-142 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 50abf6dfb7b6fd07927383c845443c021916221325 [format_title] => d45102c327f32adc56e0516860f1f195-60141002 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,构型异构,钠氯类硅烯,钠氟类硅烯,p配合物构型,三元环构型 [author_in] => [company_id] => 0,0,0,0,0 [author_id] => 20721 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 冯圣玉 [irtag] => 7 [t_index] => 0 [person_id] => 20721 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 钠氯类硅烯,三元环构型,p配合物构型,钠氟类硅烯,构型异构 [sys_author_id] => [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [check_3Y] => 0 [language] => Japanese [delivery_No] => KT838 [cauthor_ad] => [FENG, SY]SHANDONG UNIV, THEORET CHEM GRP, JINAN 250100, PEOPLES R CHINA. [author_fn] => FENG, SY; DENG, CH [format_title_en_issn_pub_year] => ae2add6c73d26556fec5e26ab7e307b1-1103936218 [publication_29] => ACTA CHIM SINICA [end_page] => 142 [abstract_en] => The structures and stability of silylenoids H2SiNaX(X=F, Cl) were predicted by ab initio calculations. The STO-3G basis set was used for full geometry optimizations. The two most stable forms are suggested to be the structures with three-membered ring and p-complex, analogous to the similar structurES previously found for silylenoid H2SiLiCl. Two species, sigma-complex and the \'\'classical\'\' (tetrahedral) form, are also local minima on the potential energy surface, but higher in energy and unstable. [publication_type] => J [begin_page] => 138 [author_en] => FENG, SY; DENG, CH [volume] => 51 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 449c28f0f3b8bd384d68afccd3e65d862050072306 [publisher_city] => BEIJING [cauthor_order] => 1 [reference_No] => 7 [cite_awos] => 7 [wos_No] => WOS:A1993KT83800006 [format_wos_No] => e0e9b169c8c55130237eb1bd9090495d-1087121773 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => FENG, SY [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => STRUCTURES AND STABILITY OF SILYLENOIDS H2SINAX (X = F, CL) [id] => hw1EvmUBFjIhTVEbKmEG [tags] => 0 ) [7] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3252,3254,3241 [tag] => 0 [abstract_cn] => 用分子动力学方法研究了阴离子表面活性剂十二烷基硫酸钠(SDS)在气液界面上的结构和动力学性质.选择单分子占有面积分别为0.45和0.68nm^2的两个模拟体系。通过径向分布函数表征了单层膜的厚度,并根据疏水链中碳原子与极性头中硫原子之间组成的矢量分布和取向函数,对比了不同界面单层膜的有序排列情况.结果表明在分子占有面积较小达到饱和吸附的情况下,界面上的SDS具有较好的有序性.通过计算气液界面附近水分子的扩散系数发现:由于氢键和静电作用的影响,界面区域内的水分子较本体溶液中的水分子有较弱的迁移能力. [keyword_cn] => 分子动力学模拟;单层膜;气液界面; [clc] => O484 TQ423.11 [author_jg] => [苑世领] 山东大学胶体与界面化学研究所, 济南, 山东 250100, 中国.@@@[崔鹏] 山东大学胶体与界面化学研究所, 济南, 山东 250100, 中国.@@@[徐桂英] 山东大学胶体与界面化学研究所, 济南, 山东 250100, 中国.@@@[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 5c779b09949632a91ea4f7f144386494-1163557893 [from_id] => 75,78,73,80,85 [issue] => 16 [sys_level_num] => 2_1 [sys_jg_type] => 0,5 [source_type] => 351 [pub_year] => 2006 [article_id] => 115692,249278,554766,662407,326828 [pages] => 6 [hints] => 12 [author_cn] => 苑世领[1,2];崔鹏[1];徐桂英[1];刘成卜[2] [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/200616/22627375.html [publication_cn] => 化学学报 [title_cn] => 气液界面上阴离子表面活性剂单层膜的分子动力学模拟 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => c52259dda965e8842b34ff8e4040d82a-1098924929 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [fund_No] => 国家自然科学基金 [check_3Y] => 5 [language] => Chinese [delivery_No] => 081CM [format_title] => 87993ad7b447acf82c3179c21776acdd530924007 [cauthor_ad] => [Yuan, SL]Shandong Univ, Inst Colloid & Interface Chem, Jinan 250100, Peoples R China. [author_fn] => Yuan Shi-Ling; Cui Peng; Xu Gui-Ying; Liu Cheng-Bu [reference] => Baaden M, 2001, J PHYS CHEM B, V105, P11131, DOI 10.1021/jp011890n@@@BAIN CD, 1994, LANGMUIR, V10, P2060, DOI 10.1021/la00019a006@@@@@@Bandyopadhyay S, 2003, J Langmuir, V19, P10443@@@Chanda J, 2005, J PHYS CHEM B, V109, P471, DOI 10.1021/jp0482924@@@Dhathathreyan A, 2002, J Langmuir, V18, P928@@@Dominguez H, 2000, J PHYS CHEM B, V104, P5302, DOI 10.1021/jp994479x@@@Dominguez H, 2002, J PHYS CHEM B, V106, P5915, DOI 10.1021/jp014403c@@@Gallet X, 1999, LANGMUIR, V15, P2409, DOI 10.1021/la980954r@@@H(o)nig D, 1991, J Phys Chem, V95, P4590@@@HOOVER WG, 1985, PHYS REV A, V31, P1695, DOI 10.1103/PhysRevA.31.1695@@@Islam M N, 2002, T Langmuir, V18, P9422@@@KAWAI T, 1989, CHEM PHYS LETT, V162, P243, DOI@@@10.1016/0009-2614(89)85132-2@@@Kawai T, 2005, Chem B, V109, P4497@@@KJAER K, 1994, PHYSICA B, V198, P100, DOI 10.1016/0921-4526(94)90137-6@@@Koyano H, 1997, T Langmuir, V13, P5426@@@[刘孝恒 Liu Xiaoheng], 2005, [化学学报, Acta Chemical Sinica], V63, P1699@@@Tajima K, 1970, Chem Soc Jpn, V43, P1991@@@TAREK M, 1995, J PHYS CHEM-US, V99, P1393, DOI 10.1021/j100005a006@@@YONEYAMA M, 1995, J AM CHEM SOC, V117, P8188, DOI 10.1021/ja00136a016@@@俞建长, 2005, 化学学报, V63, P1429 [publication_29] => ACTA CHIM SINICA [end_page] => 1664 [abstract_en] => The structures and dynamic properties of anionic surfactant sodium dodecyl sulfate (SDS) at the vapor/liquid interface were investigated using molecular dynamics method. Two systems in which the areas were 0.45 nm(2) and 0.68 nm(2) per molecule respectively were selected. The thickness of monolayer was calculated using radial distribution function (RDF), and the order of hydorcarbon chain at the interface for different systems were estimated through number density profiles and orientation correlation for the unit vector in different molecules. Using the diffusion coefficient calculated by mean square displacement (MSD) of water in the systems, it was found that the diffusion of water molecules in the interface was weaker than those in the bulky solution. [author_in] => [Yuan, SL; Cui, P; Xu, GY; Liu, CB]Shandong Univ, Inst Colloid & Interface Chem, Jinan 250100, Peoples R China.@@@[Yuan, SL; Cui, P; Xu, GY; Liu, CB] Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 1659 [article_dt] => Article [author_en] => Yuan, SL; Cui, P; Xu, GY; Liu, CB [volume] => 64 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => molecular dynamics simulation; monolayer; vapor/liquid interface [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => AIR-WATER-INTERFACE; SODIUM DODECYL-SULFATE; AIR/WATER INTERFACE; COMPUTER-SIMULATIONS; SPECTROSCOPY; REFLECTION; FILMS; LIQUID/LIQUID [publication_iso] => Acta Chim. Sin. [format_title_en] => 5fcd151ea1456bebf84afb8f95a9d6c71015616722 [publisher_city] => BEIJING [pub_date] => AUG 28 [hx_id] => 2377,2371 [reference_No] => 20 [email] => shilingyuan@sdu.edu.cn [cite_awos] => 14 [wos_No] => WOS:000240294800009 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Molecular dynamics on the monolayer of anionic surfactant at vapor/liquid interface [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => monolayer,moleculardynamicssimulation,vaporliquidinterface [jl_keyword_cn] => 气液界面,,单层膜,分子动力学模拟 [jl_clc] => o484tq42311 [jl_publisher] => sciencechinapress [company_id] => [author_id] => 25263,20462 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 崔鹏 [irtag] => 7 [t_index] => 0 [person_id] => 20462 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 苑世领 [irtag] => 7 [t_index] => 0 [person_id] => 25263 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:2480809 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 分子动力学模拟,单层膜,moleculardynamicssimulation,monolayer,气液界面,vaporliquidinterface [sys_author_id] => 25263 [format_cscd_No] => dd40068c821d6bbe2d1821af8a7e29ae-438920037 [format_title_en_publication_en_pub_year] => 9b37c37b0faf733f9a7a47dc176e1ea9414345622 [format_wos_No] => 2f85188f3ee24b9749edebf8bd69089e-1079207959 [format_title_en_issn_pub_year] => d0ebb696fe9c005140e4e1ee895f3003-721301195 [id] => jQkuvmUBFjIhTVEb8kEl [tags] => 0 ) [8] => Array ( [batch2] => 1,2,6 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199809007&DbName=CJFQ1998 [tag] => 0 [abstract_cn] => 测定了十二烷基磺酸钠(As)/正丁醇/20%苯乙烯/水体系相平衡.用油溶性偶氮二异丁腈(AIBN)和水溶性过二硫酸钾(K_2S_2O_8)为引发剂,研究了油包水(W/O)、双连续(BC)和水包油(O/W)型微乳液介质中苯乙烯的聚合反应.得到了苯乙烯转化率和聚苯乙烯分子量与体系水含量之间的关系,讨论了微乳液结构对聚合作用的影响.并通过电镜观察了聚苯乙烯的形貌,求得了聚苯乙烯的粒径,同时用~1H NMR研究了苯乙烯在微乳液液滴中的增溶位置,分析了聚合作用的实验结果. [keyword_cn] => 微乳液;;苯乙烯;;聚合作用;;~1H NMR;;As [fund_No] => 国家自然科学基金(28970136);;山东省自然科学基金资助项目 [article_id] => 498175,334507,539392,70241,239388 [clc] => O657.3 [author_jg] => [郝京诚;陶诚;胡继业;石元昌;李干佐]山东师范大学表面与界面化学实验室@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]山东师范大学表面与界面化学实验室@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]山东师范大学表面与界面化学实验室@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]山东大学胶体与界面化学研究所@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]山东大学胶体与界面化学研究所 济南250014@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250014@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250014 莱阳农学院基础部工作@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250100@@@[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250100 [format_title_cn_publication_cn_pub_year] => 6ab3ffd3e16155c4c6b2dbefabdbe7ef135227859 [hints] => 7 [issue] => 9 [author_first] => 郝京诚 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => d16bc985bbf05e9a7bfcf515edf3061d-1730813878 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-09-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 郝京诚;陶诚;胡继业;石元昌;李干佐 [issn] => 0567-7351 [batch] => 3250,3243,3241,3254,3252 [publication_cn] => 化学学报 [title_cn] => 微乳液中苯乙烯聚合反应的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 301933eb14ebd0448abb2618a1683307-926958375 [page] => 880-885 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 5a53252e81161d87e2e4a62a6074af6b-1540511228 [format_title] => e511369a5864b12eb14b1b7bcf35bc411512813100 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,聚合作用,1hnmr,苯乙烯,as,微乳液 [jl_clc] => o6573 [author_in] => [Shi, Y.-C] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Hao, J.-C] Laboratory of Surface and Interface, Shandong Normal University, Jinan, 250014, China@@@[ Tao, C] Laboratory of Surface and Interface, Shandong Normal University, Jinan, 250014, China@@@[ Hu, J.-Y] Laboratory of Surface and Interface, Shandong Normal University, Jinan, 250014, China@@@[ Li, G.-Z] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,0,0,0,0,0,0,0 [author_id] => 23301,21081 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 郝京诚 [irtag] => 7 [t_index] => 0 [person_id] => 21081 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 石元昌 [irtag] => 7 [t_index] => 0 [person_id] => 23301 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 苯乙烯,微乳液,as,聚合作用,1hnmr [cite_wos] => 7 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 4 [language] => Chinese [delivery_No] => 125YX [author_fn] => Shi, YC; Hao, JC; Tao, C; Hu, JY; Li, GZ [cite_wanfang] => 9 [format_title_en_issn_pub_year] => 082f7a564cef1f7f19de300a28da3e09-1851958242 [datebase] => Scopus [format_scopus_No] => e8715cbdb78618bae1858bd2dbcefa5599922471 [publication_29] => ACTA CHIM SINICA [end_page] => 885 [abstract_en] => The isothermal phase diagram for the system sodium dodecyle sulfonate/n - butanol/20% styrene/water has been determined at 40 degrees C. The polymerization of styrene in O/W, W/O, and BC microemulsions was investigated by using the water - soluble potassium persulfate and oil - soluble azo - bis - isobutyronitrile(AIBN) as initiators. The relationship between the conversion rate of styrene, the molecular weight of polystyrene and the water content of the system was obtained, and the effect of microemulsion structures on the polymerization of styrene was also discussed. With the microscope,the feature of polystyrene particles was observed and the diameter was 20 similar to 60 nm. At the same time, in order to analyze the polymerization ai styrene, the solubilization site of styrene in microemulsion drops was studied by H-1 NMR spectra. [publication_type] => J [begin_page] => 880 [author_en] => Shi, YC; Hao, JC; Tao, C; Hu, JY; Li, GZ [volume] => 56 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => microemulsions; styrene; polymerization; H-1 NMR; As [keyword_plu] => METHYL-METHACRYLATE; MICRO-EMULSIONS; WATER; SYSTEMS [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 614532d6da4f2037d1ac98a5d02a385140954775 [cite_scopus] => 2 [publisher_city] => SHANGHAI [reference_No] => 17 [cite_awos] => 7 [wos_No] => WOS:000076266300008 [format_wos_No] => cb0452e97f275b29c5b05354c0daa213-1810572064 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Laboratory of Surface and Interface, Shandong Normal University, Jinan, 250014, China; Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33748665968 [title_en] => Studies on polymerization of styrene in microemulsions [jl_language] => chinese [jl_author_test] => uirtypical3,uirtstag0,uuindex4,upersonid21081,uuindex1,usureu0,unameuu77f3u5143u660c,utindex0,uirtag6,uirinspecttag0,uirauthortype0,upersonid23301,unameuu90ddu4eacu8bda [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 山东师范大学表面与界面化学实验室,山东师范大学表面与界面化学实验室,山东师范大学表面与界面化学实验室,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所济南250014,济南250014,济南250014莱阳农学院基础部工作,济南250100,济南250100 [jl_country] => 中国 [jl_keyword_en] => polymerization,styrene,as,microemulsions,h1nmr [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => 7A9KvmUBFjIhTVEbYAQa [tags] => 0 ) [9] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 本文研究了三种羧酸取代的四苯基叶啉衍生物在空气/Cd~(2+)水溶液界面上所形成的单层膜及LB膜.这三种卟啉衍生物中,一种没有脂链,另外两种具有不同长度的脂链.由π-A等温线得到的平均表观分子面积相差很大.紫外-可见光谱表明,LB膜中叶啉的Soret吸收带相对于溶液的吸收均红移,但红移程度不同LB膜的偏振紫外-可见光谱表明,LB膜中三种卟啉衍生物的卟啉环具有基本一致的取向.运用亚相降低法得到了三种卟啉衍生物单层LB膜,其紫外-可见光谱与用垂直提拉法得到的LB膜的紫外一可见光谱具有一致的特征.这些结果表明:卟啉衍生物有无取代链及取代链长的不同对平均表观分子面积的大小和膜中环间的距离有影响,但对环... [keyword_cn] => LB膜;卟啉;取向;结构 [article_id] => 334857,167948,539401,498672,13367 [clc] => O643.1 [author_jg] => [刘洪国,冯绪胜,杨孔章,梁维安]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学化学系 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 4f43f69b304d55b6cfa279dfaa1c43b1-1218445284 [hints] => 10 [issue] => 2 [sys_level_num] => 2_3 [sys_jg_type] => 3,5 [format_issn_issue_page_pub_year] => 0e986843283d54e848cdeab8cd5db7ad-149203790 [source_type] => 351 [pub_year] => 1997 [pub_date] => 1997-02-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 刘洪国,冯绪胜,杨孔章,梁维安 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199702002&DbName=CJFQ1997 [publication_cn] => 化学学报 [title_cn] => 具有不同取代链长的卟啉衍生物LB膜的结构研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 6f2e1b753c5021d268ab9e91f2494aff-1993983755 [page] => 117-122 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => 73e086e5dfc61421bab693666d5f56a7-1775415125 [format_title] => 0eeb8894bf09c72cee5b59d33479b312-241599263 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => 取向,lb膜,卟啉,结构 [jl_clc] => o6431 [author_in] => [Liu, H.-G] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Feng, X.-S] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Yang, K.-Z] Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China@@@[ Liang, W.-A] Department of Chemistry, Shandong University, Jinan, 250100, China [company_id] => 0,43,169 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 取向,lb膜,卟啉,结构 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [check_3Y] => 3 [language] => Chinese [delivery_No] => WM087 [cauthor_ad] => [Liu, HG]SHANDONG UNIV,INST COLLOID & INTERFACE CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => Liu, HG; Feng, XS; Yang, KZ; Liang, WA [format_title_en_issn_pub_year] => dc79f0ce646b3e075b74d3adcefba7061626062170 [datebase] => Scopus [format_scopus_No] => 3ef1d3450bdc9b9cdb9db351b7cc3f04958903511 [publication_29] => ACTA CHIM SINICA [end_page] => 122 [abstract_en] => Monolayers and LB films of three kinds of carboxylic acid substituted porphyrins without alkyl chain or with alkyl chains of different length have been studied in this paper. Mean molecular areas were measured and found to increase as the alkyl chain length increased. UV - Vis spectrashow that Soret absorption bands of porphyrins in LB films have different red - shift compared with solution spectra. The polarized UV - Vis spectra show that the three kinds of porphyrins have the same orientation in LB films. The LB monolayers were obtained by using subphase lowing method, their UV - Vis spectra show the same characteristics as those in LB films obtained by using vertical dipping method. These results indicate that substituted alkyl chains have great influence on mean molecular areas and the distance between porphyrin rings in monolayers or LB films, but have no influence on porphyrin ring orientation. The porphyrin ring orientation is determined by porphyrin and the substituted hydrophilic groups. The three kinds of porphyrins have the same orientation in monolayers at Cd2+ aqueous solution interface, too, and the orientation preserved during the transfer. [publication_type] => J [begin_page] => 117 [author_en] => Liu, HG; Feng, XS; Yang, KZ; Liang, WA [volume] => 55 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => LANGMUIR-BLODGETT-FILMS; AIR-WATER-INTERFACE; AMPHIPHILIC PORPHYRINS; DYE MONOLAYERS; ORIENTATION; REFLECTION; LIGHT [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => cf990fd0efa50afdaa3594ba2589ac84-21563950 [cite_scopus] => 1 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 22 [cite_awos] => 7 [wos_No] => WOS:A1997WM08700003 [format_wos_No] => c63876364555580670f4a187a5b3c16e1657092424 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Liu, HG [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [standard_in] => Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100, China; Department of Chemistry, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33749823182 [title_en] => Studies on the structure of LB films of porphyrin derivatives containing different substituted alkyl chains [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_country] => 中国 [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => 9Q9KvmUBFjIhTVEbYAQa [tags] => 0 ) [10] => Array ( [batch2] => 1,2,6 [batch] => 3250,3243,3249,3252,3241 [tag] => 0 [abstract_cn] => 使用4种流行的泛函(BPW91,B3PW91,PW91和B3LYP)考查了若干Au10团簇结构的稳定结构,获得了能量最有利的6种异构体(其中2种以前未见报道),并在此基础上进一步用MP2方法校准了它们的相对稳定性,分析了它们的电子性质以及最稳定异构体与氧分子的化学反应性能.计算结果表明Au10团簇异构体的相对稳定性明显依赖所使用的理论方法和泛函,密度泛函结果显示Au10倾向于采用平面结构,且不同的泛函给出异构体的相对稳定性次序也不相同,而MP2计算则显示三维空间结构的Au10团簇更稳定,Au10可能是金团簇从二维结构到三维结构演化的一个临界点. [keyword_cn] => Au10团簇;几何结构;电子性质;DFT;MP2 [article_id] => 320887,155130,662563,475822,629392 [clc] => O621.1 [author_jg] => [韩哲] 山东大学,理论化学研究所, 济南, 山东 250100, 中国.@@@[张冬菊] 山东大学,理论化学研究所, 济南, 山东 250100, 中国.@@@[刘成卜] 山东大学,理论化学研究所, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 9a088e49880ee9347379123ea252e9e5900475551 [hints] => 22 [issue] => 5 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => 1ae73b95da1669b809d92fce1855edd7-409944510 [source_type] => 351 [pub_year] => 2009 [pub_date] => MAR 14 [pages] => 5 [from_id] => 76,75,73,80,78 [author_cn] => 韩哲;张冬菊;刘成卜; [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-79952523993&partnerID=40&md5=9c2fe610eccd889b376e411034a366a1 [publication_cn] => 化学学报 [title_cn] => Au_(10)团簇结构与电性质的理论研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => dd563c6565e4ea936974e4324d06e612787864177 [page] => 387-391 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [fund_No] => 国家自然科学基金 [check_3Y] => 10 [language] => Chinese [delivery_No] => 427LT [format_title] => 3fde5b77b0f132224f3ec3c02fba9d1e-1973587546 [cauthor_ad] => [Liu, CB]Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China. [author_fn] => Han Zhe; Zhang Dongju; Liu Chengbu [reference] => BECKE AD, 1993, J CHEM PHYS, V98, P5648, DOI 10.1063/1.464913@@@BECKE AD, 1988, PHYS REV A, V38, P3098, DOI 10.1103/PhysRevA.38.3098@@@Bonacic-Koutecky V, 2002, J CHEM PHYS, V117, P3120, DOI@@@10.1063/1.1492800@@@Dunlap,B.I, 1979, Chem.Phys, V71, P3396@@@Fa W, 2005, PHYS REV B, V72, DOI 10.1103/PhysRevB.72.205428@@@Fernandez EM, 2004, PHYS REV B, V70, DOI 10.1103/PhysRevB.70.165403@@@Frisch M J, 2004, GAUSSIAN 03,Revision D.01@@@Furche F, 2002, J CHEM PHYS, V117, P6982, DOI 10.1063/1.1507582@@@Hakkinen H, 2000, PHYS REV B, V62, pR2287, DOI 10.1103/PhysRevB.62.R2287@@@Hakkinen H, 2003, J PHYS CHEM A, V107, P6168, DOI 10.1021/jp035437i@@@HARUTA M, 1987, CHEM LETT, P405, DOI 10.1246/cl.1987.405@@@HARUTA M, 1989, J CATAL, V115, P301, DOI 10.1016/0021-9517(89)90034-1@@@HAY PJ, 1985, J CHEM PHYS, V82, P270, DOI 10.1063/1.448799@@@HAY PJ, 1985, J CHEM PHYS, V82, P299, DOI 10.1063/1.448975@@@KRISHNAN R, 1980, J CHEM PHYS, V72, P650, DOI 10.1063/1.438955@@@LEE CT, 1988, PHYS REV B, V37, P785, DOI 10.1103/PhysRevB.37.785@@@LEE HM, 2003, PHYS CHEM B, V107, P9994@@@PERDEW JP, 1992, PHYS REV B, V45, P13244, DOI 10.1103/PhysRevB.45.13244@@@PERDEW JP, 1992, PHYS REV B, V46, P6671, DOI 10.1103/PhysRevB.46.6671@@@WADT WR, 1985, J CHEM PHYS, V82, P284, DOI 10.1063/1.448800@@@Walker AV, 2005, J CHEM PHYS, V122, DOI 10.1063/1.1857475@@@Wang JL, 2002, PHYS REV B, V66, DOI 10.1103/PhysRevB.66.035418@@@Wells DH, 2002, J CHEM PHYS, V117, P10597, DOI 10.1063/1.1520137@@@Xiao L, 2004, CHEM PHYS LETT, V392, P452, DOI@@@10.1016/j.cplett.2004.05.095 [publication_29] => ACTA CHIM SINICA [end_page] => 391 [abstract_en] => Auto cluster was reexamined by performing both the MP2 calculations and density functional theory (DFT) calculations using several popular functionals, including the B3LYP, BPW91, B3PW91 and PW91. Six most stable isomers of the cluster have been located, and their relative stability, electronic property, and the reactivity towards an oxygen molecule have been studied in details. Our calculated results show that the relative stability of the isomers depends on the level of theory used: in the framework of DFT, Au-10 trends to form planar structures, while the MP2 calculations show that the three-dimensional isomers are energetically more favorable. Based on the present results, Auto may be conjecturably a critical species of gold clusters which bridges the planar structures and three-dimensional ones. [author_in] => [Han, Z] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China@@@[ Zhang, D] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China@@@[ Liu, C] Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China [publication_type] => J [begin_page] => 387 [author_en] => Han, Z; Zhang, DJ; Liu, CB [volume] => 67 [get_data] => 2018-08-29 [publisher] => SCIENCE PRESS [keyword_en] => Au cluster; geometrical structure; electronic property; DFT; MP2 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => EFFECTIVE CORE POTENTIALS; MOLECULAR CALCULATIONS; CORRELATION-ENERGY; CARBON-MONOXIDE; GOLD CATALYSTS; DENSITY; EXCHANGE; APPROXIMATION; TRANSITION; OXIDATION [publication_iso] => Acta Chim. Sin. [format_title_en] => d08c9a4704ea96d4242ac79a8e39f432900686297 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 24 [email] => cbliu@sdu.edu.cn [cite_awos] => 8 [wos_No] => WOS:000264781500006 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => A Theoretical Study on the Geometrical Structure and Electronic Properties of Au-10 Cluster [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => dft,electronicproperty,mp2,aucluster,geometricalstructure [jl_keyword_cn] => au10团簇,电子性质,mp2,几何结构,dft [jl_clc] => o6211 [jl_publisher] => sciencepress [company_id] => 0,0,0,0,0 [author_id] => 25363 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 张冬菊 [irtag] => 7 [t_index] => 0 [person_id] => 25363 ) ) [sys_author_id_arr] => [cscd_No] => CSCD:3589029 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 几何结构,aucluster,dft,au10团簇,电子性质,mp2,geometricalstructure,electronicproperty [sys_author_id] => [format_cscd_No] => 356e8e7275ebf77f330947a6bad0695b-909100998 [format_title_en_publication_en_pub_year] => 9ec2ced7517cf5526c8044de9188438c1911689567 [format_wos_No] => 4738bee34a3349cf8c924777f6332cae370141803 [format_title_en_issn_pub_year] => 9881b03c8252ba69daf5ceebc57716561438208983 [cauthor] => Liu, C(cbliu@sdu.edu.cn) [datebase] => Scopus [format_scopus_No] => 9851d9a12342ab3d4e45b88198a953261143118811 [cite_scopus] => 8 [sys_priority_field] => 76 [standard_in] => Institute of Theoretical Chemistry, Shandong University, Jinan 250100, China [scopus_No] => 2-s2.0-79952523993 [id] => 0A1FvmUBFjIhTVEbZaRs [tags] => 0 ) [11] => Array ( [issn] => 0567-7351 [reference] => Albota MA, 1998, APPL OPTICS, V37, P7352, DOI 10.1364/AO.37.007352@@@[曹笃霞 Cao Duxia], 2004, [化学学报, Acta Chemical Sinica], V62, P225@@@Dean J A, 1999, Lange\\\'s Handbook of Chemistry15th ed@@@DENK W, 1990, SCIENCE, V248, P73, DOI 10.1126/science.2321027@@@Frisch M J, 2003, J. A. Gaussian 03, Revision A. 1@@@Gaussian Inc, 2003, Gaussview 3.0, Copyright Semichem@@@Kannan R, 2001, CHEM MATER, V13, P1896, DOI 10.1021/cm000747o@@@Lakowicz J. R., 1983, PRINCIPLES FLUORESCE, P190@@@LEE CT, 1988, PHYS REV B, V37, P785, DOI 10.1103/PhysRevB.37.785@@@Lei H, 2002, Phy. Lett, V352, P240@@@Liu ZQ, 2003, CHEM-EUR J, V9, P5074, DOI 10.1002/chem.200304833@@@OUDAR JL, 1977, J CHEM PHYS, V66, P2664, DOI 10.1063/1.434213@@@PARTHENOPOULOS DA, 1989, SCIENCE, V245, P843, DOI@@@10.1126/science.245.4920.843@@@Ren Y, 2000, J MATER CHEM, V10, P2025, DOI 10.1039/b001058h@@@@@@REYNOLDS GA, 1975, OPT COMMUN, V13, P222, DOI@@@10.1016/0030-4018(75)90085-1@@@Xu C, 1996, J OPT SOC AM B, V13, P481, DOI 10.1364/JOSAB.13.000481@@@Yuan Z, 2000, J SOLID STATE CHEM, V154, P5, DOI 10.1006/jssc.2000.8803 [batch2] => 1,2,6 [format_cscd_No] => 24438ffc11c38e194b8529ff1de52cb8379099875 [begin_page] => 2103 [tag] => 0 [research_area] => Chemistry [publication_info] => 0567-7351(2004)62:20<2103:DPWDZS>2.0.TX;2-5 [abstract_en] => Two novel fluorene derivatives with dimesitylboryl as electron acceptor and diphenylamino or carbazolyl as electron donor have been synthesized, which are named 2-(N, N-diphenylamino)-7-dimesitylboryl-9,9-diethyl-fluorene (1) and 2-carbazolyl-7-dimesitylboryl-9,9-diethylfluorene (2). Upon excitation by femtosecond laser with a pulse-width of 200 fs, both compounds exhibit strong blue two-photon excited fluorescence in THF with lambda(max) = 484 nm for 1 and lambda(max) = 440 nm for 2. Their two-photon absorption cross- sections obtained by two-photon fluorescence method are 425 GM (1, excited at 800 nm) and 116 GM (2, excited at 730 nm). [abstract_cn] => 以二米基硼 B(Mes) 2 为电子受体 ,以芴基为共轭桥 ,分别以二苯胺和咔唑为电子给体 ,合成了两个新的D π A型化合物 :2 (N ,N 二苯胺基 ) 7 二米基硼基 9,9 二乙基芴 [2 (N ,N diphenylamino) 7 dimesitylboryl 9,9 diethylfluorene ,1]和 2 N 咔唑基 7 二米基硼基 9,9 二乙基芴 [2 carbazolyl 7 dimesitylboryl 9,9 diethylfluorene ,2 ] .在脉宽为 2 0 0fs的飞秒激光激发下 ,它们在THF中发出强的蓝色上转换荧光 ( 1:... [keyword_cn] => 二米基硼;芴衍生物;双光子吸收;上转换荧光 [fund_No] => 国家自然科学基金; 高等学校骨干教师计划资助项目 [format_title_en_publication_en_pub_year] => 8eed930233d5adbbb4a2838a29149049-1335882061 [publication_type] => J [author_jg] => [刘志强] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[曹笃霞] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[刘国群] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[许贵宝] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国 [cite_cscd] => 2 [cite_awos] => 7 [from_id] => 76,75,73,80,78 [issue] => 20 [email] => fangqi@icm.sdu.edu.cn [email_c] => fangqi@icm.sdu.edu.cn [sys_level_num] => 1_1 [format_title_cn_publication_cn_pub_year] => b4e95102d66761068b79e2950d4caa4d-459058622 [sys_jg_type] => 10,3,5 [format_issn_issue_page_pub_year] => 78b20d450aefcd6ff11d68cfc0935042537244656 [title_en] => Synthesis and up-converted fluorescence of D-pi-A compounds with N and B as the centers of electron donating and accepting groups [volume] => 62 [author_fn] => Liu, ZQ; Cao, DX; Fang, Q; Liu, GQ; Xu, GB [pub_year] => 2004 [check_180] => 0 [keyword_en] => dimesitylboryl; fluorene derivative; two-photon absorption; up-converted; fluorescence [end_page] => 2108 [article_id] => 329312,554757,661459,238399,490169 [pages] => 6 [hints] => 31 [author_cn] => 刘志强,曹笃霞,方奇,刘国群,许贵宝 [researcherID] => Liu, Zhiqiang/D-9589-2017; Xu, Guibao/F-3461-2010 [language] => English [source_type] => 351 [reference_No] => 17 [cscd_No] => CSCD:1811001 [batch] => 3250,3243,3249,3252,3241 [publication_en] => ACTA CHIMICA SINICA [hx_id] => 2377,2378,2371 [author_in] => [Liu, Z.-Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Cao, D.-X] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Fang, Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China@@@[ Liu, G.-Q] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China@@@[ Xu, G.-B] State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China [format_title_en_issn_pub_year] => 93a4a27234028e74ade2dc270bc653a9-1709492267 [check_3Y] => 3 [publication_cn] => 化学学报 [title_cn] => 氮硼为电子授受中心的D--π-A化合物的合成与上转换荧光 [orcID] => Liu, Zhiqiang/0000-0001-7863-1759; Liu, Guoqun/0000-0002-3342-5780 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 5cc88598f886c7b70d350eef16fc3f02-1693964479 [page] => 2103-2108 [hb_type] => 2 [article_dt] => Article [hb_batch] => issn_issue_page_pub_year_1_7 [cite_wos] => 7 [delivery_No] => 867JZ [format_title] => 570dbb87d7532630f1b96f5bc3c504f0551717426 [cauthor_ad] => [Liu, ZQ]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China. [publication_29] => ACTA CHIM SINICA [author_en] => Liu, ZQ; Cao, DX; Fang, Q; Liu, GQ; Xu, GB [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => EXCITATION CROSS-SECTIONS [publication_iso] => Acta Chim. Sin. 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[keyword_cn] => 钴(Ⅱ)配合物;schiff碱;氧合反应热力学;热分解反应动力学 [article_id] => 498158,239397,648259,44189,334502 [clc] => O644 [author_jg] => [李淑兰,孟凡芹,刘德信,杨兆荷]山东大学化学系,山东大学化学系,山东大学化学系,山东大学晶体材料研究所 济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 25006f53046e2f1153643449e9a8ba6a888282343 [hints] => 19 [issue] => 5 [sys_level_num] => 2_3 [sys_jg_type] => 0,5 [format_issn_issue_page_pub_year] => dfb9a7d4c6369c0d069efa651b23db35-867182157 [source_type] => 351 [pub_year] => 1998 [pub_date] => 1998-05-20 [pages] => 6 [from_id] => 76,80,78,73,85 [author_cn] => 李淑兰,孟凡芹,刘德信,杨兆荷 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199805010&DbName=CJFQ1998 [publication_cn] => 化学学报 [title_cn] => Co(Ⅱ)Schiff碱配合物的合成、氧合反应热力学及热分解动力学的研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 0ab8ed80068169953b3ae11641715b2b1923491053 [page] => 478-483 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => e686fc2d51d09a197f3c76796e56f8f61779492906 [format_title] => ce0a2c9f1d94383c4a9827cb078715bb-386826545 [hx_id] => 2378,2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => schiff碱,钴Ⅱ配合物,热分解反应动力学,氧合反应热力学 [jl_clc] => o644 [author_in] => [Li, S.-L] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Meng, F.-Q] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Liu, D.-X] Department of Chemistry, Shandong University, Jinan, 250100, China@@@[ Yang, Z.-H] Institute of Crystal Material, Shandong University, Jinan, 250100, China [company_id] => 24,0,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => schiff碱,钴Ⅱ配合物,热分解反应动力学,氧合反应热力学 [cite_wos] => 7 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 1 [language] => Chinese [delivery_No] => ZT693 [cauthor_ad] => [Li, SL]Shandong Univ, Dept Chem, Jinan 250100, Peoples R China. [author_fn] => Li, SL; Meng, FQ; Liu, DX; Yang, ZH [cite_wanfang] => 21 [format_title_en_issn_pub_year] => eaa6947e7c8b8f85eccedba0e0950ebe61941124 [datebase] => Scopus [format_scopus_No] => 3e390a70551a9c81f1b0e310af94bb2c-10496174 [publication_29] => ACTA CHIM SINICA [end_page] => 483 [abstract_en] => Two new cobalt( II) schiff base complexes were prepared and characterized by elemental analyses, IR spectra and thermal analyses. The compositions of the complexes were also determined. Saturated oxygen uptake of the complexes in CH3CN solvent at different temperatures was obtained by manometric oxygen-uptake measurements. Oxygenation equilibrium constants and its thermodynamic parameters Delta H degrees, Delta S degrees were calculated from the above measurements. The effects of temperature and ligand structure on oxygenation were discussed. The thermal stability and non-isothermal kinetics of thermal decomposition reaction were also investigated by TG-DTG technique. The possible reaction mechanisms of their first step of thermodecomposition were deduced by means of integral and differential equations. [publication_type] => J [begin_page] => 478 [author_en] => Li, SL; Meng, FQ; Liu, DX; Yang, ZH [volume] => 56 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => cobalt( II ) complexes; schiff base; oxygenation thermodynamics;; kinetics of thermal decomposition [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 976f75cebec3273b1e4c5afaffd8349a-1234744020 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 21 [cite_awos] => 7 [wos_No] => WOS:000074115200011 [format_wos_No] => f7b80624378e3734d05c894b8cc0d6a9970619356 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Li, SL [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => Department of Chemistry, Shandong University, Jinan, 250100, China; Institute of Crystal Material, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-33750422658 [title_en] => Studies on synthesis, oxygenation thermodynamics and kinetics of thermal decomposition of cobalt(II) Schiff base complexes [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 济南250100 [jl_company_test] => uircu0,uorgidu24,uparentidu24,unameuu6676u4f53u6750u6599u7814u7a76u6240,ulevelu1 [jl_country] => 中国 [jl_keyword_en] => ,oxygenationthermodynamics,cobaltiicomplexes,schiffbase,kineticsofthermaldecomposition [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => iQ1EvmUBFjIhTVEbKmEG [tags] => 0 ) [13] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [abstract_cn] => X射线单晶结构分析结果表明,标题化合物晶体—ZnVAL C_(28)H_(30)N_4O_4SZn属正交晶系,空间群P2_12_12_1,a=0.9259(2),b=1.4409(4),c=2.1046(8)nm,Z=4,最终因子R_w=0.080.利用热重分析对配合物第一步热分解过程进行了非等温动力学研究,探讨了反应的可能机理,得到了其相应的动力学参数,非等温动力学方程为:da/dt=A·e~(-E/RT)3/2(1-α)~(4/3)[1/(1-α)~(1/3)-1]~(-1) [keyword_cn] => Schiff碱;锌配合物;晶体结构;热分解动力学 [article_id] => 167992,335952,620584 [clc] => O641.4 [author_jg] => [李淑兰,刘德信,周建华,孟凡芹,杨兆荷]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学晶体材料研究所 济南250100,济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 6fad7d5fc8bcdc95b29f7876c5a4f99a-1058287203 [hints] => 10 [issue] => 4 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 0da8539cbdc0e7e36d5428fb02316104821989056 [source_type] => 351 [pub_year] => 1995 [pub_date] => 1995-04-20 [pages] => 6 [from_id] => 80,73,78 [author_cn] => 李淑兰,刘德信,周建华,孟凡芹,杨兆荷 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199504006&DbName=CJFQ1995 [publication_cn] => 化学学报 [title_cn] => 邻香兰素L-甲硫氨酸Schiff碱二吡啶合锌(Ⅱ)配合物的合成、晶体结构和热分解动力学 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => e43afca21131e5afdfa13036b7d29acc-1645257951 [page] => 343-348 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => schiff碱,锌配合物,热分解动力学,晶体结构 [jl_clc] => o6414 [author_in] => [LI, SL; LIU, DX; ZHOU, JH; MENG, FQ; YANG, ZH]SHANDONG UNIV,INST CRYSTAL MAT,JINAN 250100,PEOPLES R CHINA. [company_id] => 24,0,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 晶体结构,热分解动力学,锌配合物,schiff碱 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [check_3Y] => 2 [language] => Chinese [delivery_No] => QY409 [format_title] => 5ebe9fb11447bed262b9ba43e4f706e7-1732834348 [cauthor_ad] => [LI, SL]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => LI, SL; LIU, DX; ZHOU, JH; MENG, FQ; YANG, ZH [format_title_en_issn_pub_year] => 2d6c23331a2a394752dd39994a315046-718154076 [publication_29] => ACTA CHIM SINICA [end_page] => 348 [abstract_en] => The crystal of o-vanillin L-methionine dipyridine Zinc(II)-ZnVAL C28H30N4O4SZn was synthesized and its structure was determined by single crystal X-ray diffraction method, The complex is orthorhombic system, space group P2(1)2(1)2(1) with a=0.9259(2), b=1,4409(4), c= 2. 1046(8)nm, Z=4, final R(W)=0.080 for 1378 unique reflections I greater than or equal to 3 sigma(I). The kinetics of thermal decomposition reaction of the complex was studied under a non-isothermal condition by TG. The kinetic parameters were obtained from the analysis of TG, DTG curves by integral and differential methods, The kinetic equation of thermal decomposition reaction are:; d alpha/dt = A.e(-E/RT) 3/2(1-alpha)(4/3)[1/(1-alpha)(1/3)-1](-1). [publication_type] => J [begin_page] => 343 [author_en] => LI, SL; LIU, DX; ZHOU, JH; MENG, FQ; YANG, ZH [volume] => 53 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 0b76287a095328525204915431cad942-2108932373 [format_title_en] => 53267178e3eaad085f16f760d4adf0cd-1200054150 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 8 [cite_awos] => 7 [wos_No] => WOS:A1995QY40900007 [format_wos_No] => 3ed3ee6712154ab08da2b9c6df2449cc1280902727 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => LI, SL [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => SYNTHESIS, CRYSTAL-STRUCTURE AND KINETICS OF THERMAL-DECOMPOSITION OF O-VANILLIN L-METHIONINE SCHIFF-BASE DIPYRIDINE ZINC(II) [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [id] => sw1GvmUBFjIhTVEbGdA3 [tags] => 0 ) [14] => Array ( [batch2] => 1,2 [batch] => 3250,3249,3252,3254,3241 [tag] => 0 [abstract_cn] => 以AlCl3和Li3N为前驱物,利用过量Li3N与水反应大量放热现象,引发两种前驱物之间的固相反应合成了AlN纳米粉.X射线衍射分析、红外吸收光谱、透射电子显微镜以及X射线光电子能谱测试结果表明,利用这种新的合成方法制备的氮化铝主要是六方相,而且颗粒细小.另外,这种方法反应迅速、操作过程简便,有利于降低制备成本和扩大制备规模. [keyword_cn] => 氮化铝;纳米粉;固相反应合成;水引发剂; [clc] => O614.31 TB383 [author_jg] => [李凯] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[董守义] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[郝霄鹏] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[崔得良] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.@@@[刘振刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[于美燕] 山东大学化学与化工学院, 济南, 山东 250100, 中国.@@@[王琪珑] 山东大学化学与化工学院, 济南, 山东 250100, 中国 [format_title_cn_publication_cn_pub_year] => 4d7589a18bdfca76b59f8fcf5b72628e-1673590898 [from_id] => 75,78,73,80,85 [issue] => 12 [sys_level_num] => 2_1 [sys_jg_type] => 10,5 [source_type] => 351 [pub_year] => 2004 [article_id] => 68524,620411,249098,663322,329730 [pages] => 4 [hints] => 28 [author_cn] => 李凯 [1];刘振刚 [2];于美燕 [2];董守义 [1];王琪珑 [2];郝霄鹏 [1];崔得良 [1] [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/200412/9918180.html [publication_cn] => 化学学报 [title_cn] => 利用水引发固相反应方法合成氮化铝纳米粉 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 5d788508b55bf4258eb40d2768f224f1-1404738250 [hb_type] => 2 [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [fund_No] => 国家自然科学基金; 教育部博士点基金; 山东省自然科学基金资助项目 [check_3Y] => 7 [language] => Chinese [delivery_No] => 831TL [format_title] => c144c5f92b101f74fd5f97de552340a61064673409 [cauthor_ad] => [Li, K]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China. [author_fn] => Li, K; Liu, ZG; Yu, MY; Dong, SY; Wang, QL; Hao, XP; Cui, DL [reference] => Hao X P, 2002, Cryst. Growth, V242, P229@@@LI X, 1990, J APPL PHYS, V68, P5369, DOI 10.1063/1.347035@@@Reier T, 1998, ELECTROCHIM ACTA, V43, P149, DOI@@@10.1016/S0013-4686(97)00243-0@@@ROMAN YG, 1989, THIN SOLID FILMS, V169, P241, DOI@@@10.1016/0040-6090(89)90707-4@@@SHIN J, 2000, J AM CERAM SOC, V83, P5@@@Song ZR, 2003, MATER LETT, V57, P4643, DOI 10.1016/S0167-577X(03)00377-X@@@VAIDHYANATHAN B, 2000, J MATER RES, V15, P4@@@YU Q, 2003, J AM CERAM SOC, V86, P7@@@YU Q, 2003, J EUR CERAM SOC, V23, P2015@@@金海波, 2000, 金属学报, V36, P775@@@郑新和, 2001, 中国稀土学报, V19, P430@@@戴长虹, 1999, 金属学报, V32, P1221@@@蔡杰, 1999, 真空电了技术, V2, P28@@@JCPDS No. 08-0262@@@乐志强, 2001, 无机精细化学品手册, P1251 [publication_29] => ACTA CHIM SINICA [end_page] => 1147 [abstract_en] => AlN nanoparticles were prepared by the water induced solid state reaction method, with AlCl3 and Li3N as the starting materials. The results of X-ray diffraction (XRD) analysis, Fourier transformation infrared (FT-IR) absorption spectra measurement, the transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) observation proved that, the sample we prepared with this method was hexagonal AlN. Besides, the particles were very small. The water induced solid state reaction method includes many merits, such as, the reaction complete in a very short time period, and the experimental process is very simple. It is possible to prepare AlN nanoparticles on a large scale with very low cost by this method. [author_in] => [Li, K; Liu, ZG; Yu, MY; Dong, SY; Wang, QL; Hao, XP; Cui, DL]Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China.@@@[Li, K; Liu, ZG; Yu, MY; Dong, SY; Wang, QL; Hao, XP; Cui, DL] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China. [publication_type] => J [begin_page] => 1144 [article_dt] => Article [author_en] => Li, K; Liu, ZG; Yu, MY; Dong, SY; Wang, QL; Hao, XP; Cui, DL [volume] => 62 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => aluminium nitride; nanoparticle; water induced solid state reaction [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => CHEMICAL VAPOR-DEPOSITION; FILMS; PRESSURE; ALUMINUM [publication_iso] => Acta Chim. Sin. [format_title_en] => 456563ee9fb33ca49247e6fb081b479d-1820681771 [publisher_city] => BEIJING [pub_date] => JUN 28 [hx_id] => 2377,2371 [reference_No] => 14 [email] => cuidl@sdu.edu.cn [cite_awos] => 9 [wos_No] => WOS:000222218900010 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 1 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Preparation of AIN nanoparticles by a water induced solid state reaction [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => waterinducedsolidstatereaction,nanoparticle,aluminiumnitride [jl_keyword_cn] => ,氮化铝,纳米粉,水引发剂,固相反应合成 [jl_clc] => o61431tb383 [jl_publisher] => sciencechinapress [company_id] => 24,151,43,169 [sys_subject_sort] => 0,0,0,0 [college_parent_id] => 24,151,43,169 [company_test] => Array,Array,Array,Array [author_id] => 21754,21755,21086,20439 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 崔得良 [irtag] => 7 [t_index] => 0 [person_id] => 20439 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 郝霄鹏 [irtag] => 7 [t_index] => 0 [person_id] => 21086 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 李凯 [irtag] => 7 [t_index] => 0 [person_id] => 21754 ) [3] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 0 [name] => 李凯 [irtag] => 7 [t_index] => 0 [person_id] => 21755 ) ) [sys_author_id_arr] => 20439崔得良,21086郝霄鹏 [cscd_No] => CSCD:1657765 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => aluminiumnitride,氮化铝,waterinducedsolidstatereaction,水引发剂,纳米粉,nanoparticle,固相反应合成 [sys_author_id] => 20439,21086,24118 [format_cscd_No] => c51455ca6aa794455c4862c70acf5f61-1476298859 [format_title_en_publication_en_pub_year] => 2c8e42cf774ecc28a68c8b99bf6ed9be102813045 [format_wos_No] => 856332758794194bba140c336de084de-332225002 [format_title_en_issn_pub_year] => af2b62f2f5278a0ca66866198c7c42da864312233 [id] => HwkxvmUBFjIhTVEbTvGU [tags] => 0 ) [15] => Array ( [batch2] => 1,2,6 [batch] => 3249,3250,3252,3254,3243,3241 [tag] => 0 [abstract_cn] => 使用RS75流变仪 ,采用小振幅振荡剪切方法和稳态剪切方法对含蜡原油在溶胶 -凝胶等温转变过程中的流变性进行了研究 .结果表明 ,等温转变成的凝胶原油的结构在很大程度上决定于预剪切速率 ,非牛顿含蜡原油在结构恢复过程中表现出不可逆的触变特性 .而凝胶原油在外力作用下向溶胶状态转变的过程中 ,要经历从线性粘弹性变形 ,到非线性粘弹性变形 ,再到结构屈服的过程 ,且高剪切应力下的溶胶原油结构与预剪切速率无关 [keyword_cn] => 含蜡原油;溶胶;凝胶;流变性;储能模量 [article_id] => 331536,491922,105802,661936,554771,239381 [clc] => O73 [author_jg] => [李传宪] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[张春光] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[孙德罕] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.@@@[李琦瑰] 石油大学(华东)储运工程学院, 东营, 山东 257061, 中国 [format_title_cn_publication_cn_pub_year] => 127b04d6b747cc3d91aa86bae8730895101504599 [hints] => 6 [issue] => 3 [sys_level_num] => 2_3 [sys_jg_type] => 11,10,3,5 [format_issn_issue_page_pub_year] => 24f72c53e1bece171d9d74a71bd1e752-535943502 [source_type] => 351 [pub_year] => 2003 [pub_date] => MAR [pages] => 4 [from_id] => 76,75,73,80,78,85 [author_cn] => 李传宪,张春光,孙德军,李琦瑰 [issn] => 0567-7351 [uri] => https://www.scopus.com/inward/record.uri?eid=2-s2.0-33750500367&partnerID=40&md5=997ca420c90f9e1bbad002e64ef029fa [publication_cn] => 化学学报 [title_cn] => 原油溶胶-凝胶等温转变过程中的流变性研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => b4b444239576d2480775f0c51489eb50421313602 [page] => 363-366 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [check_3Y] => 2 [language] => Chinese [delivery_No] => 668FN [format_title] => 286fa4b266d821286ca922694328cf09-2119879194 [cauthor_ad] => [Li, CX]Shandong Univ, Key Lab Colloid & Interface Chem, State Educ Minist, Jinan 250100, Peoples R China. [author_fn] => Li, CX; Zhang, CG; Sun, DJ; Li, QG [reference] => Barnes H A J, 1997, Non-Newtonian Fluid Mech, V70, P1@@@Cazaux G, 1998, SPE49213@@@Evdokimov IN, 2001, J PETROL SCI ENG, V30, P199, DOI@@@10.1016/S0920-4105(01)00132-2@@@@@@MILLS PDA, 1991, COLLOID POLYM SCI, V269, P949, DOI 10.1007/BF00657312@@@@@@RONNINGSEN HP, 1991, ENERG FUEL, V5, P895@@@Singh P, 1999, J RHEOL, V43, P1437, DOI 10.1122/1.551054@@@Webber RM, 1999, J RHEOL, V43, P911, DOI 10.1122/1.551045@@@Yaras D, 1993, J.Rheol, V37, P35 [publication_29] => ACTA CHIM SINICA [end_page] => 366 [abstract_en] => The rheological properties of waxy crude oil in sol-gel transition at constant temperature, have been studied with rheometer RS75 in the modes of small amplitude oscillatory shearing and steady shearing. The recovered structures of the crude oil gel including equilibrium structures in rest are dependent on the pre-shear, rates to a great extent. In the transition of gel to sol, the crude oil gel first shows linear visco-elastic behavior, then nonlinear visco-elastic behavior, and finally yielding property. [author_in] => [Li, C.-X] Key Laboratory for Colloid and Interface Chemistry of the State Education Ministry, Shandong University, Jinan 250100, China, College of Oil Storage and Transportation, University of Petroleum (East China), Dongying 257061, China@@@[ Zhang, C.-G] Key Laboratory for Colloid and Interface Chemistry of the State Education Ministry, Shandong University, Jinan 250100, China@@@[ Sun, D.-J] Key Laboratory for Colloid and Interface Chemistry of the State Education Ministry, Shandong University, Jinan 250100, China@@@[ Li, Q.-G] College of Oil Storage and Transportation, University of Petroleum (East China), Dongying 257061, China [publication_type] => J [begin_page] => 363 [author_en] => Li, CX; Zhang, CG; Sun, DJ; Li, QG [volume] => 61 [get_data] => 2018-08-29 [publisher] => SCIENCE CHINA PRESS [keyword_en] => waxy crude oil; sol; gel; rheological property; storage modulus [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [keyword_plu] => FLOW PROPERTIES; CRYSTALLIZATION [publication_iso] => Acta Chim. Sin. [format_title_en] => 513698379035ea6e8977784314fb86bd1699044395 [publisher_city] => BEIJING [hx_id] => 2377,2378,2371 [reference_No] => 8 [email] => lchxian@hdpu.edu.cn [cite_awos] => 11 [wos_No] => WOS:000182279800012 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [title_en] => Study on the rheological properties of crude oil in sol-gel transition at constant temperature [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_publication_en] => actachimicasinica [jl_country] => 中国,中国 [jl_keyword_en] => waxycrudeoil,rheologicalproperty,storagemodulus,sol,gel [jl_keyword_cn] => 凝胶,储能模量,流变性,含蜡原油,溶胶 [jl_clc] => o73 [jl_publisher] => sciencechinapress [company_id] => [author_id] => 25332,23456 [author_test] => Array ( [0] => Array ( [sure] => 1 [irmagnum] => 0 [u_index] => 3 [name] => 孙德军 [irtag] => 0 [t_index] => 0 [person_id] => 23456 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 张成刚 [sys_author_id] => Array ( [0] => 23456 ) [irtag] => 7 [t_index] => 0 [person_id] => 25332 ) ) [sys_author_id_arr] => 23456孙德军 [cscd_No] => CSCD:1358566 [jl_publication_cn_publication_en] => actachimicasinica,化学学报 [jl_keyword_cn_keyword_en] => 含蜡原油,储能模量,凝胶,storagemodulus,sol,rheologicalproperty,流变性,溶胶,waxycrudeoil,gel [sys_author_id] => 23456 [format_cscd_No] => b0f32af02953eb28d6daf292d5108efa975336356 [format_title_en_publication_en_pub_year] => 5f9e61309ee3c060f6ff4d091f0b8002995137209 [format_wos_No] => eb5c8445c89951296d05606196f455a01011457240 [format_title_en_issn_pub_year] => 9be1f5f9ba85fe79320f9ba0791f2104-1397354345 [cauthor] => Li, CX(lchxian@hdpu.edu.cn) [datebase] => Scopus [format_scopus_No] => 9a94ba4807b0cff4be0e14743f20b0171502811045 [cite_scopus] => 7 [sys_priority_field] => 76 [standard_in] => Key Laboratory for Colloid and Interface Chemistry of the State Education Ministry, Shandong University, Jinan 250100, China; College of Oil Storage and Transportation, University of Petroleum (East China), Dongying 257061, China [scopus_No] => 2-s2.0-33750500367 [id] => ow5JvmUBFjIhTVEbudND [tags] => 0 ) [16] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3254,3252 [tag] => 0 [abstract_cn] => 通过PAM/月桂酸钠(R~1 COONa)混合溶液比浓粘度和紫外一可见吸收光谱的测定,考察了两者之间的相互作用机理.结果表明,在中性或弱酸性溶液中,PAM大分子可与R~1COOH发生氢键缔合,而 R~1 COOH则以疏水力与R~1 COO~-缔合成二聚体、预胶束或胶束,从而使PAM大分子链上带有大量电荷,混合溶液表现出聚电解质的粘度行为. [keyword_cn] => PAM(聚丙烯酰胺);R~1COONa(月桂酸钠);比浓粘度;紫外光谱 [article_id] => 335959,44185,620581,155178 [clc] => O641 [author_jg] => [徐桂英,李干佐,李方,毛宏志,刘木辛,苏红梅]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所 济南250100,济南250100,济南250100,济南250100,济南250100,济南250100 [format_title_cn_publication_cn_pub_year] => 528570ff0ee99996e8c0942285a85d3a-1562094894 [hints] => 6 [issue] => 9 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => a4fd3f6c3032e486c7d964bc86ae4cf8-323588728 [source_type] => 351 [pub_year] => 1995 [pub_date] => 1995-09-20 [pages] => 5 [from_id] => 80,78,73,85 [author_cn] => 徐桂英,李干佐,李方,毛宏志,刘木辛,苏红梅 [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199509001&DbName=CJFQ1995 [publication_cn] => 化学学报 [title_cn] => PAM与月桂酸钠的相互作用 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 7061b8428e26de07c89460a67a7e72dc-1355434896 [page] => 837-841 [hb_type] => 2 [article_dt] => Article [hb_batch] => title_cn_publication_cn_pub_year_2_3 [format_title_en] => c855e850957038f657c376b8ea654599-1633689650 [format_title] => 0f3d1958f6ff405f972145d0232894911151852661 [hx_id] => 2371 [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => pam聚丙烯酰胺,r1coona月桂酸钠,比浓粘度,紫外光谱 [jl_clc] => o641 [author_in] => [company_id] => 0,0,0,0,0 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 紫外光谱,r1coona月桂酸钠,比浓粘度,pam聚丙烯酰胺 [sys_author_id] => [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 7 [check_3Y] => 0 [language] => English [delivery_No] => TD117 [cauthor_ad] => [XU, GY]SHANDONG UNIV,INST COLLOID & INTERFACE CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => XU, GY; LI, GZ; LI, F; MAO, HZ; LIU, MX; SU, HM [format_title_en_issn_pub_year] => 47d9a8dfbaa0a64de1e9b6b1cef9438f-338231509 [publication_29] => ACTA CHIM SINICA [end_page] => 841 [researcherID] => Su, Hongmei/S-6093-2016 [abstract_en] => The interaction between polyacrylamide (PAM) and sodium laurate (R(1) COONa) have been studied by viscosity and UV-vis spectroscopy. The reduced viscosity measurements show that PAM/R(1) COONa mixed solution exhibits viscometric behavior of polyelectrolyte. UV-vis spectra indicated that hydrogen bond was formed between PAM and R(1) COOH. And R(1) COOH-R(1) COO- premicelle or micelle was bound to the macromolecule of PAM to form polymer-surfactant complex. [orcID] => Su, Hongmei/0000-0001-7384-6523 [publication_type] => J [begin_page] => 837 [author_en] => XU, GY; LI, GZ; LI, F; MAO, HZ; LIU, MX; SU, HM [volume] => 53 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 5a6a474660f8c7fc3ae69adf5da1ddd4636384844 [publisher_city] => SHANGHAI [cauthor_order] => 1 [reference_No] => 3 [cite_awos] => 7 [wos_No] => WOS:A1995TD11700002 [format_wos_No] => fd25a0d708ee4823d7700203f68be5d41393096714 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => XU, GY [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THE INTERACTION BETWEEN POLYACRYLAMIDE AND SODIUM LAURATE [id] => sA1GvmUBFjIhTVEbGdA3 [tags] => 0 ) [17] => Array ( [batch2] => 1,2,6 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB200007019&DbName=CJFQ2000 [tag] => 0 [abstract_cn] => 为了弄清火菇素蛋白的结构与功能的关系并揭示抗癌机理,使其更好地发挥临床作用,测定了火菇素的圆二色性,井用蛋白质二级结构解析程序分析了火菇素的溶液二级结构.火菇素远紫外圆二色性的研究表明,其水溶液在208nm处表现为宽大负峰,最大平均残基摩尔椭圆度[0]_(208)=-6574deg·cm~2·dmol~(-1),在223nm处为肩,经二级结构解析程序计算分析,火菇素的二级结构和二硫键和芳香氨基酸对火菇素圆二色性的贡献分别为77.4%和22.6%,二级结构的组成为:α-螺旋19.7%,β-折叠和β-转角50.1%,无规卷曲和γ-转角30.2%.火菇素二级结构对pH,SDS和乙醇有一定的稳定性,在... [keyword_cn] => 火菇素;;圆二色性;;溶液二级结构 [fund_No] => 山东省科委九五攻关项目 [article_id] => 554754,239534,333771,496934 [clc] => Z89 [author_jg] => [冯永君;张长铠;陈雅丽;周永芬;易涛]山东大学微生物技术国家重点实验室@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]山东大学微生物技术国家重点实验室@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]山东大学微生物技术国家重点实验室@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]北京大学化学与分子工程学院@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]北京大学化学与分子工程学院 济南250100首都师范大学生物系@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]北京@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]100037@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]济南250100@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]济南250100@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]北京100871@@@[冯永君;张长铠;陈雅丽;周永芬;易涛]北京100871 [format_title_cn_publication_cn_pub_year] => e8d9961c375a2a174dd55ca9cb8327501624228497 [hints] => 2 [issue] => 7 [author_first] => 冯永君 [sys_level_num] => 2_3 [sys_jg_type] => 11,5 [format_issn_issue_page_pub_year] => ea1e925523ec3003bce687ceb59c4dba191463324 [source_type] => 351 [pub_year] => 2000 [pub_date] => 2000-07-20 [pages] => 5 [from_id] => 76,80,73,78 [author_cn] => 冯永君;张长铠;陈雅丽;周永芬;易涛 [issn] => 0567-7351 [batch] => 3250,3243,3241,3252 [publication_cn] => 化学学报 [title_cn] => 火菇素的圆二色性与溶液二级结构 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 548a57e71d12cb5ca754d3104705bacb-1519008992 [page] => 816-820 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,溶液二级结构,圆二色性,火菇素 [jl_clc] => z89 [author_in] => [Feng, Y.-J] National Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, China@@@[ Zhang, C.-K] National Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, China@@@[ Chen, Y.-L] National Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, China@@@[ Zhou, Y.-F] College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China@@@[ Yi, T] College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China [company_id] => 0,0,0,0,0,0,0,0 [author_id] => [author_test] => Array ( ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [hb_batch] => grant_no [cite_wos] => 6 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 6 [language] => Chinese [delivery_No] => 336AF [cauthor_ad] => [Feng, YJ]Shandong Univ, Natl Key Lab Microbial Technol, Jinan 250100, Peoples R China. [format_title] => b5b301d2271689a8b035078f2f1dfe1b1122164388 [author_fn] => Feng, YJ; Zhang, CK; Chen, YL; Zhou, YF; Yi, T [cite_wanfang] => 14 [cauthor] => National Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, China;(songwei@public.east.cn.net) [format_title_en_issn_pub_year] => 5d8d727d731994e77a5423f1401acdfe-1246511370 [datebase] => Scopus [format_scopus_No] => 08b090cfccd42a545c20825ec41efc8d1007758885 [publication_29] => ACTA CHIM SINICA [end_page] => 820 [abstract_en] => In order to reveal the relationship between the structure and the function of flammulin and to make best use of this antitumor substance, the secondary structures of flammulin are studied by the circular dichroism spectroscopy. The far UV circular dichroism spectra of flammulin show a negative peak at 208 mn, with [theta](208) = - 6574 deg . cm(2) . dmol(-1), and a negative shoulder at 223 nm, Based on computer analysis using CCA program, the secondary structure is assigned as alpha - helix 19.7%, beta - pleated sheet and beta - turn 50.1%, random coil and gamma - turn 30.2%. About 77.4% of total CD spectra are contributed by the secondary structures, and 22.6% are contributed by disulphide bond and aromatic amino acid. The near UV circular dichroism spectra of flammulin give a broad negative peak at 268 nm, The secondary structures are relatively stable to pH and SDS. However the protein is sensitive to heat. The structure of flammulin remains well over a wide DH range (from 4.6 to 9.4). But more alkaline pH condition can denature flammulin irreversibly. [publication_type] => J [begin_page] => 816 [author_en] => Feng, YJ; Zhang, CK; Chen, YL; Zhou, YF; Yi, T [volume] => 58 [publisher] => ACTA CHIMICA SINICA [get_data] => 2018-08-29 [keyword_en] => flammulin; circular dichroism; secondary structures [keyword_plu] => PROTEIN CONFORMATION; LASER RAMAN; SPECTROSCOPY [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => e39f8a9eba433e2839dc900def64c354-883924819 [cite_scopus] => 6 [format_title_en] => 467a6cd2738157a08dfde6660224c257-1679093694 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2378,2371 [reference_No] => 14 [cite_awos] => 6 [wos_No] => WOS:000088279100017 [format_wos_No] => 0f30d650fe812470e867586971129b62-408165063 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Feng, YJ [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 354 FENGLING LU, SHANGHAI; 200032, PEOPLES R CHINA [standard_in] => National Key Laboratory of Microbial Technology, Shandong University, Jinan, 250100, China; College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China [scopus_No] => 2-s2.0-0042781541 [title_en] => Circular dichroism spectra and secondary structures in solution of flammulin [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 山东大学微生物技术国家重点实验室,山东大学微生物技术国家重点实验室,山东大学微生物技术国家重点实验室,北京大学化学与分子工程学院,北京大学化学与分子工程学院济南250100首都师范大学生物系,北京,100037,济南250100,济南250100,北京100871,北京100871 [jl_country] => 中国 [jl_keyword_en] => secondarystructures,circulardichroism,flammulin [sys_author_in_last_arr] => china [jl_publisher] => actachimicasinica [sys_author_id] => [id] => kg5JvmUBFjIhTVEbudND [tags] => 0 ) [18] => Array ( [batch2] => 1,2,6 [batch] => 3243,3241,3254,3252 [tag] => 0 [abstract_cn] => 研究表面活性剂缔合体系中木素模型化合物的生物降解机制具有重要意义.本文以黄孢原毛平革菌在一定条件下分泌出的木素过氧化物酶(LiP)为生物催化剂,用分光光度技术研究了非离子表面活性剂TritonX-100存在下水溶液中LiP催化氧化藜芦醇(VA)反应的动力学.结果表明,在TritonX-100水溶液中,LiP催化氧化VA反应遵循乒乓机制.稳态动力学参数测定表明,TritonX-100对上述酶促反应的最大反应初速率及VA的米氏常数影响不大.但使过氧化氢的米氏常数下降近50%.依据不同TritonX-100浓度下(远低于、接近于和远大于其临界胶束浓度)酶促反应的动力学参数和VA的疏水性指数,我们认为该结果是表面活性剂单体对酶蛋白分子的修饰所致. [keyword_cn] => 黄孢原毛平革菌;木素过氧化物酶;藜芦醇;微生物降解;表面活性剂;稳态动力学;催化氧化;环境污染物;生物催化剂; [clc] => X172 Q67 [author_jg] => [黄锡荣;卢雪梅;宋少芳;孙德军;曲音波;高培基]山东大学,中国 [format_title_cn_publication_cn_pub_year] => 862c47c8b11f1bd9be1e7a7013b2a38e1909515466 [from_id] => 76,80,73,85 [issue] => 10 [sys_level_num] => 2_1 [sys_jg_type] => 11,3,5 [source_type] => 351 [pub_year] => 2001 [article_id] => 237798,333208,68708,496006 [pages] => 4 [hints] => 3 [author_cn] => 黄锡荣;卢雪梅;宋少芳;孙德军;曲音波;高培基 [issn] => 0567-7351 [uri] => http://lib.cqvip.com/qk/91047X/200110/5649411.html [publication_cn] => 化学学报 [title_cn] => 非离子表面活性剂水溶液中木素过氧化物酶催化氧化藜芦醇反应稳态动力学研究 [CSSN] => 31-1320/O6 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 77b888c8d76ea91cd5a7a6cf57e87ce4670418440 [hb_type] => 2 [jl_publication_cn] => 化学学报 [jl_country] => 中国 [jl_keyword_cn] => ,木素过氧化物酶,藜芦醇,生物催化剂,微生物降解,催化氧化,环境污染物,表面活性剂,黄孢原毛平革菌,稳态动力学 [jl_clc] => x172q67 [author_in] => [Huang, X.-R] Key Lab. for Colloid and Interface Chemistry of the Education Ministry of China, Shandong University, Jinan, 250100, China, State Key Lab. of Microbial Technology of China, Shandong University, Jinan, 250100, China@@@[ Lu, X.-M] State Key Lab. of Microbial Technology of China, Shandong University, Jinan, 250100, China@@@[ Song, S.-F] Key Lab. for Colloid and Interface Chemistry of the Education Ministry of China, Shandong University, Jinan, 250100, China@@@[ Sun, D.-J] Key Lab. for Colloid and Interface Chemistry of the Education Ministry of China, Shandong University, Jinan, 250100, China@@@[ Qu, Y.-B] State Key Lab. of Microbial Technology of China, Shandong University, Jinan, 250100, China@@@[ Gao, P.-J] State Key Lab. of Microbial Technology of China, Shandong University, Jinan, 250100, China [company_id] => 0,0,0,0,0,0,0,0 [author_id] => 22630,21289,23152,23456 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 黄锡荣 [irtag] => 7 [t_index] => 1 [person_id] => 21289 ) [1] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 2 [name] => 卢雪梅 [irtag] => 7 [t_index] => 0 [person_id] => 22630 ) [2] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 5 [name] => 曲音波 [irtag] => 7 [t_index] => 0 [person_id] => 23152 ) [3] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 4 [name] => 孙德军 [irtag] => 7 [t_index] => 0 [person_id] => 23456 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 催化氧化,木素过氧化物酶,微生物降解,藜芦醇,表面活性剂,稳态动力学,生物催化剂,黄孢原毛平革菌,环境污染物 [hb_batch] => grant_no [cite_wos] => 6 [publication_en] => ACTA CHIMICA SINICA [check_3Y] => 2 [language] => Chinese [delivery_No] => 487PL [cauthor_ad] => [Huang, XR]Shandong Univ, Key Lab Colloid & Interface Chem, Educ Minist China, Jinan 250100, Peoples R China. [format_title] => 8f9fa7ed4658c5d2c1588c876b7040c1567337447 [author_fn] => Huang, XR; Lu, XM; Song, SF; Sun, DJ; Qu, YB; Gao, PJ [cite_wanfang] => 5 [cauthor] => Huang, XR(xrhuang@sdu.edu.cn) [format_title_en_issn_pub_year] => d2ada9133e0e54f0c3c8f7415f9a39d3-1077178727 [datebase] => Scopus [format_scopus_No] => 82160d0119eb6d788056423f04b26f09-717173159 [publication_29] => ACTA CHIM SINICA [end_page] => 1586 [abstract_en] => Biodegradation of lignin model compounds is of great significance to the world\'s environment and resources. Phanerochaete chrysosporium, a wood - decaying fungus, produces extracellular enzymic proteins which are able to catalyze the oxidation of a large variety of substrates through the reaction with hydrogen peroxide. In this paper, ligninase (UP) and its optimum substrate veratryl alcohol (VA) are selected. The kinetics of the H2O2 - dependent ligninase - catalyzed oxidation of veratryl alcohol in the aqueous medium containing nonionic surfactant TritonX - 100 has been investigated using spectrophotometric technique. The results obtained based on steady - state kinetic studies suggest a ping - pong mechanism. Presence of TritonX - 100 has small effect on the maximum initial rate and the Michaelis constant for VA, but it causes the Michaelis constant for H2O2 to decrease dramatically. Based on the kinetic parameters of the enzyme catalyzed reaction at different TritonX - 100 concentrations (lower than, near to, and larger than its critical micelle concentration) and the hydrophobicity index of VA, we think that modification of the enzymic protein by the surfactant monomer is responsible for the above - mentioned results. [article_dt] => Article [publication_type] => J [begin_page] => 1583 [author_en] => Huang, XR; Lu, XM; Song, SF; Sun, DJ; Qu, YB; Gao, PJ [volume] => 59 [publisher] => SCIENCE PRESS [get_data] => 2018-08-29 [keyword_en] => phanerochaete chrysosporium; ligninase; veratryl alcohol; surfactant;; steady-state kinetics [page] => 1583-1586 [keyword_plu] => PHANEROCHAETE-CHRYSOSPORIUM; DEGRADATION [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 758e6068c1913a358db0b1ef29f42dcb731814695 [cite_scopus] => 7 [format_title_en] => 2e7246437341bf5c311c12f69b37c3f2292514615 [publisher_city] => BEIJING [cauthor_order] => 1 [hx_id] => 2378,2371 [reference_No] => 15 [format_issn_issue_page_pub_year] => 76e7b646cda80afa70ed9cf97ef95bea-784491298 [cite_awos] => 6 [wos_No] => WOS:000171884400011 [format_wos_No] => a90daa3f867ad4ba8694556f8b807a7a-2020295890 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => Huang, XR [check_180] => 0 [publisher_ad] => 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA [standard_in] => Key Lab. for Colloid and Interface Chemistry of the Education Ministry of China, Shandong University, Jinan, 250100, China; State Key Lab. of Microbial Technology of China, Shandong University, Jinan, 250100, China [scopus_No] => 2-s2.0-0042370535 [title_en] => Steady-state kinetic studies on the oxidation of veratryl alcohol catalyzed by ligninase in aqueous media containing nonionic surfactant [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [jl_language] => chinese [jl_article_dt] => 期刊论文 [jl_author_test] => uirtypical3,uirtstag0,unameuu66f2u97f3u6ce2,upersonid23456,uuindex2,uuindex1,usureu0,uuindex4,utindex0,uirtag6,uirinspecttag0,uuindex5,uirauthortype0,upersonid22630,unameuu9ec4u9521u8363,unameuu5b59u5fb7u519b,upersonid23152,unameuu5362u96eau6885,upersonid21289 [jl_publication_en] => actachimicasinica [sys_author_jg_last_arr] => 中国 [jl_keyword_en] => ,ligninase,surfactant,veratrylalcohol,steadystatekinetics,phanerochaetechrysosporium [sys_author_in_last_arr] => china [jl_publisher] => sciencepress [sys_author_id] => [id] => 1wkxvmUBFjIhTVEbTvGU [tags] => 0 ) [19] => Array ( [batch2] => 1,2 [batch] => 3250,3241,3252 [tag] => 0 [CSSN] => 31-1320/O6 [keyword_cn] => 配位反应;生成常数;冠醚;环醚;热力学性质;物理性能;镧系;二苯并;高氯酸盐; [article_id] => 167937,336435,648252 [abstract_cn] => 用滴定量热计于298.15 K测定了除钷、镥以外的全部十三种镧系(Ⅲ)高氯酸盐与二苯并-18-冠-6在无水乙腈中的配位作用.借助计算机用自编程序算出了配位反应的生成常数和焓变,进而算出了配位反应的自由能变化和熵变化.探讨了镧系(Ⅲ)阳离子对配位反应的影响.此外,还比较了几种不同冠醚与高氯酸镧在无水乙腈中配位反应的热力学性质. [author_jg] => [黄锡荣;蒋本杲;尹敬执;阎海科]山东大学化学系,山东大学化学系,山东大学化学系,中国科学院化学研究所 济南 250100,济南 250100,济南 250100,北京 100080 [format_title_cn_publication_cn_pub_year] => 864c17cc49b65f36ea369d021ec61b571317171837 [hints] => 6 [issue] => 4 [sys_level_num] => 2_3 [sys_jg_type] => 5 [format_issn_issue_page_pub_year] => 5c68f3ed77e12a2d13429a8c988bbd40957353560 [source_type] => 351 [pub_year] => 1991 [pub_date] => 1991-05-01 [pages] => 6 [from_id] => 80,73,78 [author_cn] => 黄锡荣;蒋本杲;尹敬执;阎海科; [issn] => 0567-7351 [uri] => http://kns.cnki.net/kns/detail/detail.aspx?FileName=HXXB199104008&DbName=CJFQ1991 [publication_cn] => 化学学报 [title_cn] => 稀土(Ⅲ)-冠醚配位反应的热力学性质 Ⅱ. 镧系(Ⅲ)高氯酸盐与二苯并18-冠-6在无水乙腈中配位反应的量热滴定研究 [SYS_TAG] => 3 [format_title_cn_issn_pub_year] => 261ef99a237c0aad71e939dfc8ce05b4764849422 [page] => 359-364 [hb_type] => 2 [article_dt] => Article [jl_publication_cn] => 化学学报 [jl_article_dt] => 期刊论文 [jl_keyword_cn] => ,环醚,镧系,物理性能,配位反应,高氯酸盐,生成常数,二苯并,冠醚,热力学性质 [author_in] => [HUANG, XR; JIANG, BG; YIN, JZ; YAN, HK]ACAD SINICA,INST CHEM,BEIJING 100080,PEOPLES R CHINA. [company_id] => 0,43,169 [author_id] => 21289 [author_test] => Array ( [0] => Array ( [sure] => 0 [irmagnum] => 0 [u_index] => 1 [name] => 黄锡荣 [irtag] => 7 [t_index] => 0 [person_id] => 21289 ) ) [sys_author_id_arr] => [jl_publication_cn_publication_en] => 化学学报 [jl_keyword_cn_keyword_en] => 配位反应,镧系,物理性能,高氯酸盐,二苯并,环醚,生成常数,冠醚,热力学性质 [sys_author_id] => [hb_batch] => grant_no [publication_en] => ACTA CHIMICA SINICA [cite_wos] => 6 [check_3Y] => 2 [language] => Chinese [delivery_No] => FV356 [format_title] => f0ea57b7feb70828ecb0cfd63d3b245e-549700517 [cauthor_ad] => [HUANG, XR]SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA. [author_fn] => HUANG, XR; JIANG, BG; YIN, JZ; YAN, HK [format_title_en_issn_pub_year] => 1d747f70791907c9cb7816af829f9028158479968 [publication_29] => ACTA CHIM SINICA [end_page] => 364 [abstract_en] => The coordination reactions of dibenzo-18-crown-6 with lanthanide perchlorates except Pm, Lu in anhydrous acetonitrile were investigated at 298.15 K by titration calorimeter. The formation constants and enthalpies of coordination reactions were calculated using computer program made by ourselves. The changes of free energy and entropy of every coordination reaction were obtained. The influences of lanthanide cations (III) on the coordination reactions were discussed. Comparisons were also made on the thermodynamic properties for coordination reaction of lanthanum perchlorate with dibenzo-18-crown-6 and with other crowns in anhydrous acetonitrile, respectively. [publication_type] => J [begin_page] => 359 [author_en] => HUANG, XR; JIANG, BG; YIN, JZ; YAN, HK [volume] => 49 [get_data] => 2018-08-29 [publisher] => ACTA CHIMICA SINICA [keyword_plu] => MACROCYCLIC LIGANDS; COMPLEXES; 15-CROWN-5; 18-CROWN-6; POLYETHERS; CATIONS [format_publication_cn] => 6918be3b26b1fa6ec0424f6071208a75331227575 [publication_iso] => Acta Chim. Sin. [format_title_en_publication_en_pub_year] => 56933f5cfe87fb6c0f5d9d340eb52ff5-97608163 [format_title_en] => 2247946979f800c6f518db961a4b531a68710459 [publisher_city] => SHANGHAI [cauthor_order] => 1 [hx_id] => 2371 [reference_No] => 13 [cite_awos] => 8 [wos_No] => WOS:A1991FV35600009 [format_wos_No] => 95dc7dd5e57c41057811e522888265c4-1470588439 [wos_sub] => Chemistry, Multidisciplinary [research_area] => Chemistry [cauthor_back] => HUANG, XR [check_180] => 0 [publisher_ad] => SHANGHAI INST ORGANIC CHEM ACADEMIA SINICA 345 LINGLING LU, SHANGHAI,; PEOPLES R CHINA [title_en] => THERMODYNAMIC PROPERTIES OF RARE EARTH(III)-CROWNETHER COORDINATION REACTIONS .2. CALORIMETRIC TITRATION STUDIES ON COORDINATION REACTIONS OF LANTHANIDE PERCHLORATES WITH DIBENZO-18-CROWN-6 IN ANHYDROUS ACETONITRILE [format_publication_en] => 169b60c7845c9e5f36906950b18f11111348184734 [sys_subject_sort] => 0,0 [college_parent_id] => 43,169 [company_test] => Array,Array [id] => gg1EvmUBFjIhTVEbKmEG [tags] => 0 ) ) 1-->
41. 多支结构的均三嗪衍生物的合成及双光子吸收性质 CSCD SCOPUS SCIE

作者:崔月芝;方奇;薛刚;许贵宝;于文涛;尹磊

作者机构:[崔月芝] 山东轻工业学院化工系, 济南, 山东 250100, 中国.;[方奇] 山东轻工业学院化工系, 济南, 山东 250100, 中国.;[薛刚] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[许贵宝] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[于文涛] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[尹磊] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2005,Vol.63,Issue.15,50-57

WOS被引数:8

资源类型:期刊论文

WOS:000231163200008

42. I+HI′(v)→IH(v′)+I′反应几率振荡行为的量子散射理论研究 SCIE

作者:蔡政亭,赵显,邓从豪

作者机构:[蔡政亭,赵显,邓从豪]山东大学理论化学研究室,山东大学理论化学研究室,山东大学理论化学研究室 济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1995,Vol.53,Issue.11,1054-1059

WOS被引数:8

资源类型:期刊论文

WOS:A1995TL44500003

43. 芴衍生物的合成、结构与蓝色(λ_(max)=418nm)双光子荧光 CSCD SCOPUS SCIE

作者:曹笃霞,方奇,薛刚,许贵宝,于文涛,刘志强

作者机构:[曹笃霞,方奇,薛刚,许贵宝,于文涛,刘志强]山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室,山东大学晶体材料国家重点实验室 济南250100,济南250100,济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.3,225-229

WOS被引数:8

资源类型:期刊论文

WOS:000188877700001

44. 类卡宾H2C=CLiF的构型及其异构化 SCIE

作者:王秉泽;许临晓;邓从豪

作者机构:[王秉泽;许临晓;邓从豪]山东大学化学系,复旦大学化学系,山东大学化学系 济南,上海,济南

来源:化学学报,ACTA CHIMICA SINICA,1988,Vol.46,Issue.12

WOS被引数:8

资源类型:期刊论文

WOS:A1988U041200002

45. 姜黄素类铂(Ⅱ)配合物的合成及其抗肿瘤活性 CSCD SCOPUS SCIE

作者:周双生;薛璇;姜波;鲁传华;田玉鹏;蒋明华;

作者机构:[周双生] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.;[薛璇] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.;[姜波] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.;[鲁传华] 安徽中医学院药学院, 合肥, 安徽 230031, 中国.;[田玉鹏] 安徽大学化学化工学院, 晶体材料国家重点实验室, 合肥, 安徽 230039, 中国.;[蒋明华] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2011,Vol.69,Issue.19,2335-2340

WOS被引数:8

资源类型:期刊论文

WOS:000296933700021

46. SBA-15空间限制纳米TiO_2颗粒的制备及其光催化性能研究 CSCD SCOPUS SCIE

作者:苏继新;屈文;马丽媛;殷晶;潘齐;

作者机构:[苏继新] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[屈文] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[马丽媛] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[殷晶] 山东大学环境科学与工程学院, 济南, 山东 250100, 中国.;[潘齐] 山东省环境监测中心, 济南, 山东 250013, 中国

来源:化学学报,ACTA CHIMICA SINICA,2008,Vol.66,Issue.21,2416-2422

WOS被引数:8

资源类型:会议论文;期刊论文

WOS:000261527700017

47. 钠卤类硅烯的结构与稳定性 SCIE

作者:冯圣玉;邓从豪;

作者机构:[冯圣玉;邓从豪]山东大学理论化学研究室;[冯圣玉;邓从豪]山东大学理论化学研究室 济南 250100;[冯圣玉;邓从豪]济南 250100

来源:化学学报,ACTA CHIMICA SINICA,1993,Vol.51,Issue.2,138-142

WOS被引数:7

资源类型:期刊论文

WOS:A1993KT83800006

48. 气液界面上阴离子表面活性剂单层膜的分子动力学模拟 CSCD SCIE

作者:苑世领[1,2];崔鹏[1];徐桂英[1];刘成卜[2]

作者机构:[苑世领] 山东大学胶体与界面化学研究所, 济南, 山东 250100, 中国.;[崔鹏] 山东大学胶体与界面化学研究所, 济南, 山东 250100, 中国.;[徐桂英] 山东大学胶体与界面化学研究所, 济南, 山东 250100, 中国.;[刘成卜] 山东大学理论化学研究所, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2006,Vol.64,Issue.16

WOS被引数:7

资源类型:期刊论文

WOS:000240294800009

49. 微乳液中苯乙烯聚合反应的研究 SCOPUS SCIE

作者:郝京诚;陶诚;胡继业;石元昌;李干佐

作者机构:[郝京诚;陶诚;胡继业;石元昌;李干佐]山东师范大学表面与界面化学实验室;[郝京诚;陶诚;胡继业;石元昌;李干佐]山东师范大学表面与界面化学实验室;[郝京诚;陶诚;胡继业;石元昌;李干佐]山东师范大学表面与界面化学实验室;[郝京诚;陶诚;胡继业;石元昌;李干佐]山东大学胶体与界面化学研究所;[郝京诚;陶诚;胡继业;石元昌;李干佐]山东大学胶体与界面化学研究所 济南250014;[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250014;[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250014 莱阳农学院基础部工作;[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250100;[郝京诚;陶诚;胡继业;石元昌;李干佐]济南250100

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.9,880-885

WOS被引数:7

资源类型:期刊论文

WOS:000076266300008

50. 具有不同取代链长的卟啉衍生物LB膜的结构研究 SCOPUS SCIE

作者:刘洪国,冯绪胜,杨孔章,梁维安

作者机构:[刘洪国,冯绪胜,杨孔章,梁维安]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学化学系 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1997,Vol.55,Issue.2,117-122

WOS被引数:7

资源类型:期刊论文

WOS:A1997WM08700003

51. Au_(10)团簇结构与电性质的理论研究 CSCD SCOPUS SCIE

作者:韩哲;张冬菊;刘成卜;

作者机构:[韩哲] 山东大学,理论化学研究所, 济南, 山东 250100, 中国.;[张冬菊] 山东大学,理论化学研究所, 济南, 山东 250100, 中国.;[刘成卜] 山东大学,理论化学研究所, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2009,Vol.67,Issue.5,387-391

WOS被引数:7

资源类型:期刊论文

WOS:000264781500006

52. 氮硼为电子授受中心的D--π-A化合物的合成与上转换荧光 CSCD SCOPUS SCIE

作者:刘志强,曹笃霞,方奇,刘国群,许贵宝

作者机构:[刘志强] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[曹笃霞] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[方奇] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[刘国群] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[许贵宝] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.20,2103-2108

WOS被引数:7

资源类型:期刊论文

WOS:000224840200025

53. Co(Ⅱ)Schiff碱配合物的合成、氧合反应热力学及热分解动力学的研究 SCOPUS SCIE

作者:李淑兰,孟凡芹,刘德信,杨兆荷

作者机构:[李淑兰,孟凡芹,刘德信,杨兆荷]山东大学化学系,山东大学化学系,山东大学化学系,山东大学晶体材料研究所 济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1998,Vol.56,Issue.5,478-483

WOS被引数:7

资源类型:期刊论文

WOS:000074115200011

54. 邻香兰素L-甲硫氨酸Schiff碱二吡啶合锌(Ⅱ)配合物的合成、晶体结构和热分解动力学 SCIE

作者:李淑兰,刘德信,周建华,孟凡芹,杨兆荷

作者机构:[李淑兰,刘德信,周建华,孟凡芹,杨兆荷]山东大学化学系,山东大学化学系,山东大学化学系,山东大学化学系,山东大学晶体材料研究所 济南250100,济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1995,Vol.53,Issue.4,343-348

WOS被引数:7

资源类型:期刊论文

WOS:A1995QY40900007

55. 利用水引发固相反应方法合成氮化铝纳米粉 CSCD SCIE

作者:李凯 [1];刘振刚 [2];于美燕 [2];董守义 [1];王琪珑 [2];郝霄鹏 [1];崔得良 [1]

作者机构:[李凯] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[董守义] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[郝霄鹏] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[崔得良] 山东大学, 晶体材料国家重点实验室, 济南, 山东 250100, 中国.;[刘振刚] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[于美燕] 山东大学化学与化工学院, 济南, 山东 250100, 中国.;[王琪珑] 山东大学化学与化工学院, 济南, 山东 250100, 中国

来源:化学学报,ACTA CHIMICA SINICA,2004,Vol.62,Issue.12

WOS被引数:7

资源类型:期刊论文

WOS:000222218900010

56. 原油溶胶-凝胶等温转变过程中的流变性研究 CSCD SCOPUS SCIE

作者:李传宪,张春光,孙德军,李琦瑰

作者机构:[李传宪] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[张春光] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[孙德罕] 山东大学, 胶体与界面化学教育部重点实验室, 济南, 山东 250100, 中国.;[李琦瑰] 石油大学(华东)储运工程学院, 东营, 山东 257061, 中国

来源:化学学报,ACTA CHIMICA SINICA,2003,Vol.61,Issue.3,363-366

WOS被引数:7

资源类型:期刊论文

WOS:000182279800012

57. PAM与月桂酸钠的相互作用 SCIE

作者:徐桂英,李干佐,李方,毛宏志,刘木辛,苏红梅

作者机构:[徐桂英,李干佐,李方,毛宏志,刘木辛,苏红梅]山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所,山东大学胶体与界面化学研究所 济南250100,济南250100,济南250100,济南250100,济南250100,济南250100

来源:化学学报,ACTA CHIMICA SINICA,1995,Vol.53,Issue.9,837-841

WOS被引数:7

资源类型:期刊论文

WOS:A1995TD11700002

58. 火菇素的圆二色性与溶液二级结构 SCOPUS SCIE

作者:冯永君;张长铠;陈雅丽;周永芬;易涛

作者机构:[冯永君;张长铠;陈雅丽;周永芬;易涛]山东大学微生物技术国家重点实验室;[冯永君;张长铠;陈雅丽;周永芬;易涛]山东大学微生物技术国家重点实验室;[冯永君;张长铠;陈雅丽;周永芬;易涛]山东大学微生物技术国家重点实验室;[冯永君;张长铠;陈雅丽;周永芬;易涛]北京大学化学与分子工程学院;[冯永君;张长铠;陈雅丽;周永芬;易涛]北京大学化学与分子工程学院 济南250100首都师范大学生物系;[冯永君;张长铠;陈雅丽;周永芬;易涛]北京;[冯永君;张长铠;陈雅丽;周永芬;易涛]100037;[冯永君;张长铠;陈雅丽;周永芬;易涛]济南250100;[冯永君;张长铠;陈雅丽;周永芬;易涛]济南250100;[冯永君;张长铠;陈雅丽;周永芬;易涛]北京100871;[冯永君;张长铠;陈雅丽;周永芬;易涛]北京100871

来源:化学学报,ACTA CHIMICA SINICA,2000,Vol.58,Issue.7,816-820

WOS被引数:6

资源类型:期刊论文

WOS:000088279100017

59. 非离子表面活性剂水溶液中木素过氧化物酶催化氧化藜芦醇反应稳态动力学研究 SCOPUS SCIE

作者:黄锡荣;卢雪梅;宋少芳;孙德军;曲音波;高培基

作者机构:[黄锡荣;卢雪梅;宋少芳;孙德军;曲音波;高培基]山东大学,中国

来源:化学学报,ACTA CHIMICA SINICA,2001,Vol.59,Issue.10,1583-1586

WOS被引数:6

资源类型:期刊论文

WOS:000171884400011

60. 稀土(Ⅲ)-冠醚配位反应的热力学性质 Ⅱ. 镧系(Ⅲ)高氯酸盐与二苯并18-冠-6在无水乙腈中配位反应的量热滴定研究 SCIE

作者:黄锡荣;蒋本杲;尹敬执;阎海科;

作者机构:[黄锡荣;蒋本杲;尹敬执;阎海科]山东大学化学系,山东大学化学系,山东大学化学系,中国科学院化学研究所 济南 250100,济南 250100,济南 250100,北京 100080

来源:化学学报,ACTA CHIMICA SINICA,1991,Vol.49,Issue.4,359-364

WOS被引数:6

资源类型:期刊论文

WOS:A1991FV35600009

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